2-甲基-1,8-辛二醛 | 30157-60-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 2-甲基-1,8-辛二醛
• 中文别名: 2-甲基辛二醛
• 英文名称: 2-methyl-1,8-octanedial
• 英文别名: 2-methyloctanedial
• CAS: 30157-60-9
• 化学式: C₉H₁₆O₂
• 分子量: 156.225
• InChiKey: GROOSSLNHYKEFI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  11
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-甲基-1,8-辛二醛 、 聚合甲醛 生成 2-(Hydroxymethyl)-2-methyloctane-1,8-diol
  参考文献：
  名称：

  OMATSU, TOSIXIRO;TOKITADA, YASUO;IOSIMURA, NORIAKI

  摘要：

  DOI：
• 作为产物：
  描述：

  7-辛烯醛 生成 2-甲基-1,8-辛二醛
  参考文献：
  名称：

  OMATSU, TOSIXIRO;TOKITO, YASUO;JOSIMURA, NORIAKI

  摘要：

  DOI：

文献信息

• Lithium rho-diarylphosphinobenzenesulfonates, process for preparation of the same and use thereof
  申请人：——

  公开号：US20040249195A1

  公开（公告）日：2004-12-09

  Lithium p-diarylphosphinobenzenesulfonates represented by the general formula (I) 1 wherein R 1 and R 2 are each optionally substituted aryl; a process for preparing the same; a group VIII metal complex comprising a group VIII metal compound and the above lithium p-diarylphosphinobenzenesulfonate coordinating thereto and a process for hydroformylation with the complex. Hydroformylation with the complex permits easy and industrially advantageous production of aldehydes.

  本发明涉及一般式(I)1所表示的磷酸苯磺酸二芳基锂，其中R1和R2分别是可选取代的芳基; 一种制备它们的方法; 一种包括羰基化反应配位到上述锂磷酸苯磺酸二芳基的群 VIII 金属化合物的群 VIII 金属配合物，以及使用该配合物进行羰基化反应的方法。使用该配合物进行羰基化反应可轻松地、具有工业优势地生产醛类。
• Process for producing 1,9-nonanedial
  申请人：Kuraray Company, Ltd.

  公开号：US04510332A1

  公开（公告）日：1985-04-09

  A process for producing 1,9-nonanedial which comprises hydroformylating 7-octen-1-al with a mixture of hydrogen and carbon monoxide in an aqueous sulfolane or 1,4-butanediol solution in the presence of a rhodium complex and the sodium, potassium or lithium salt of m-(diphenylphosphino)benzenesulfonic acid, extracting 1,9-nonanedial from the reaction mixture with a primary alcohol or a mixture of a primary alcohol and a saturated aliphatic hydrocarbon, and recycling the extraction residue containing the catalyst components to the 7-octen-1-al hydroformylation step.

  一种制备1,9-壬二醛的方法，包括在水合硫酮或1,4-丁二醇溶液中，在钯配合物和m-(二苯基膦基)苯磺酸钠、钾或锂盐的存在下，用氢气和一氧化碳的混合物对7-辛烯-1-醛进行氢甲酰化反应，用一种一级醇或一种一级醇和饱和脂肪族烃的混合物从反应混合物中提取1,9-壬二醛，并将含有催化剂成分的萃取残渣回收到7-辛烯-1-醛氢甲酰化步骤。
• PROCESS FOR THE REDUCTIVE AMINATION OF ALDEHYDES AND KETONES
  申请人：Molitor Erich J.

  公开号：US20080167499A1

  公开（公告）日：2008-07-10

  Aldehyde or ketone compounds having more than one carbonyl group are reductively aminated to form a product amine compound having more than one primary amino group. The aldehyde or ketone compound is reacted with the product amine compound in the presence of an alcohol solvent, to form a reaction mixture that contains one or more intermediates. The intermediate is then reductively aminated to form the desired product. This process may produce the desired product in very high yields with low levels of secondary amine impurities.

  具有多个羰基基团的醛或酮化合物通过还原胺化反应形成具有多个一级氨基团的产物胺化合物。在醇溶剂存在下，将醛或酮化合物与产物胺化合物反应，形成含有一个或多个中间体的反应混合物。然后，将中间体还原胺化反应形成所需的产物。该过程可产生高收率且含有低水平的二级胺杂质的所需产物。
• METHOD FOR PRODUCING DIALDEHYDE
  申请人：KURARAY CO., LTD.

  公开号：US20160052852A1

  公开（公告）日：2016-02-25

  Provided is an industrially advantageous method for producing a dialdehyde having a production ratio of linear dialdehydes to branched dialdehydes of 80/20 to 90/10, with an amount of rhodium to be used that is lower than that in the related art. Specifically, provided is a method for producing a dialdehyde, including reacting a linear olefinic compound having each of an ethylenic double bond and an aldehyde group on each end of the molecule with carbon monoxide and hydrogen, in the presence of a rhodium catalyst comprised of a bisphosphite represented by General Formula (I) and a rhodium compound, in which the reaction pressure of a mixed gas formed of carbon monoxide and hydrogen is decreased as the reaction proceeds, wherein R represents a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, or an alkoxy group having 1 to 4 carbon atoms, and W represents an alkylene group having 1 to 20 carbon atoms, a cycloalkylene group having 5 to 18 carbon atoms, or an alkylene-arylene group having 7 to 11 carbon atoms, and a rhodium compound.

  本发明提供了一种工业上有利的制备双醛的方法，其线性双醛与支链双醛的生产比为80/20到90/10，所需铑的量比相关技术低。具体而言，本发明提供了一种制备双醛的方法，包括在存在由一般式（I）表示的双膦酸酯和铑化合物组成的铑催化剂的条件下，将具有分子两端乙烯双键和醛基的线性烯烃化合物与一氧化碳和氢反应，其中反应压力随着反应的进行而降低，其中R代表氢原子、具有1至4个碳原子的烷基或具有1至4个碳原子的烷氧基，W代表具有1至20个碳原子的烷基、具有5至18个碳原子的环烷基或具有7至11个碳原子的烷基-芳基基团，以及铑化合物。
• Method of producing 1,9-nonanedial and/or 9-hydroxy-7-nonen-1-al
  申请人：KURARAY CO., LTD.

  公开号：EP0064285A1

  公开（公告）日：1982-11-10

  There is disclosed a method of producing 1,9-nonanedial and/or 9-hydroxy-7-nonen-1-al which comprises reacting 2,7-octadien-1-ol with a mixture of hydrogen and carbon monoxide in an organic solvent in the presence of a rhodium catalyst and a monodentate tertiary organic phosphorus compound in an amount of 30-300 equivalents per gram atom of rhodium at a hydrogen partial pressure of 0.5-20 kg/cm2 (absolute) and a carbon monoxide partial pressure of 0.1-5.0 kg/cm2 (absolute).

  本发明公开了一种生产 1，9-壬二烯醛和/或 9-羟基-7-壬烯-1-醛的方法，该 方法包括在铑催化剂和单阳离子叔有机磷化合物的存在下，在有机溶剂中使 2，7-辛二 烯-1-醇与氢气和一氧化碳的混合物反应，铑催化剂的用量为每克铑原子 30-300 当量，氢 分压为 0.5-20千克/平方厘米（绝对值）和一氧化碳分压为0.1-5.0千克/平方厘米（绝对值）。