6-deoxy-6-thiol-α-CD | 94827-11-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 6-deoxy-6-thiol-α-CD
• CAS: 94827-11-9
• 化学式: C₃₆H₆₀O₂₉S
• 分子量: 988.921
• InChiKey: UWIFMMGPOJWJBS-RWMJIURBSA-N

物化性质

• 沸点：
  1403.6±60.0 °C(Predicted)
• 密度：
  1.606±0.06 g/cm3(Predicted)

反应信息

• 作为产物：
  描述：

  6-deoxy-6-thiouronium-α-CD p-toluenesulfonylate 在 sodium hydroxide 作用下， 以 水 为溶剂， 反应 0.25h， 生成 6-deoxy-6-thiol-α-CD
  参考文献：
  名称：

  Complexation of a disulfide-linked α-cyclodextrin dimer with 1-alkanols

  摘要：

  NMR titration experiments showed that a disulfide-linked alpha-cyclodextrin dimer (1) stepwise forms 1:1 and 1:2 (host:guest) complexes with 1-alkanols. In the cases of ethanol and I-propanol with short alkyl chains, the first and second guest molecules are included within the different CD cavities of 1. On the other hand, 1-pentanol and 1-hexanol with relatively long alkyl chains are bound to both of the CD cavities of 1 in their 1:1 complexes. The 1:1 complexes are less soluble in D2O than their 1:2 complexes and slowly form precipitates. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2008.04.015