1-benzylimidazol-2-yl(1-phenylaldimine) | 13750-77-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1-benzylimidazol-2-yl(1-phenylaldimine)
• 英文别名: 1-benzylimidazol-2-yl(1-phenyalldimine)；N-(1-benzyl-1H-imidazol-2-ylmethylene)-aniline；PhN=CHbim；1-benzyl-2-1-phenylaldiminoimidazole；(E)-1-(1-Benzyl-1H-imidazol-2-yl)-N-phenylmethanimine；1-(1-benzylimidazol-2-yl)-N-phenylmethanimine
• CAS: 13750-77-1
• 化学式: C₁₇H₁₅N₃
• 分子量: 261.326
• InChiKey: VTGGZTHWQWXYCA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  30.2
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  乙二醇二甲醚溴化镍 、 1-benzylimidazol-2-yl(1-phenylaldimine) 以 二氯甲烷 为溶剂， 以70%的产率得到dibromo[1-benzylimidazol-2-yl(1-phenylaldimine)]nickel(II)
  参考文献：
  名称：

  Synthesis of nickel(II) complexes containing neutral N,N− and anionic N,O− bidentate ligands, and their behaviour as chain-growth catalysts; structural characterisation of complexes containing (mim)2CO, , and mimCPh2O− (mim=1-methylimidazol-2-yl)

  摘要：

  The complexes NiBr2(L-2) [L-2 = (mim)(2)CO (7a), (bim)(2)CO (7b), py(mim)CO (8), PhN=CHbim (9)], NiBr(o-Tol){(mim)(2)CO) (10), Ni(L-2)(o-Tol)(PPh3) [L-2 = mimCO(2)(-) (11a), bmCO(2)(-)(11b), mimCPh(2)O(-) (12), mimC(6)H(4)O(-) (13)], and [Nif(MiM)2C0h1[BF412.0.25H,O (16) have been synthesised from nickel(II) salts (7-9, 16) or NiBr(o-Tol)(PPh3)(2) [10-13], where mim = 1-methylimidazol-2-yl, bim = 1-benzylimidazol-2-yl, and py = pyridin-2-yl. The square-planar complexes (11a, 12) and octahedral 16 have been characterised by X-ray diffraction studies, together with octahedral cis-[Ni(mim)(2)CO)(2)Br(OH2)](BrCD3CN)-C-. (14) and cis-[Ni{(mim)(2)CO}(2)(OH2)(2)Br(2)(.)3CD(3)CN (15). Preliminary catalytic studies have been undertaken with a number of the nickel complexes. Complexes 11-13 form single component catalysts for the oligomerization or polymerization of ethylene and the bromo-complexes (7-9) form active catalysts for the oligomerization or polymerization of ethylene when activated with MMAO. (c) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.06.069

文献信息

• Synthesis and Structures of the Ligands 1-Methylimidazol-2-yl(pyridin-2-yl)methanone {(py)(mim)CO} and 1-Benzylimidazol-2-yl(1-phenylaldimine) (PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes [Mo(CO)4(L2-N,N′)]
  作者：Michael P. Batten、Allan J. Canty、Kingsley J. Cavell、Brian W. Skelton、Allan H. White

  DOI：10.1002/zaac.200500531

  日期：2006.4

  The complexes [Mo(CO)4(L2-N,N')] [L2 = 1-methylimidazol- 2-yl(pyridin-2-yl)methanone and 1-benzylimidazol-2-yl(1- phenylaldimine)] have been synthesized from hexacarbonylmolybdenum(0) in order to define the coordination characteristics of the bidentate nitrogen-donor ligands; the complexes exhibit distorted octahedral coordination for molybdenum(0) and cis-bidentate ligand configurations.

  配合物 [Mo(CO)4(L2-N,N')] [L2 = 1-methylimidazol-2-yl(pyridin-2-yl)methanone and 1-benzylimidazol-2-yl(1-phenylaldimine)]由六羰基钼（0）合成，以定义二齿氮供体配体的配位特性；对于钼 (0) 和顺式双齿配体构型，配合物表现出扭曲的八面体配位。