3,6-bis(triphenylsilyl)carbazole | 1097245-13-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 3,6-bis(triphenylsilyl)carbazole
• 英文别名: triphenyl-(6-triphenylsilyl-9H-carbazol-3-yl)silane
• CAS: 1097245-13-0
• 化学式: C₄₈H₃₇NSi₂
• 分子量: 683.999
• InChiKey: DBDJXGIDPXHUGS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.08
• 重原子数：
  51
• 可旋转键数：
  8
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  15.8
• 氢给体数：
  1
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  3-bromo-9-phenyl-6-(triphenylsilyl)-9-carbazole 、 3,6-bis(triphenylsilyl)carbazole 在 三叔丁基膦 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 、 sodium t-butanolate 作用下， 以 邻二甲苯 为溶剂， 以53 %的产率得到Triphenyl-[9-(9-phenyl-6-triphenylsilylcarbazol-3-yl)-6-triphenylsilylcarbazol-3-yl]silane
  参考文献：
  名称：

  US2023/363255

  摘要：

  公开号：
• 作为产物：
  描述：

  9-acetyl-3,6-bis(triphenylsilyl)carbazole 在 水 、 sodium hydroxide 作用下， 以 四氢呋喃 为溶剂， 反应 3.0h， 以1.28 g的产率得到3,6-bis(triphenylsilyl)carbazole
  参考文献：
  名称：

  Carbazole derivative and semiconductor nanocrystal

  摘要：

  通用公式（1）所代表的一个碳基化合物衍生物，其中至少一个芳香环具有一个到三个取代基，每个取代基由以下通用公式（2）表示：在通用公式（1）中，Ar1和Ar2分别独立表示一个取代或未取代的芳基，可能与苯环形成环，一个取代或未取代的杂环基，一个取代或未取代的芳基硅基，或一个氢原子，Ar3表示一个取代或未取代的芳基，—X—Y—Z （2）在通用公式（2）中，X表示一个亚甲基基团，一个羰氧基团，一个氧羰基团，一个羰基团，一个氧原子或一个硫原子，Y表示一个取代或未取代的烷基基团，Z表示一个羧基，一个羟基或一个硫醇基团。

  公开号：

  US09206202B2

文献信息

• CARBAZOLE DERIVATIVE AND SEMICONDUCTOR NANOCRYSTAL
  申请人：HARADA Shigeyuki

  公开号：US20130026426A1

  公开（公告）日：2013-01-31

  A carbazole derivative represented by the following General Formula (1) where at least one aromatic ring has one to three substituents each represented by the following General Formula (2): in General Formula (1), Ar 1 and Ar 2 each independently represent a substituted or unsubstituted aryl group which may form a ring with a benzene ring, a substituted or unsubstituted heterocyclic group, a substituted or unsubstituted arylsilyl group, or a hydrogen atom, and Ar 3 represents a substituted or unsubstituted aryl group, —X—Y—Z  (2) in General Formula (2), X represents a methylene group, a carbonyloxy group, an oxycarbonyl group, a carbonyl group, an oxygen atom or a sulfur atom, Y represents a substituted or unsubstituted alkylene group, and Z represents a carboxyl group, a hydroxyl group or a thiol group.

  一种由以下一般式（1）表示的咔唑衍生物，其中至少一个芳香环具有一个到三个取代基，每个取代基由以下一般式（2）表示：在一般式（1）中，Ar1和Ar2分别独立表示取代或未取代的芳基，可能与苯环形成环，也可能是取代或未取代的杂环基，取代或未取代的芳基硅基，或氢原子；Ar3表示取代或未取代的芳基，—X—Y—Z（2）在一般式（2）中，X表示一个亚甲基基团、一个羰氧基团、一个氧羰基团、一个羰基团、一个氧原子或一个硫原子，Y表示一个取代或未取代的烷基基团，Z表示一个羧基、一个羟基或一个硫醇基。
• ORGANIC LIGHT-EMITTING DIODES COMPRISING AT LEAST ONE DISILYL COMPOUND SELECTED FROM DISILYLCARBAZOLES, DISILYLDIBENZOFURANS, DISILYLDIBENZOTHIOPHENES, DISILYLDIBENZOPHOLES, DISILYLDIBENZOTHIOPHENE S-OXIDES AND DISILYLDIBENZOTHIOPHENE S,S-DIOXIDES
  申请人：Langer Nicolle

