4-acryloyloxyphenyl 2-acryloyloxy-2-propyl ketone | 110538-17-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4-acryloyloxyphenyl 2-acryloyloxy-2-propyl ketone
• 英文别名: [4-(2-Methyl-2-prop-2-enoyloxypropanoyl)phenyl] prop-2-enoate
• CAS: 110538-17-5
• 化学式: C₁₆H₁₆O₅
• 分子量: 288.3
• InChiKey: LRRWMFCRRKTOOZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  21
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  69.7
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  2-hydroxy-1-(4-hydroxyphenyl)-2-methylpropan-1-one 、 丙烯酰氯 在 三乙胺 作用下， 以 1,4-二氧六环 为溶剂， 生成 4-acryloyloxyphenyl 2-acryloyloxy-2-propyl ketone
  参考文献：
  名称：

  Copolymerizable photoinitiators

  摘要：

  本发明涉及一般式I的共聚光引发剂，其中R.sup.1和R.sup.2分别为H、C.sub.1-C.sub.6烷基或苯基，R.sup.3为H、C.sub.1-C.sub.6烷基、C.sub.1-C.sub.6烷基、C.sub.1-C.sub.6酰基或基团Z，R.sup.4为H、卤素、C.sub.1-C.sub.12烷基、C.sub.1-C.sub.12烷氧基、C.sub.1-C.sub.12烷硫基或基团--X[(CH.sub.2--CH.sub.2--O).sub.n--Z].sub.m，其中X为O、S或N，n为0至4的整数，m为X=O和S时为整数1，X=N时为整数1或2，Z为--CO--CR.dbd.CR'R"基团，其中R、R'、R"分别为H或CH.sub.3，始终至少一个R.sup.3或R.sup.4基团含有Z基团。

  公开号：

  US04922004A1

文献信息

• Liquid crystal display device and method for manufacturing the same
  申请人：Samsung Display Co., Ltd.

  公开号：US10578925B2

  公开（公告）日：2020-03-03

  A liquid crystal display device includes a first substrate, a first alignment film disposed on the first substrate, a second substrate, and a liquid crystal layer disposed between the first alignment film and the second substrate. The first substrate has a surface curved in a first direction and the second substrate has a surface curved in the first direction. The first alignment film includes a polymerization initiator and a polymer chain that is a copolymer of a dianhydride-based compound and a diamine-based compound. The polymer chain includes a main chain including a repeating unit including an imide group, a first side chain, including a vertical align group, bonded to the main chain, and a second side chain bonded to the main chain. The functional group includes a biphenyl group or a terphenyl group.

  液晶显示装置包括第一基板、设置在第一基板上的第一对准膜、第二基板以及设置在第一对准膜和第二基板之间的液晶层。第一基板的表面沿第一方向弯曲，第二基板的表面沿第一方向弯曲。第一配向膜包括聚合引发剂和聚合物链，聚合物链是二酐基化合物和二胺基化合物的共聚物。聚合物链包括一条主链，主链上有一个包括酰亚胺基团的重复单元；一条第一侧链，包括一个与主链结合的垂直排列基团；以及一条与主链结合的第二侧链。官能团包括联苯基团或三联苯基团。
• ACRYLIC PRESSURE-SENSITIVE ADHESIVE COMPOSITION FOR POLARIZING PLATE, CONTAINING A PHOTO-INITIATOR GROUP
  申请人：LG Chem, Ltd.

  公开号：EP2087060B1

  公开（公告）日：2015-08-26
• ACRYLIC PRESSURE-SENSITIVE ADHESIVE COMPOSITION FOR POLARIZING PLATE,CONTAINING A PHOTO-INITIATOR GROUP
  申请人：Kim No-Ma

  公开号：US20100129568A1

  公开（公告）日：2010-05-27

  The present invention relates to an acrylic pressure-sensitive adhesive composition which comprises a (meth)acrylic copolymer comprising an alkyl(meth)acrylic acid ester monomer, in which alkyl has 2 to 14 carbon atoms, and a (meth)acrylic acid ester monomer containing a copolymerizable photo-initiator group, wherein it has a gel fraction of 10 to 55% and a swelling ratio of 30 to 110, and a sol (uncross-linked polymer) eluted in final pressure-sensitive adhesive with a solvent (ethyl acetate) has a weight average molecular weight of 600,000 or more; and a polarizing plate and a liquid crystal display device, comprising the same. The polarizing plate according to the present invention has an excellent adhesion durability under a high temperature or a high temperature and humidity condition, has an excellent low light leakage property by effectively providing stress release property, and may greatly improve productivity for polarizing plates, by using photo-curing.
• LIQUID CRYSTAL DISPLAY DEVICE AND METHOD FOR MANUFACTURING THE SAME
  申请人：Samsung Display Co., Ltd.

  公开号：US20170139280A1

  公开（公告）日：2017-05-18

  A liquid crystal display device includes a first substrate, a first alignment film disposed on the first substrate, a second substrate, and a liquid crystal layer disposed between the first alignment film and the second substrate. The first substrate has a surface curved in a first direction and the second substrate has a surface curved in the first direction. The first alignment film includes a polymerization initiator and a polymer chain that is a copolymer of a dianhydride-based compound and a diamine-based compound. The polymer chain includes a main chain including a repeating unit including an imide group, a first side chain, including a vertical align group, bonded to the main chain, and a second side chain bonded to the main chain. The functional group includes a biphenyl group or a terphenyl group.
• LIQUID CRYSTAL DISPLAY AND METHOD OF MANUFACTURING THE SAME
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20170160593A1

  公开（公告）日：2017-06-08

  A liquid crystal display (LCD) includes a first substrate which has a first surface, a first alignment layer which is disposed on the first surface of the first substrate and includes a polymerization initiator, a photocurable layer which is formed on the first alignment layer and includes an azobenzene group, a second substrate which has a first surface facing the first substrate and a second surface located opposite the first surface thereof, a second alignment layer which is disposed on the first surface of the second substrate, and a liquid crystal layer which is interposed between the photocurable layer and the second alignment layer.