3,5-Bis[[bis(pyridin-2-ylmethyl)amino]methyl]-4-(methoxymethoxy)benzaldehyde | 918550-35-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,5-Bis[[bis(pyridin-2-ylmethyl)amino]methyl]-4-(methoxymethoxy)benzaldehyde
• 英文别名: 3,5-bis[[bis(pyridin-2-ylmethyl)amino]methyl]-4-(methoxymethoxy)benzaldehyde
• CAS: 918550-35-3
• 化学式: C₃₅H₃₆N₆O₃
• 分子量: 588.709
• InChiKey: LXFUSNMVZXHIEG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  44
• 可旋转键数：
  16
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  93.6
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  2,5-di(diethoxyphosphorylmethyl)pyrazine 、 3,5-Bis[[bis(pyridin-2-ylmethyl)amino]methyl]-4-(methoxymethoxy)benzaldehyde 在 potassium tert-butylate 、 甲醇 、 三氟乙酸 作用下， 以 四氢呋喃 为溶剂， 生成 4-[(E)-2-[5-[(E)-2-[3,5-bis[[bis(pyridin-2-ylmethyl)amino]methyl]-4-hydroxyphenyl]ethenyl]pyrazin-2-yl]ethenyl]-2,6-bis[[bis(pyridin-2-ylmethyl)amino]methyl]phenol
  参考文献：
  名称：

  A selective fluorescent sensor for Pb(II) in water

  摘要：

  A new fluorescent sensor (1) containing bis(2-pyridylmethyl)amine group as a binding moiety for Pb2+ was developed. Compound I shows selective response to Pb2+ over other metal ions in pH 7.0 HEPES buffer solution. The fluorescence intensity enhancement was ascribed to the complex formation between Pb2+ and 1 which blocked the photo-induced electron transfer process. (c) 2006 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tetlet.2006.10.060
• 作为产物：
  描述：

  二甲基吡啶胺 在 potassium carbonate 作用下， 以 乙醇 、 丙酮 为溶剂， 生成 3,5-Bis[[bis(pyridin-2-ylmethyl)amino]methyl]-4-(methoxymethoxy)benzaldehyde
  参考文献：
  名称：

  A selective fluorescent sensor for Pb(II) in water

  摘要：

  A new fluorescent sensor (1) containing bis(2-pyridylmethyl)amine group as a binding moiety for Pb2+ was developed. Compound I shows selective response to Pb2+ over other metal ions in pH 7.0 HEPES buffer solution. The fluorescence intensity enhancement was ascribed to the complex formation between Pb2+ and 1 which blocked the photo-induced electron transfer process. (c) 2006 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tetlet.2006.10.060

文献信息

• A selective fluorescent sensor for Pb(II) in water
  作者：Fang-Ying Wu、Se Won Bae、Jong-In Hong

  DOI：10.1016/j.tetlet.2006.10.060

  日期：2006.12

  A new fluorescent sensor (1) containing bis(2-pyridylmethyl)amine group as a binding moiety for Pb2+ was developed. Compound I shows selective response to Pb2+ over other metal ions in pH 7.0 HEPES buffer solution. The fluorescence intensity enhancement was ascribed to the complex formation between Pb2+ and 1 which blocked the photo-induced electron transfer process. (c) 2006 Published by Elsevier Ltd.