2-ethyldecanal | 19009-58-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-ethyldecanal
• 英文别名: 2-Ethyl decanal
• CAS: 19009-58-6
• 化学式: C₁₂H₂₄O
• 分子量: 184.322
• InChiKey: KYUSUAYEKINLQX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  13
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-十一烯 生成 2-ethyldecanal
  参考文献：
  名称：

  OSWALD, ALEXIS A.;BHATIA, RAM N.

  摘要：

  DOI：

文献信息

• [EN] MORPHOLINE-SPIROCYCLIC PIPERIDINE AMIDES AS MODULATORS OF ION CHANNELS<br/>[FR] AMIDES DE PIPÉRIDINE SPIROCYCLIQUES MORPHOLINES UTILISÉS EN TANT QUE MODULATEURS DE CANAUX IONIQUES
  申请人：VERTEX PHARMA

  公开号：WO2012125613A1

  公开（公告）日：2012-09-20

  The invention relates to morpholine spirocyclic piperidine amide compounds useful as inhibitors of ion channels. The invention also provides pharmaceutically acceptable compositions comprising the compounds of the invention and methods of using the compositions in the treatment of various disorders.

  这项发明涉及吗啡啶螺环哌啶酰胺化合物，可用作离子通道抑制剂。该发明还提供了包括该发明化合物的药用可接受组合物，以及使用这些组合物治疗各种疾病的方法。
• Highly dispersed potassium on alumina as a metalating agent. Alkylation of enolizable compounds
  作者：Diego Savoia、Emilio Tagliavini、Claudio Trombini、Achille Umani-Ronchi

  DOI：10.1016/s0022-328x(00)80496-9

  日期：1981.1

  Highly dispersed potassium on alumina (K/Al2O3) acts as a metalating agent towards enolizable compounds and the intermediate organopotassium derivatives can be alkylated with primary alkyl bromides. The reaction conditions are dependent on the substrate. In particular, tetrahydrofuran is the solvent of choice for the metalation of nitriles and aldehydeN,N-dimethylhydrazones at −60°C and of N-cyclohexyl

  氧化铝上高度分散的钾（K / Al 2 O 3）作为可烯醇化化合物的金属化剂，中间有机钾衍生物可以用伯烷基溴化物烷基化。反应条件取决于底物。特别地，四氢呋喃是在-60℃下腈和醛N，N-二甲基hydr和N-环己基酮亚胺在室温下金属化的选择的溶剂，而己烷必须用于酮。
• Highly selective and recyclable homogeneous hydroformylation of olefins with [Rh(cod)Cl]2/PPh3 regulated by Et3N as additive
  作者：Peng Wang、Huibing Shi、Baolin Feng、Deming Zhao、Da Yang

  DOI：10.1016/j.mcat.2023.113459

  日期：2023.9

  improved (up to 99%), the applicability for the synthesis of important aldehydes was wider in the absence of solvent. More importantly, the catalytic system could be recycled more than 7 times through vacuum distillation operation and provided a new synthesis method for the pesticide dinotefuran (Tetrahydrofuran-3-formaldehyde) and perfume (Lily aldehyde) intermediates.

  在三乙胺（Et 3 N）作为添加剂的存在下，在合成气气氛下进行Rh催化的不同烯烃向相应醛的加氢甲酰化。研究了各种反应参数（包括膦配体、溶剂、添加剂）的影响。结果发现，通过在[Rh(cod)Cl] 2 /PPh 3中加入Et 3 N作为添加剂，催化体系，底物的转化率（包括环烯烃、内烯烃和直链烯烃，高达99%）和产物的化学/区域选择性得到提高（高达99%），在没有催化剂的情况下合成重要醛类的适用性更广泛溶剂。更重要的是，该催化体系通过减压蒸馏操作可循环使用7次以上，为农药呋虫胺（四氢呋喃-3-甲醛）和香料（百合醛）中间体的合成提供了新的方法。
• Transition metal complex catalyst for the carbonylation of epoxide derivatives
  申请人：Samsung Electronics Co., Ltd.

  公开号：EP1034842A2

  公开（公告）日：2000-09-13

  The present invention relates to a process for carbonylation of epoxide derivatives, in which the reactivity, selectivity and the yield are superior. More specifically, the present invention relates to a process for hydroformylation of an epoxide derivative in which there is utilized a transition metal catalyst having a cyclopentadienyl radical, thereby improving the reactivity and selectivity. Further, the present invention relates to a process for hydroesterification of an epoxide derivative, in which a proper catalyst is selected, and the reaction temperature and pressure are adjusted within proper ranges under the presence of a cobalt catalyst, thereby improving the product selectivity and the yield.

  本发明涉及一种环氧化物衍生物的羰基化工艺，在该工艺中，反应活性、选择性和产率都很高。更具体地说，本发明涉及一种环氧化物衍生物的加氢甲酰化工艺，其中使用了具有环戊二烯基的过渡金属催化剂，从而提高了反应性和选择性。此外，本发明还涉及一种环氧化物衍生物的氢酯化工艺，其中选择了适当的催化剂，并在钴催化剂存在的情况下将反应温度和压力调整在适当的范围内，从而提高了产品的选择性和产率。
• LIQUID DETERGENT COMPOSITION COMPRISING SUSPENDED SOLID PARTICLES
  申请人：Henkel AG & Co. KGaA

  公开号：EP3722407A1

  公开（公告）日：2020-10-14

  Liquid detergent composition comprising (a) a continuous liquid phase that is transparent or translucent; and (b) solid particles, wherein said particles (b1) are made of a polymeric matrix material; (b2) are dispersed in the continuous liquid phase; (b3) have a diameter in the range of about 0.8 to about 8 mm, preferably 1.0 to 2.5 mm; and (b4) comprise a plurality of microcapsules with a diameter in the range of from about 4 to about 70 |jm dispersed in the polymeric matrix material. Use of the liquid detergent for the cleaning of textiles. Method for the cleaning of textiles, comprising contacting the textiles with an aqueous solution of the liquid detergent composition.

  液体洗涤剂组合物，包括 (a) 透明或半透明的连续液相；和 (b) 固体颗粒，其中所述颗粒 (b1) 由聚合物基质材料制成； (b2) 分散在连续液相中； (b3) 直径范围约为 0.8 至 8 毫米，最好为 1.0 至 2.5 毫米；以及 (b4) 包括分散在聚合物基质材料中的多个微胶囊，其直径在约 4 至约 70 |jm 的范围内。 液体洗涤剂用于清洁纺织品。 清洁纺织品的方法，包括将纺织品与液体洗涤剂组合物的水溶液接触。