oxacyclopentadecane | 295-50-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: oxacyclopentadecane
• 英文别名: Oxacyclopentadecan
• CAS: 295-50-1
• 化学式: C₁₄H₂₈O
• 分子量: 212.376
• InChiKey: OQHZUKSDGKGPOT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1,14-十四烷二醇 在 sodium 、 甲苯 、 苯 作用下， 生成 oxacyclopentadecane
  参考文献：
  名称：

  Vielgliedrige heterocyclische Verbindungen。九。Vielgliedrige Cyclische Oxyde and Oxidoketone

  摘要：

  DOI：

  10.1002/hlca.193601901105

文献信息

• Two-component industrial maintenance resin coating systems and compositions and coating processes using them
  申请人：CELANESE CORPORATION

  公开号：EP0024915A1

  公开（公告）日：1981-03-11

  The present invention is directed to a two-component industrial maintenance coating system. The first component comprises a polyamine terminated epoxy resin which is end capped with specifically defined monoepoxides. A co-solvent is optionally employed in the first component where the end capped adduct is a solid at room temperature. The second component comprises a low molecular weight polyepoxide resin crosslinker and optionally a diluent when the epoxy crosslinker is very viscous or solid at room temperature. Before the two components are mixed together the end capped adduct is converted to its water soluble or water dispersable salt form by reaction with a volatile acid to achieve a certain degree of salting. When the two components are mixed together the epoxide resin crosslinker is microemulsified. The composition which results upon mixing the components is curable at room temperature and exhibits an excellent balance of chemical and physical properties.

  本发明涉及一种双组分工业维护涂料体系。第一组份由端封有特定单环氧化物的多胺端封环氧树脂组成。第一组份中可选择使用助溶剂，其中端封端加合物在室温下为固体。第二组份包括低分子量的聚环氧树脂交联剂，当环氧树脂交联剂在室温下非常粘稠或呈固态时，可选择使用稀释剂。在将两种成分混合在一起之前，通过与挥发性酸反应，将端封加成物转化为水溶性或水分散性盐形式，以达到一定的盐化程度。当两种成分混合在一起时，环氧树脂交联剂被微乳化。混合后的组合物可在室温下固化，并具有出色的化学和物理性能平衡。
• Novolac based epoxy resin curing agents for use in aqueous systems
  申请人：INTEREZ, Inc. (a Georgia corporation)

  公开号：EP0175588A2

  公开（公告）日：1986-03-26

  The instant invention is an epoxy resin curing agent based upon an epoxy novolac containing, on the average, between about and 7.5 epoxy groups per molecule, in which substantially all of the epoxide groups are reacted with a polyamine wherein each primary amine hydrogen in the resulting reaction product is further reacted with a monoepoxide or a monocarboxylic acid. The resulting epoxy resin curing agent may be used in a water based system for curing epoxide resins. The curing agent is rendered water soluble or water dispersible by salting with a conventional volatile monocarboxylic acid such as acetic, formic or propionic acid.

  本发明是一种环氧树脂固化剂，基于平均每分子含有约至 7.5 个环氧基团的环氧酚醛， 其中基本上所有的环氧基团都与多胺反应，而反应产物中的每个伯胺氢进一步与一元环氧 物或一元羧酸反应。生成的环氧树脂固化剂可用于固化环氧树脂的水基体系中。通过与常规挥发性单羧酸（如乙酸、甲酸或丙酸）进行盐析，可使固化剂具有水溶性或水分散性。
• Novolac based epoxy resin curing agents for use in solvent
  申请人：INTEREZ, Inc. (a Georgia corporation)

  公开号：EP0175589A2

  公开（公告）日：1986-03-26

  The instant invention is an epoxy resin curing agent based upon an epoxy novolac containing, on the average, between about 3 and about 7.5 epoxy groups per molecule, in which substantially all of the epoxide groups are reacted with a polyamine wherein each primary amine hydrogen in the resulting reaction product is further reacted with a monoepoxide. The resulting epoxy resin curing agent may be used in a solvent based system to cure epoxy resins under low temperature curing conditions.

  本发明是一种环氧树脂固化剂，基于平均每个分子含有约 3 至约 7.5 个环氧基团的环氧酚醛，其中基本上所有的环氧基团都与多胺反应，在反应生成物中的每个伯胺氢进一步与单环氧化物反应。 所生成的环氧树脂固化剂可用于溶剂型体系，在低温固化条件下固化环氧树脂。
• Ink-jet printing media containing macrocyclic polyethers
  申请人：Hewlett-Packard Company

  公开号：EP0237788A2

  公开（公告）日：1987-09-23

  An improved ink suitable for use in ink-jet printers is provided. The ink includes (a) a vehicle comprising at least one member selected from the group consisting of water and a non-aqueous component and (b) an anionic dye having cations associated therewith. The ink composition is characterized by further including a macrocyclic poly­ether associated with the cations, the macrocyclic poly­ether having binding sites and a cavity size suitable for complexing the cations. The ink composition of the inven­tion evidences reduced crusting, increased fade resistance and, for use in thermal ink-jet printers, reduced koga­tion.

  本文提供了一种适用于喷墨打印机的改进型墨水。该墨水包括：(a) 由至少一种选自由水和非水性成分组成的组中的成员构成的载体；(b) 具有与之相关的阳离子的阴离子染料。该墨水组合物的特点是进一步包括与阳离子相关联的大环聚醚，大环聚醚具有适合与阳离子络合的结合位点和空腔尺寸。本发明的墨水组合物减少了结皮现象，提高了抗褪色性，在热喷墨打印机中使用时，减少了磕碰现象。
• HEAT-STORAGE MATERIAL, COMPOSITION THEREFOR, AND USES OF THESE
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：EP1577362A1

  公开（公告）日：2005-09-21

  A heat-accumulative material which is a polymer or oligomer having, as a main constituent component, units having a polyether main chain and a side chain, side chains capable of being crystallized, and heat-accumulative composition comprising the same heat-accumulative material. The heat-accumulative material tends to be kept at a constant temperature more effectively by absorbing heat as ambient temperature increases to melt, and releasing heat as ambient temperature decreases to solidify, to moderate changes in ambient temperature, and thereby to exhibit the function as a heat-accumulative material. They have a sufficiently high viscosity, preventing the heat-accumulative material from flowing out even when it is molten. Each of the heat-accumulative material and composition can be made into a heat-accumulative film or sheet, laminate, molded article, composite fiber and cloth which can be suitably used around a body.

  一种蓄热材料，它是一种聚合物或低聚物，其主要成分是具有聚醚主链和侧链（侧链能够结晶）的单元，以及由相同蓄热材料组成的蓄热组合物。蓄热材料在环境温度升高时吸收热量而熔化，在环境温度降低时释放热量而凝固，从而更有效地保持恒温，以缓和环境温度的变化，从而发挥蓄热材料的功能。它们具有足够高的粘度，即使在熔化时也能防止蓄热材料流出。每种蓄热材料和组合物都可以制成蓄热薄膜或薄片、层压板、模制件、复合纤维和布，可在人体周围适当使用。