  公开号：US20110031477A1

  公开（公告）日：2011-02-10

  The present invention relates to an organic light-emitting diode comprising an anode An and a cathode Ka and a light-emitting layer E and if appropriate at least one further layer, where the light-emitting layer E and/or the at least one further layer comprises at least one compound selected from disilylcarbazoles, disilyldibenzofurans, disilyldibenzothiophenes, disilyldibenzophospholes, disilyldibenzothiophene S-oxides and disilyldibenzothiophene S,S-dioxides, to a light-emitting layer comprising at least one of the aforementioned compounds, to the use of the aforementioned compounds as matrix material, hole/exciton blocker material, electron/exciton blocker material, hole injection material, electron injection material, hole conductor material and/or electron conductor material, and to a device selected from the group consisting of stationary visual display units, mobile visual display units and illumination units comprising at least one inventive organic light-emitting diode.

  本发明涉及一种有机发光二极管，包括阳极An和阴极Ka以及发光层E，如适当的至少一层，其中发光层E和/或至少一层包括至少一种选择自二硅基咔唑、二硅基二苯并呋喃、二硅基二苯并噻吩、二硅基二苯并磷杂环戊二烯、二硅基二苯并噻吩S-氧化物和二硅基二苯并噻吩S,S-二氧化物的化合物，至少包括上述化合物之一的发光层，使用上述化合物作为基质材料、空穴/激子阻挡材料、电子/激子阻挡材料、空穴注入材料、电子注入材料、空穴传导材料和/或电子传导材料，并选择自固定的视觉显示单元、移动的视觉显示单元和包括至少一个创新有机发光二极管的照明单元的设备。
• ORGANIC LIGHT-EMITTING DIODES COMPRISING CARBENE-TRANSITION METAL COMPLEX EMITTERS, AND AT LEAST ONE COMPOUND SELECTED FROM DISILYLCARBAZOLES, DISILYLDIBENZOFURANS, DISILYLDIBENZOTHIOPHENES, DISILYLDIBENZOPHOSPHOLES, DISILYLDIBENZOTHIOPHENE S-OXIDES AND DISILYLDIBENZOTHIOPHENE S,S-DIOXIDES
  申请人：Langer Nicolle

  公开号：US20100219403A1

  公开（公告）日：2010-09-02

  The present invention relates to an organic light-emitting diode comprising an anode An and a cathode Ka and a light-emitting layer E which is arranged between the anode An and the cathode Ka and comprises at least one carbene complex and if appropriate at least one further layer, where the light-emitting layer E and/or the at least one further layer comprises at least one compound selected from disilylcarbazoles, disilyldibenzofurans, disilyldibenzothiophenes, disilyldibenzophospholes, disilyldibenzothiophene S-oxides and disilyldibenzothiophene S,S-dioxides, to a light-emitting layer comprising at least one of the aforementioned compounds and at least one carbene complex, to the use of the aforementioned compounds as matrix material, hole/exciton blocker material, electron/exciton blocker material, hole injection material, electron injection material, hole conductor material and/or electron conductor material, and to a device selected from the group consisting of stationary visual display units, mobile visual display units and illumination units comprising at least one inventive organic light-emitting diode; to selected disilylcarbazoles, disilyldibenzofurans, disilyldibenzothiophenes, disilyldibenzophospholes, disilyldibenzothiophene S-oxides and disilyldibenzothiophene S,S-dioxides, and to processes for their preparation.

  本发明涉及一种有机电致发光二极管，包括阳极An和阴极Ka以及位于阳极An和阴极Ka之间的发光层E，该发光层E包括至少一种卡宾配合物和必要时至少一种进一步层，其中发光层E和/或至少一种进一步层包括至少一种从二硅基咔唑，二硅基二苯并呋喃，二硅基二苯并噻吩，二硅基二苯基膦，二硅基二苯并噻吩S-氧化物和二硅基二苯并噻吩S，S-二氧化物中选择的化合物，以及包括至少一种上述化合物和至少一种卡宾配合物的发光层，将上述化合物用作基质材料、空穴/激子阻挡材料、电子/激子阻挡材料、空穴注入材料、电子注入材料、空穴导体材料和/或电子导体材料，并且选择从固定的视觉显示单元、移动的视觉显示单元和包括至少一种创新有机电致发光二极管的照明单元的设备，选择的二硅基咔唑，二硅基二苯并呋喃，二硅基二苯并噻吩，二硅基二苯基膦，二硅基二苯并噻吩S-氧化物和二硅基二苯并噻吩S，S-二氧化物，以及它们的制备方法。
• Organic light-emitting diodes comprising carbene-transition metal complex emitter, and at least one compound selected from disilylcarbazoles, disilyldibenzofurans, disilyldibenzothiophenes, disilyldibenzophospholes, disilyldibenzothiophene s-oxides and disilyldibe
  申请人：Langer Nicolle

