12,12,12',12'-tetramethyl-10,10'-diphenyl-10,10',12,12'-tetrahydro-[7,7']bis(indeno[2,1-b]carbazolyl) | 1257248-37-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 12,12,12',12'-tetramethyl-10,10'-diphenyl-10,10',12,12'-tetrahydro-[7,7']bis(indeno[2,1-b]carbazolyl)
• 英文别名: 2-(7,7-Dimethyl-5-phenylindeno[2,1-b]carbazol-2-yl)-7,7-dimethyl-5-phenylindeno[2,1-b]carbazole
• CAS: 1257248-37-5
• 化学式: C₅₄H₄₀N₂
• 分子量: 716.925
• InChiKey: TVNYMSUBQKKXND-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.7
• 重原子数：
  56
• 可旋转键数：
  3
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  9.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  2-溴-5,7-二氢-7,7-二甲基-5-苯基茚并[2,1-b]咔唑 在 四(三苯基膦)钯 、 1,1'-双(二苯膦基)二茂铁二氯化钯(II)二氯甲烷复合物 、 potassium acetate 、 potassium carbonate 作用下， 以 乙醇 、 水 、 二甲基亚砜 、 甲苯 为溶剂， 反应 21.0h， 生成 12,12,12',12'-tetramethyl-10,10'-diphenyl-10,10',12,12'-tetrahydro-[7,7']bis(indeno[2,1-b]carbazolyl)
  参考文献：
  名称：

  COMPOUND HAVING INDENOCARBAZOLE RING STRUCTURE AND ORGANIC ELECTROLUMINESCENT ELEMENT

  摘要：

  公开号：

  EP2599773B1

文献信息

• COMPOUND, ORGANIC ELECTROLUMINESCENT ELEMENT MATERIAL, ORGANIC ELECTROLUMINESCENT ELEMENT, AND ELECTRONIC DEVICE
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20180029983A1

  公开（公告）日：2018-02-01

  Disclosed herein is a compound represented by formula (1): A-L-B, wherein: A is a group represented by formula (1-A); B is a group represented by formula (1-B); L is a single bond, a substituted or unsubstituted arylene group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heteroarylene group having 5 to 50 ring atoms; and L is bonded to one of R 1 to R 4 of formula (1-A) and R 11 to R 14 of formula (1-B); in which the groups Q 1 , Q 2 , L 1 , L 2 , R 1 -R 4 , R 11 -R 14 , R a -R d and R e -R h defined herein. Also disclosed herein are materials and devices containing the compound represented by formula (1).

  本文披露了一种由化学式（1）表示的化合物：A-L-B，其中：A是由化学式（1-A）表示的基团；B是由化学式（1-B）表示的基团；L是单键，具有6到50个环碳原子的取代或未取代芳基基团，或具有5到50个环原子的取代或未取代杂芳基基团；并且L与化学式（1-A）的R1至R4中的一个和化学式（1-B）的R11至R14中的一个键合；其中本文定义了基团Q1、Q2、L1、L2、R1-R4、R11-R14、Ra-Rd和Re-Rh。本文还披露了含有由化学式（1）表示的化合物的材料和器件。
• MATERIALS FOR ORGANIC ELECTROLUMINESCENT DEVICES
  申请人：Pflumm Christof

  公开号：US20120068170A1

  公开（公告）日：2012-03-22

  The present invention describes indenocarbazole derivatives having electron- and hole-transporting properties, in particular for use in the emission and/or charge-transport layer of electroluminescent devices or as matrix material. The invention furthermore relates to a process for the preparation of the compounds according to the invention and to electronic devices comprising same.

  本发明描述了具有电子和空穴传输性质的吲哚并[3,2-b]咔唑衍生物，特别适用于电致发光器件的发射和/或电荷传输层或作为基质材料。此外，本发明还涉及根据本发明制备化合物的方法以及包括这些化合物的电子器件。
• COMPOUND HAVING INDENOCARBAZOLE RING STRUCTURE, AND ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Yokoyama Norimasa

  公开号：US20130126856A1

  公开（公告）日：2013-05-23

  An organic compound with excellent characteristics excelling in hole-injecting/transporting performance and having electron blocking ability, high stability in a thin-film state and high luminous efficiency is provided as material for an organic electroluminescent device. The compound of a general formula (1) having an indenocarbazole ring structure is used as a constituent material of at least one organic layer in the organic electroluminescent device that includes a pair of electrodes and one or more organic layers sandwiched between the pair of electrodes.

  提供了一种具有出色特性的有机化合物，其在注入/传输空穴性能方面表现优异，并具有阻止电子的能力，在薄膜状态下具有高稳定性和高发光效率，作为有机电致发光器件的材料。公式（1）的化合物具有茚诺咔唑环结构，作为至少一个有机层的组分材料用于有机电致发光器件中，该器件包括一对电极和夹在电极对之间的一个或多个有机层。
• CARBAZOLE DERIVATIVES FOR ORGANIC ELECTROLUMINESCENCE DEVICES
  申请人：Jatsch Anja

  公开号：US20140225046A1

  公开（公告）日：2014-08-14

  The present invention describes carbazole derivatives formula (1), where the following applies to the symbols used: Y is on each occurrence, identically or differently, CR or N; X is selected from C(R1)2, O, S, PR1, P(═O)R1 or BR1; characterised in that at least one group R is present which stands, identically or differently on each occurrence, for a group of the following formula (2), and/or in that at least one group R1 is present which stands for a group of the following formula (3) or (4), in particular for use as triplet matrix materials in organic electroluminescent devices. The invention furthermore relates to a process for the preparation of the compounds according to the invention and to electronic devices comprising same.

  本发明描述了咔唑衍生物的公式（1），其中以下符号的含义如下：Y在每次出现时，相同或不同地为CR或N；X从C（R1）2，O，S，PR1，P（═O）R1或BR1中选择；其特征在于至少存在一个R基团，该基团在每次出现时相同或不同，代表以下公式（2）的基团，和/或至少存在一个R1基团，该基团代表以下公式（3）或（4）的基团，特别适用于有机电致发光器件中的三重态基质材料。此外，本发明还涉及一种制备本发明化合物的方法和包含其的电子设备。
• Plurality of host materials and an organic electroluminescence device comprising the same
  申请人：Rohm and Haas Electronic Materials Korea Ltd.

  公开号：US11130747B2

  公开（公告）日：2021-09-28

  The present invention relates to a plurality of host materials and an organic electroluminescent device comprising the same. By comprising a specific combination of a plurality of host compounds, the organic electroluminescent device according to the present invention provides high efficiency and long lifespan.

  本发明涉及多种宿主材料和由其组成的有机电致发光器件。本发明的有机电致发光器件由多种主化合物的特定组合构成，具有高效率和长寿命的特点。