1,1-dimethylol-1-vinyloxymethylpropane | 15347-56-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,1-dimethylol-1-vinyloxymethylpropane
• 英文别名: TMP-monoallyl ether；TMP-ME；2-(Ethenoxymethyl)-2-ethylpropane-1,3-diol
• CAS: 15347-56-5
• 化学式: C₈H₁₆O₃
• 分子量: 160.213
• InChiKey: CYIPZJOFQPGQLJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  11
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  49.7
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1,1-dimethylol-1-vinyloxymethylpropane 、 碳酸二甲酯 在 sodium hydroxide 作用下， 反应 20.0h， 以32.6%的产率得到
  参考文献：
  名称：

  [EN] METHOD FOR PRODUCING CYCLIC CARBONATES
  [FR] PROCÉDÉ POUR PRODUIRE DES CARBONATES CYCLIQUES

  摘要：

  线性或环状碳酸酯作为异氰酸酯自由聚氨酯和聚碳酸酯的潜在单体，是由多元醇和二烷基碳酸酯或二苯碳酸酯制备的。这项发明旨在生产带有或不带有催化剂的线性或环状碳酸酯。多元醇化合物与碳酸酯（如二甲基碳酸酯和二乙基碳酸酯）反应，以产生相应的线性和/或环状碳酸酯。

  公开号：

  WO2012158107A1

文献信息

• [EN] PROCESS FOR PRODUCING ETHER COMPOUNDS IN PRESENCE OF A COPPER (II) SALT<br/>[FR] PROCEDE DE PRODUCTION DE COMPOSES D'ETHER EN PRESENCE D'UN SEL DE CUIVRE(II)
  申请人：SHOWA DENKO KK

  公开号：WO2003106024A1

  公开（公告）日：2003-12-24

  A process for producing allylic ether compounds in presence of a catalyst comprising at least one Cu(II) salt by reaction of an allylic alcohol with either itself or another alcohol.

  一种在至少含有一种Cu(II)盐催化剂存在下，通过将烯丙醇与自身或另一种醇反应制备烯丙醚化合物的方法。
• Process for producing polymer having crosslinkable silyl group and curable composition
  申请人：——

  公开号：US20040220364A1

  公开（公告）日：2004-11-04

  A process for producing a crosslinkable silyl group-containing polymer which is excellent in oil resistance, heat resistance, weatherability, low staining properties, and compression set characteristics, includes the steps of radically polymerizing a vinyl monomer in the presence of a thiocarbonylthio group-containing compound with a specific structure, and introducing crosslinkable silyl groups. Also provided is a curable composition which contains the polymer and which is easy to handle.

  一种生产含有交联硅基聚合物的方法，该聚合物具有优异的耐油性、耐热性、耐候性、低染色性和压缩永久变形特性，该方法包括在具有特定结构的硫代氨基羰基硫基化合物的存在下，自由基聚合乙烯单体，并引入可交联的硅基团。此外，还提供了一种易于处理的含有该聚合物的可固化组合物。
• Curable composition
  申请人：——

  公开号：US20040249026A1

  公开（公告）日：2004-12-09

  Provided is a curable composition which can easily regulate the properties of a cured object prepared therefrom, which can prepare a cured object that does not substantially discolor or soften a finishing agent or coating material applied to the surface thereof, and which has a high curing rate in the inner regions. The curable composition contains (A) a polymer having at least one mercapto group at the molecular ends, the polymer being derived from a thiocarbonylthio group-containing polymer (a2) prepared by polymerizing a monomer (a1) which contains an acrylic ester as a principal component and which contains 50% by weight or more of the acrylic ester and less than 50% by weight of a monomer copolymerizable with the acrylic ester in the presence of a thiocarbonylthio group-containing compound; (B) a compound having at least two mercapto groups per molecule; and (C) an oxidizing agent.

  提供了一种可治愈的组合物，可以轻松调节所制备的治愈物体的性质，可以制备出不会显着变色或软化表面上涂有精加工剂或涂层材料的治愈物体，并且具有内部区域高固化速率。可治愈组合物包含（A）一种聚合物，在分子末端具有至少一个巯基，该聚合物是由含有硫代羰基硫基的聚合物（a2）衍生而来，所述聚合物是通过在含有硫代羰基硫基化合物的存在下聚合含有丙烯酸酯为主要成分且含有50％或更多丙烯酸酯和少于50％与丙烯酸酯共聚的单体（a1）而制备的；（B）每个分子中至少有两个巯基的化合物；和（C）氧化剂。
• Fluorine-containing compounds and polymers derived therefrom
  申请人：——

  公开号：US20030109626A1

  公开（公告）日：2003-06-12

  Provided are fluorine-containing compounds, and polymers derived therefrom, for use in compositions used for treating textile substrates. Also provided are methods of making fluorine-containing compounds and polymers derived therefrom, compositions comprising the compounds and/or polymers of the present invention, methods of treating substrates, and the treated products derived therefrom.

  提供含氟化合物和由此衍生的聚合物，用于处理纺织物基材的组合物。还提供制备含氟化合物和由此衍生的聚合物的方法，包括本发明化合物和/或聚合物的组合物，处理基材的方法以及由此衍生的处理产品。
• Polyurethane polymer
  申请人：——

  公开号：US20040171765A1

  公开（公告）日：2004-09-02

  Provided is a polyurethane polymer which is excellent in oil resistance, weatherability, light resistance, heat resistance, hot water resistance, hydrolysis resistance, strength, chlorine resistance, and chemical resistance, and which can be produced simply and economically. The polyurethane polymer is produced by polymerizing at least two components: a vinyl polymer (A) having a mercapto group at each end of the molecular chain produced by a reversible addition-fragmentation chain transfer polymerization method, and an organic polyisocyanate (B). Also provided are polyurethane-based materials containing the polyurethane polymer, and polyurethane elastic fiber.

  提供了一种聚氨酯聚合物，具有优异的耐油性、耐候性、耐光性、耐热性、耐热水性、耐水解性、强度、耐氯性和耐化学性，可以简单经济地生产。该聚氨酯聚合物通过聚合至少两种组分制备：一种乙烯基聚合物(A)，其分子链的每端具有一个巯基，通过可逆加成-断裂链转移聚合方法制备，和一种有机多异氰酸酯(B)。还提供了含有该聚氨酯聚合物的聚氨酯基材料和聚氨酯弹性纤维。