| 1430799-50-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• CAS: 1430799-50-0
• 化学式: C₁₀₉H₁₀₆P₄Pt₂Si
• 分子量: 1958.18
• InChiKey: UGKZILQKXREHCY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 potassium carbonate 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 反应 2.0h， 生成 [[[[3-ethynyl-5-(pyren-1-ylethynyl)]phenyl]ethynyl]]-[[[3-[[bis(triethylphosphine)][3-(pyren-1-ylethynyl)-phenylethynyl]platinumethynyl]][5-(pyren-1-ylethynyl)]phenyl]ethynyl]bis(triethylphosphine)platinum
  参考文献：
  名称：

  Synthesis and characterization of multipyrene-modified platinum acetylide oligomers

  摘要：

  A series of new multipyrene-modified platinum acetylide oligomers were successfully synthesized utilizing the coupling reaction of trans-Pt complexes with C-H bonds in alkynes as the key step. These new conjugated oligomers were characterized by multinuclear NMR (H-1, C-13, and P-31) and mass spectrometry (MALDI-TOF-MS). Preliminary spectroscopic studies of these oligomers were also carried out.

  DOI：

  10.1007/s00706-012-0892-4
• 作为产物：
  描述：

  [[3-(pyren-1-ylethynyl)-5-[(trimethylsilyl)-ethynyl]phenyl]ethynyl]bis(triethylphosphine)-platinum(IV) iodide 、 [[3-ethynyl-5-(pyren-1-ylethynyl)phenyl]ethynyl]-[[3-(pyren-1-ylethynyl)phenyl]ethynyl]bis-(triethylphosphine)platinum 在 copper(l) iodide 、 二乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 1.5h， 生成
  参考文献：
  名称：

  Synthesis and characterization of multipyrene-modified platinum acetylide oligomers

  摘要：

  A series of new multipyrene-modified platinum acetylide oligomers were successfully synthesized utilizing the coupling reaction of trans-Pt complexes with C-H bonds in alkynes as the key step. These new conjugated oligomers were characterized by multinuclear NMR (H-1, C-13, and P-31) and mass spectrometry (MALDI-TOF-MS). Preliminary spectroscopic studies of these oligomers were also carried out.

  DOI：

  10.1007/s00706-012-0892-4