Deca-8-yl methacrylate | 936470-75-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Deca-8-yl methacrylate
• 英文别名: decan-3-yl 2-methylprop-2-enoate
• CAS: 936470-75-6
• 化学式: C₁₄H₂₆O₂
• 分子量: 226.35
• InChiKey: LJZJMIZQMNDARW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  16
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  氢气 、 Deca-8-yl methacrylate 、 decan-8-yl acrylate 、 、 、 二聚环戊二烯 以 水 为溶剂， 生成 羟基双环戊烯
  参考文献：
  名称：

  Sansevieria plant named ‘MARLOWE’

  摘要：

  一种新的、独特的、命名为“MARLOWE”的肉苁蓉栽培品种，其特征在于其具有不同绿色调的斑块状叶片和叶片背面上浅绿色的斑纹，在莲座上生长；植株高60-80厘米；直立的植株习性，对干旱具有很高的耐受性，需要少量的水，并且对草炭病（Colletotrichum sansevieriae）具有抗性。

  公开号：

  USPP034061P2
• 作为产物：
  描述：

  甲基丙烯酸 、 对甲苯磺酸 、 4-甲氧基苯酚 在 水 、 4-甲氧基苯酚 、 氢氧化钾 作用下， 以 水 为溶剂， 反应 2.0h， 以to give tricyclo[5.2.1.02,6 ]deca-8-yl methacrylate (的产率得到Deca-8-yl methacrylate
  参考文献：
  名称：

  Sansevieria plant named ‘MARLOWE’

  摘要：

  一种新的、独特的、命名为“MARLOWE”的肉苁蓉栽培品种，其特征在于其具有不同绿色调的斑块状叶片和叶片背面上浅绿色的斑纹，在莲座上生长；植株高60-80厘米；直立的植株习性，对干旱具有很高的耐受性，需要少量的水，并且对草炭病（Colletotrichum sansevieriae）具有抗性。

  公开号：

  USPP034061P2

文献信息

• Process for producing methacrylic acid esters
  申请人：Hitachi Chemical Company, Ltd.

  公开号：US05072027A1

  公开（公告）日：1991-12-10

  In a process for producing a methacrylic acid ester by subjecting methyl methacrylate and an alcohol to a transesterification reaction in the presence of a catalyst and a polymerization inhibitor, the filtration time of catalyst and the like can be shortened by making a total water content in the catalyst, alcohol and methyl methacrylate 1000 ppm or less, or the generation of large bubbles during the reaction can be prevented by adding the starting alcohol to the reaction system at the alcohol conversion of 40% or more, or high catalytic activity is obtained even if a secondary or tertiary alcohol is used as a starting material by using as a catalyst that obtained by drying lithium hydroxide monohydrate with heating, these effects being also obtained by combining individual conditions.

  通过在催化剂和聚合抑制剂的存在下，将甲基丙烯酸甲酯和醇进行酯交换反应，制备甲基丙烯酸酯的过程中，可以通过使催化剂和其他物质的总水含量在1000 ppm或以下来缩短催化剂的过滤时间，或者在醇转化率达到40%或以上时向反应体系中添加起始醇来防止反应过程中大气泡的产生，或者使用通过加热干燥氢氧化锂单水合物获得的催化剂即使使用二级或三级醇作为起始物料也可以获得高催化活性，这些效果也可以通过组合单个条件来获得。
• Polymers of tricyclo[5.2.1.0.sup.2,6 ]deca-8-yl (meth)acrylate
  申请人：Hitachi Chemical Company, Ltd.

  公开号：US04591626A1

  公开（公告）日：1986-05-27

  A polymer obtained by polymerizing tricyclo[5.2.1.0.sup.2,6 ]deca-8-yl acrylate or methacrylate in an amount of 100-5% by weight with one or more copolymerizable unsaturated monomers in an amount of 0 to 95% by weight is excellent in transparency, moisture resistance, and heat resistance and is suitable as a material for optical elements.

  通过将三环[5.2.1.0.sup.2,6]癸烯基丙烯酸酯或甲基丙烯酸酯在重量上占100-5％的情况下与一个或多个可共聚不饱和单体在重量上占0-95％聚合而成的聚合物在透明度、防潮性和耐热性方面表现出色，适用于光学元件材料。
• Plastic optical fiber
  申请人：HITACHI, LTD.

