| 1242511-71-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 1242511-71-2
• 化学式: C₁₅H₂₅NOS
• 分子量: 267.436
• InChiKey: UMENPYXREXEPFW-TVRADYJESA-N

反应信息

• 作为反应物：
  描述：

  以 苯 为溶剂， 生成 、
  参考文献：
  名称：

  Ring-Opening of NH-Aziridines with Thiols in Ionic Liquids: Application to the Synthesis of Aminosulfide Catalysts for Asymmetric Epoxidation of Aldehydes

  摘要：

  The ring opening of NH-aziridines with thiols was found to proceed in good yield at room temperature in the presence of an ionic liquid1-butyl-3-methylimidazolium chloride (BMIM chloride). This mild methodology was applied to the synthesis of a camphor-derived chiral aminosulfide. The sulfide was used to generate a sulfur ylide, which effected an asymmetric epoxidation of benzaldehyde (e.r. 85:15, trans:cis 90:10, 87% yield). The amino group enabled easy recovery of the sulfide (98% yield) after the reaction by a simple acid/base extraction.

  DOI：

  10.1080/10426501003773787