苯并[l]芘-8-醇 | 77508-25-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 中文名称: 苯并[l]芘-8-醇
• 英文名称: 1-Hydroxybenzopyrene
• 英文别名: Benzo(l)pyren-8-ol；benzo[l]pyren-8-ol
• CAS: 77508-25-9
• 化学式: C₂₀H₁₂O
• 分子量: 268.315
• InChiKey: PGZZCIZBXLTEGA-UHFFFAOYSA-N

物化性质

• 熔点：
  180-181 °C(Solv: benzene (71-43-2))
• 沸点：
  527.2±19.0 °C(Predicted)
• 密度：
  1.379±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  21
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3,6-Dibromobenzopyrene 在 正丁基锂 、 正己烷 、 氯 、 sodium hydride 、 乙硫醇 作用下， 以 六甲基磷酰三胺 、 乙醚 、 N,N-二甲基甲酰胺 为溶剂， 反应 24.33h， 生成 苯并[l]芘-8-醇
  参考文献：
  名称：

  Isomeric phenols of benzo[e]pyrene

  摘要：

  DOI：

  10.1021/jo00327a010

文献信息

• LEE H.; SHYAMASUNDAR N.; HARVEY R. G., J. ORG. CHEM., 1981, 46, NO 14, 2889-2895
  作者：LEE H.、 SHYAMASUNDAR N.、 HARVEY R. G.

  DOI：——

  日期：——
• PRODUCTION OF HIGHER QUALITY BIO-OILS BY IN-LINE ESTERIFICATION OF PYROLYSIS VAPOR
  申请人：Hilten Roger Norris

  公开号：US20110296745A1

  公开（公告）日：2011-12-08

  The disclosure encompasses in-line reactive condensation processes via vapor phase esterification of bio-oil to decease reactive species concentration and water content in the oily phase of a two-phase oil, thereby increasing storage stability and heating value. Esterification of the bio-oil vapor occurs via the vapor phase contact and subsequent reaction of organic acids with ethanol during condensation results in the production of water and esters. The pyrolysis oil product can have an increased ester content and an increased stability when compared to a condensed pyrolysis oil product not treated with an atomized alcohol.
• US8900416B2
  申请人：——

  公开号：US8900416B2

  公开（公告）日：2014-12-02
• [EN] PRODUCTION OF HIGHER QUALITY BIO-OILS BY IN-LINE ESTERIFICATION OF PYROLYSIS VAPOR<br/>[FR] PRODUCTION DE BIO-HUILES DE QUALITÉ SUPÉRIEURE PAR ESTÉRIFICATION EN LIGNE DE VAPEUR DE PYROLYSE
  申请人：UNIV GEORGIA

  公开号：WO2010099058A2

  公开（公告）日：2010-09-02

  The disclosure encompasses in-line reactive condensation processes via vapor phase esterification of bio-oil to decease reactive species concentration and water content in the oily phase of a two-phase oil, thereby increasing storage stability and heating value. Esterification of the bio-oil vapor occurs via the vapor phase contact and subsequent reaction of organic acids with ethanol during condensation results in the production of water and esters. The pyrolysis oil product can have an increased ester content and an increased stability when compared to a condensed pyrolysis oil product not treated with an atomized alcohol.
• Isomeric phenols of benzo[e]pyrene
  作者：Hongmee Lee、N. Shyamasundar、Ronald G. Harvey

  DOI：10.1021/jo00327a010

  日期：1981.7