  公开号：US08373159B2

  公开（公告）日：2013-02-12

  The present invention relates to an organic light-emitting diode comprising an anode An and a cathode Ka and a light-emitting layer E which is arranged between the anode An and the cathode Ka and comprises at least one carbene complex and if appropriate at least one further layer, where the light-emitting layer E and/or the at least one further layer comprises at least one compound selected from disilylcarbazoles, disilyldibenzofurans, disilyldibenzothiophenes, disilyldibenzophospholes, disilyldibenzothiophene S-oxides and disilyldibenzothiophene S,S-dioxides, to a light-emitting layer comprising at least one of the aforementioned compounds and at least one carbene complex, to the use of the aforementioned compounds as matrix material, hole/exciton blocker material, electron/exciton blocker material, hole injection material, electron injection material, hole conductor material and/or electron conductor material, and to a device selected from the group consisting of stationary visual display units, mobile visual display units and illumination units comprising at least one inventive organic light-emitting diode; to selected disilylcarbazoles, disilyldibenzofurans, disilyldibenzothiophenes, disilyldibenzophospholes, disilyldibenzothiophene S-oxides and disilyldibenzothiophene S,S-dioxides, and to processes for their preparation.

  本发明涉及一种有机发光二极管，包括阳极An和阴极Ka以及位于阳极An和阴极Ka之间的发光层E，该发光层E包括至少一种卡宾配合物和必要时至少一种进一步层，其中发光层E和/或至少一种进一步层包括至少一种从二硅基咔唑，二硅基二苯并呋喃，二硅基二苯并噻吩，二硅基二苯基膦，二硅基二苯并噻吩S-氧化物和二硅基二苯并噻吩S，S-二氧化物中选择的化合物，以及至少一种卡宾配合物，以及所述化合物的使用作为基质材料，空穴/激子阻挡材料，电子/激子阻挡材料，空穴注入材料，电子注入材料，空穴导体材料和/或电子导体材料，以及选择的二硅基咔唑，二硅基二苯并呋喃，二硅基二苯并噻吩，二硅基二苯基膦，二硅基二苯并噻吩S-氧化物和二硅基二苯并噻吩S，S-二氧化物，以及它们的制备方法。此外，本发明还涉及选自固定视觉显示单元，移动视觉显示单元和包括至少一种创新有机发光二极管的照明单元的装置。
• Organic light-emitting diodes comprising at least one disilyl compound selected from disilylcarbazoles, disilyldibenzofurans, disilyldibenzothiophenes, disilyldibenzopholes, disilyldibenzothiophene S-oxides and disilyldibenzothiophene S,S-dioxides
  申请人：Langer Nicolle

  公开号：US08697255B2

  公开（公告）日：2014-04-15

  The present invention relates to an organic light-emitting diode comprising an anode and a cathode Ka and a light-emitting layer E and if appropriate at least one further layer, where the light-emitting layer E and/or the at least one further layer comprises at least one compound selected from disilylcarbazoles, disilyldibenzofurans, disilyldibenzothiophenes, disilyldibenzophospholes, disilyldibenzothiophene S-oxides and disilyldibenzothiophene S,S-dioxides, to a light-emitting layer comprising at least one of the aforementioned compounds, to the use of the aforementioned compounds as matrix material, hole/exciton blocker material, electron/exciton blocker material, hole injection material, electron injection material, hole conductor material and/or electron conductor material, and to a device selected from the group consisting of stationary visual display units, mobile visual display units and illumination units comprising at least one inventive organic light-emitting diode.

  本发明涉及一种有机发光二极管，包括阳极和阴极Ka以及发光层E和必要时至少一层进一步的材料，其中发光层E和/或至少一层进一步的材料包括至少一种选自二硅基咔唑、二硅基二苯并呋喃、二硅基二苯并噻吩、二硅基二苯基膦、二硅基噻吩S-氧化物和二硅基噻吩S，S-二氧化物的化合物，以及至少一种前述化合物作为基质材料、空穴/激子阻挡材料、电子/激子阻挡材料、空穴注入材料、电子注入材料、空穴导体材料和/或电子导体材料的用途，以及选自固定式视觉显示单元、移动式视觉显示单元和至少包括一种本发明有机发光二极管的照明单元的装置。