phenyl 3-O-benzyl-2,6-di-O-pivaloyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-1-thio-β-D-glucopyranoside | 945391-30-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: phenyl 3-O-benzyl-2,6-di-O-pivaloyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-1-thio-β-D-glucopyranoside
• CAS: 945391-30-0
• 化学式: C₆₅H₁₀₂O₂₇S
• 分子量: 1347.57
• InChiKey: BEERZBDEWPTQOY-TZOCTITPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.14
• 重原子数：
  93.0
• 可旋转键数：
  32.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  275.89
• 氢给体数：
  1.0
• 氢受体数：
  28.0

反应信息

• 作为反应物：
  描述：

  、 phenyl 2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-1-thio-β-D-glucopyranoside 、 phenyl 3-O-benzyl-2,6-di-O-pivaloyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-1-thio-β-D-glucopyranoside 、 phenyl 3-O-benzyl-2,6-di-O-pivaloyl-β-D-glucopyranosyl-[1-4]-3-O-benzyl-2,6-di-O-pivaloyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6,-tri-O-methyl-β-D-glcopyranosyl-[1-4]-2,3,6-tri-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-1-thio-β-D-glucopyranoside 在 三氟化硼乙醚 active moleculae sieve 4A 作用下， 以 二氯甲烷 为溶剂， -30.0 ℃ 、0.13 Pa 条件下， 反应 9.0h， 以5%的产率得到phenyl 3-O-benzyl-2,6-di-pivaloyl-β-D-glucopyranosyl-[1-4]-3-O-benzyl-2,6-di-O-pivaloyl-β-D-glucopyranosyl-[1-4]-3-O-benzyl-2,6-di-O-pivaloyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6,-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-methyl-1-thio-β-D-glucopyranoside
  参考文献：
  名称：

  WO2006/67883

  摘要：

  公开号：
• 作为产物：
  描述：

  、 phenyl 2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-1-thio-β-D-glucopyranoside 在 三氟化硼乙醚 active moleculae sieve 4A 作用下， 以 二氯甲烷 为溶剂， -30.0~-20.0 ℃ 、0.13 Pa 条件下， 反应 53.3h， 以55%的产率得到phenyl 3-O-benzyl-2,6-di-O-pivaloyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-1-thio-β-D-glucopyranoside
  参考文献：
  名称：

  WO2006/67883

  摘要：

  公开号：