6,6-Dimethoxy-undecane | 145070-63-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 6,6-Dimethoxy-undecane
• 英文别名: 6,6-Dimethoxyundecane
• CAS: 145070-63-9
• 化学式: C₁₃H₂₈O₂
• 分子量: 216.364
• InChiKey: BGQUZIUNBMLCRL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  15
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  6,6-Dimethoxy-undecane 在 硫化氢 、 zinc(II) chloride 作用下， 以 乙醇 为溶剂， 以54%的产率得到Undecane-6-thione
  参考文献：
  名称：

  烯硫醇的选择性合成

  摘要：

  通过在氯化锌存在下用硫化氢处理二甲基乙缩醛来制备互变异构纯的脂族硫酮3。用LDA去质子化得到Z-烯硫醇盐4，其被三甲基甲硅烷基氯S-甲硅烷基化以得到甲硅烷基乙烯基硫化物5。甲醇5定量提供烯硫醇1，没有异构的硫代酮3。

  DOI：

  10.1016/s0040-4039(00)60029-1

文献信息

• SOLID CATALYST FOR OLEFIN POLYMERIZATION AND PROCESS FOR PRODUCING OLEFIN POLYMER
  申请人：Sumitomo Chemical Company, Limited

  公开号：US20130072648A1

  公开（公告）日：2013-03-21

  A solid catalyst for olefin polymerization and a process for producing an olefin polymer are provided. The polymer has a small content of a component which is dissolved out into a low temperature organic solvent, such as a low-molecular weight component and an amorphous component. The solid catalyst is obtained by bringing a solid catalyst component for olefin polymerization containing a titanium atom, a magnesium atom, a halogen atom, and an aliphatic carboxylate; an organoaluminum compound; and a compound represented by formula (I) into contact with each other: wherein R 1 is a hydrocarbyl group having 1 to 10 carbon atoms, R 2 is a hydrogen atom, a halogen atom or a hydrocarbyl group having 1 to 16 carbon atoms, and the R 1 the R 2 groups are independently the same or different, and the respective R 1 groups and R 2 groups may be joined with each other to form a ring.