cis-[Pt(CH3COO)2(P-n-Bu3)2] | 656223-41-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: cis-[Pt(CH3COO)2(P-n-Bu3)2]
• CAS: 656223-41-5
• 化学式: C₂₈H₆₀O₄P₂Pt
• 分子量: 717.81
• InChiKey: KLPHAFRLQZOZGF-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  trans-[Pt(CH3COO)2(P-n-Bu3)2] 以 not given 为溶剂， 生成 cis-[Pt(CH3COO)2(P-n-Bu3)2]
  参考文献：
  名称：

  Reaction of platinum acetate with phosphines and molecular structure of trans-[Pt(OAc)2(PPh3)2]

  摘要：

  An improved synthesis of platinum acetate is reported in detail. This tetrameric complex reacts with PPh3 or P-n-BU3 at room temperature to give the thermodynamically unstable bis-substituted trans-[Pt(OAc)(2)L-2] complexes, which are not easily accessible via other routes. The structure of the new compound trans-[Pt(OAc)(2)(PPh3)(2)] has been determined by X-ray analysis. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00314-1