  公开号：EP0246613A2

  公开（公告）日：1987-11-25

  The plastic optical fiber of this invention has a core comprising a copolymer which comprises, as the essential constituents, a (meth)acrylic ester I represented by the following formula [I] wherein R₁ denotes hydrogen or methyl; a (meth)acrylic ester II represented by the following formula [II] wherein R2₂denotes hydrogen or methyl, and R₃ denotes C₁-C₈ alkyl, cycloalkyl, or aromatic group; and a multifunctional monomer. The core being formed by heat-curing of the thermosetting resin composition, it provides for a plastic optical fiber with an effect of excellency in the thermal resistance and the mechanical strength. Further, since a fibered polymer can be obtained without a drawing step according to this inven­tion, it gives also an effect of decreasing the light transmission loss caused by a drawing step for plastic optical fibers of the prior art.

  本发明的塑料光纤的芯部由共聚物组成，共聚物的基本成分包括由下式[I]表示的(甲基)丙烯酸酯 I；由下式[II]表示的(甲基)丙烯酸酯 II。 其中 R₁ 表示氢或甲基；由下式[II]表示的(甲基)丙烯酸酯 II 其中 R2₂ 表示氢或甲基，R₃ 表示 C₁-C₈ 烷基、环烷基或芳香基；以及一种多功能单体。通过热固性树脂组合物的热固化形成的纤芯，使塑料光纤具有优异的耐热性和机械强度。此外，由于根据本发明无需拉丝步骤即可获得纤维状聚合物，因此还可减少现有技术中塑料光纤因拉丝步骤而造成的光传输损失。
• Resin composition and compression-molded article of same
  申请人：Mitsubishi Chemical Corporation

  公开号：US10363724B2

  公开（公告）日：2019-07-30

  A resin composition including an epoxy resin (A), a curing agent (B), and vinyl polymer particles (C), in which the contained amount of epoxy resin (a1) having a molecular weight of 100-480 is 30-90 parts by mass per 100 parts by mass of the epoxy resin (A), the contained amount of epoxy resin (a2) having a molecular weight of 2,000-40,000 is 10-70 parts by mass per 100 parts by mass of the epoxy resin (A), the contained amount of the vinyl polymer particles (C) is 2-30 parts by mass per 100 parts by mass of the epoxy resin (A), and the instantaneous maximum thickening value of the vinyl polymer particles obtained by the following method is 0.3-5.0 Pa·s/° C.

  一种树脂组合物，包括环氧树脂 (A)、固化剂 (B) 和乙烯基聚合物颗粒 (C)，其中分子量为 100-480 的环氧树脂 (a1) 的含量为每 100 份环氧树脂 (A) 30-90 份；分子量为 2、000-40,000的环氧树脂(a2)的含量为每100份环氧树脂(A)10-70份(质量)，乙烯基聚合物颗粒(C)的含量为每100份环氧树脂(A)2-30份(质量)，通过以下方法获得的乙烯基聚合物颗粒的瞬时最大增稠值为0.3-5.0 Pa-s/° C。
• Radiation sensitive resin composition, cathode separator and el display device
  申请人：JSR CORPORATION

  公开号：US20020055059A1

  公开（公告）日：2002-05-09

  A radiation sensitive resin composition for the formation of cathode separators for EL display devices which have heat resistance and adhesion required for cathode separators for EL display devices and an inversely tapered shape, cathode separators formed therefrom and an EL display device comprising the cathode separators. The radiation sensitive resin composition for the formation of cathode separators for EL display devices comprises (A) an alkali soluble resin, (B) the compound represented by the formulae (I) to (IV) and (C) a trihalomethyltriazine and/or an onium salt, the cathode separators are formed from the radiation sensitive resin composition and the EL display device comprises the cathode separators formed from the radiation sensitive resin composition.

  一种用于形成电致发光显示装置阴极分离器的辐射敏感树脂组合物，该组合物具有电致发光显示装置阴极分离器所需的耐热性和粘附性，并具有反锥形，由其形成的阴极分离器和包括阴极分离器的电致发光显示装置。 用于形成电致发光显示装置阴极分离器的辐射敏感树脂组合物包括(A)碱溶性树脂，(B)式(I)至(IV)所代表的化合物和(C)三卤甲基三嗪和/或鎓盐，阴极分离器由辐射敏感树脂组合物形成，电致发光显示装置包括由辐射敏感树脂组合物形成的阴极分离器。