4-Methyl-3-pentenyl O-<5-acetamido-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonic acid)-(2->8)-O-(5-acetamido-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonic acid)-(2->3)-O-(β-D-galactopyranosyl)-(1->4)-β-D-glucopyranoside | 160835-53-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4-Methyl-3-pentenyl O-<5-acetamido-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonic acid)-(2->8)-O-(5-acetamido-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonic acid)-(2->3)-O-(β-D-galactopyranosyl)-(1->4)-β-D-glucopyranoside
• CAS: 160835-53-0
• 化学式: C₄₀H₆₆N₂O₂₇
• 分子量: 1006.96
• InChiKey: JWJGPCDGFHOTRR-WMYWXMCZSA-N

反应信息

• 作为反应物：
  描述：

  4-Methyl-3-pentenyl O-<5-acetamido-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonic acid)-(2->8)-O-(5-acetamido-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonic acid)-(2->3)-O-(β-D-galactopyranosyl)-(1->4)-β-D-glucopyranoside 在 二甲基硫 、 臭氧 作用下， 生成 3-Oxopropyl O-(5-acetamido-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonic acid)-(2->8)-O-(5-acetamido-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonic acid)-(2->3)-O-(β-D-galactopyranosyl)-(1->4)-β-D-glucopyranoside
  参考文献：
  名称：

  Diakur, James; Noujaim, Antoine A., Journal of Carbohydrate Chemistry, 1994, vol. 13, # 5, p. 777 - 798

  摘要：

  DOI：
• 作为产物：
  描述：

  4-Methyl-3-pentenyl O-(benzyl 5-acetamido-4,7,8,9-tetra-O-acetyl-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonate)-(2->8)-(benzyl 5-acetamido-2,4,7,9-tetra-O-acetyl-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonate)-(2->3)-O-(2-O-.... 在 氢氧化钾 作用下， 以 甲醇 为溶剂， 以93%的产率得到4-Methyl-3-pentenyl O-<5-acetamido-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonic acid)-(2->8)-O-(5-acetamido-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosylonic acid)-(2->3)-O-(β-D-galactopyranosyl)-(1->4)-β-D-glucopyranoside
  参考文献：
  名称：

  Diakur, James; Noujaim, Antoine A., Journal of Carbohydrate Chemistry, 1994, vol. 13, # 5, p. 777 - 798

  摘要：

  DOI：