[[3-ethynyl-5-(pyren-1-ylethynyl)phenyl]ethynyl]-[[3-(pyren-1-ylethynyl)phenyl]ethynyl]bis-(triethylphosphine)platinum | 1430799-48-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: [[3-ethynyl-5-(pyren-1-ylethynyl)phenyl]ethynyl]-[[3-(pyren-1-ylethynyl)phenyl]ethynyl]bis-(triethylphosphine)platinum
• CAS: 1430799-48-6
• 化学式: C₆₆H₅₆P₂Pt
• 分子量: 1106.2
• InChiKey: CCMWQGPXIJACSL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  trans diiodobis(triethylphosphine)platinum(II) 、 [[3-ethynyl-5-(pyren-1-ylethynyl)phenyl]ethynyl]-[[3-(pyren-1-ylethynyl)phenyl]ethynyl]bis-(triethylphosphine)platinum 在 copper(l) iodide 、 二异丙胺 作用下， 以 四氢呋喃 为溶剂， 反应 2.0h， 以70%的产率得到[[[3-[[bis(triethylphosphine)][3-(pyren-1-ylethynyl)-phenylethynyl]platinumethynyl]][5-(pyren-1-ylethynyl)]-phenyl]ethynyl]bis(triethylphosphine)platinumiodide
  参考文献：
  名称：

  Synthesis and characterization of multipyrene-modified platinum acetylide oligomers

  摘要：

  A series of new multipyrene-modified platinum acetylide oligomers were successfully synthesized utilizing the coupling reaction of trans-Pt complexes with C-H bonds in alkynes as the key step. These new conjugated oligomers were characterized by multinuclear NMR (H-1, C-13, and P-31) and mass spectrometry (MALDI-TOF-MS). Preliminary spectroscopic studies of these oligomers were also carried out.

  DOI：

  10.1007/s00706-012-0892-4
• 作为产物：
  描述：

  1,3,5-三溴苯 在 copper(l) iodide 、 四(三苯基膦)钯 、 potassium carbonate 、 二乙胺 、 三乙胺 、 二异丙胺 、 sodium hydroxide 作用下， 以 四氢呋喃 、 甲醇 、 甲苯 为溶剂， 反应 42.0h， 生成 [[3-ethynyl-5-(pyren-1-ylethynyl)phenyl]ethynyl]-[[3-(pyren-1-ylethynyl)phenyl]ethynyl]bis-(triethylphosphine)platinum
  参考文献：
  名称：

  Synthesis and characterization of multipyrene-modified platinum acetylide oligomers

  摘要：

  A series of new multipyrene-modified platinum acetylide oligomers were successfully synthesized utilizing the coupling reaction of trans-Pt complexes with C-H bonds in alkynes as the key step. These new conjugated oligomers were characterized by multinuclear NMR (H-1, C-13, and P-31) and mass spectrometry (MALDI-TOF-MS). Preliminary spectroscopic studies of these oligomers were also carried out.

  DOI：

  10.1007/s00706-012-0892-4