1,1,1-trifluoro-7-(dimethylamino)-4-methyl-5-aza-3-hepten-2-one | 158304-53-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,1,1-trifluoro-7-(dimethylamino)-4-methyl-5-aza-3-hepten-2-one
• CAS: 158304-53-1
• 化学式: C₉H₁₅F₃N₂O
• 分子量: 224.226
• InChiKey: UDYUTHVAEDCFSR-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  sodium azide 、 copper(II) perchlorate hexahydrate 、 1,1,1-trifluoro-7-(dimethylamino)-4-methyl-5-aza-3-hepten-2-one 在 triethylamine 作用下， 以 甲醇 为溶剂， 以48%的产率得到[Cu(1,1,1-trifluoro-7-(dimethylamino)-4-methyl-5-aza-3-hepten-2-onate)(azide)]n
  参考文献：
  名称：

  Tuning magnetic exchange using the versatile azide ligand

  摘要：

  The ability of the azido ligand to generate various chemical architectures and magnetic couplings is surveyed, using Cu(II) and Ni(II) derivatives. Depending on the ratio between the azide salt, the metal salt and the tridentate Schiff base LH (L : 1,1,1- trifluoro-7-(dimethylamino)-4-methyl-5-aza-3-hepten-2-onato), molecular bimetallic [CuL(mu(1,3)-N-3)](2) (1) and monometallic [NiL(mu(1)-N-3)] (2) as well as extended {[CuL(mu(1,1)-N-3)]}(n) (3) and {[Ni-2(mu(1,1)-N-3)(mu(1,3)-N-3)(L)(2)(MeOH)(2)]}(n) (4) chains were obtained. These systems were fully characterized by X-ray diffraction and magnetic susceptibility measurements. In 1, the asymmetrical double mu(1,3)-N-3 bridge mediates a ferromagnetic exchange whereas 3 and 4 exhibit unusual symmetric and asymmetric single mu(1,1)-N-3 coordination modes that transmit weak ferromagnetic interactions. Ab initio calculations were systematically performed to clarify the origin of the observed magnetic exchanges and to study the role of the asymmetric coordination modes on the magnetic coupling. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.02.045