(2S,3aR,5R,6S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-6-hydroxy-2-methyl-tetrahydro-furo[2,3-d][1,3]dioxole-2-carboxylic acid methyl ester | 121018-05-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (2S,3aR,5R,6S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-6-hydroxy-2-methyl-tetrahydro-furo[2,3-d][1,3]dioxole-2-carboxylic acid methyl ester
• 英文别名: methyl (2S,3aR,5R,6S,6aR)-5-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-6-hydroxy-2-methyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxole-2-carboxylate
• CAS: 121018-05-1
• 化学式: C₁₃H₂₀O₈
• 分子量: 304.297
• InChiKey: YJJVMGAXERPHJV-OZHGGOSRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.5
• 重原子数：
  21
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  92.7
• 氢给体数：
  1
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  (2S,3aR,5R,6S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-6-hydroxy-2-methyl-tetrahydro-furo[2,3-d][1,3]dioxole-2-carboxylic acid methyl ester 生成 methyl (2S,3aR,5S,6S,6aR)-5-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2-methyl-6-trityloxy-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxole-2-carboxylate
  参考文献：
  名称：

  BAKINOVSKIJ, L. V.;NEPOGODEV, S. A.;KOCHETKOV, N. K., BIOORGAN. XIMIYA, 14,(1988) N 9, S. 1234-1241

  摘要：

  DOI：
• 作为产物：
  描述：

  methyl (2S,3aR,5R,6S,6aR)-5-[(1R)-1,2-dihydroxyethyl]-6-hydroxy-2-methyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxole-2-carboxylate 生成 (2S,3aR,5R,6S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-6-hydroxy-2-methyl-tetrahydro-furo[2,3-d][1,3]dioxole-2-carboxylic acid methyl ester
  参考文献：
  名称：

  BAKINOVSKIJ, L. V.;NEPOGODEV, S. A.;KOCHETKOV, N. K., BIOORGAN. XIMIYA, 14,(1988) N 9, S. 1234-1241

  摘要：

  DOI：

文献信息

• NEPOGODEV, S. A.;BAKINOVSKIJ, L. V.;KOCHETKOV, N. K., BIOORGAN. XIMIYA, 15,(1989) N1, S. 1555-1560
  作者：NEPOGODEV, S. A.、BAKINOVSKIJ, L. V.、KOCHETKOV, N. K.

  DOI：——

  日期：——
• Synthesis of (1?5)-?-d-galactofuranan and cyclo[(1?5)-?-d-galactofurano]oligosaccharides
  作者：S. A. Nepogod'ev、L. V. Backinowsky、N. K. Kochetkov

  DOI：10.1007/bf00699946

  日期：1993.8

  Synthesis of a linear (1-->5)-beta-D-galactofuranan was accomplished by trityl-cyanoethylidene polycondensation. On 10-fold reduction in the monomer concentration, the condensation products are cyclic oligosaccharides; the formation of 1,5-anhydro-alpha-D-galactofuranose was also demonstrated.
• Synthesis of cyclo-[(1-6)-β-D-galactofura no-oligosaccharides
  作者：N.K. Kochetkov、S.A. Nepogod'ev、L.V. Backinowsky

  DOI：10.1016/s0040-4020(01)97589-1

  日期：1990.1