2,5-di(diethoxyphosphorylmethyl)pyrazine | 918550-33-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机膦酸及其衍生物
• 英文名称: 2,5-di(diethoxyphosphorylmethyl)pyrazine
• 英文别名: 2,5-Bis[[diethoxy(oxido)phosphaniumyl]methyl]pyrazine；2,5-bis[[diethoxy(oxido)phosphaniumyl]methyl]pyrazine
• CAS: 918550-33-1
• 化学式: C₁₄H₂₆N₂O₆P₂
• 分子量: 380.318
• InChiKey: AJMQWLKJGOSBFY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.6
• 重原子数：
  24
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  109
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  2,5-di(diethoxyphosphorylmethyl)pyrazine 、 1,1-dimethyl-7,7-adamantyljulolidine-9-carboaldehyde 在 potassium tert-butylate 作用下， 以 四氢呋喃 为溶剂， 反应 1.17h， 以58.6%的产率得到
  参考文献：
  名称：

  Synthesis of Donor-Aromatic-Donor Type π-conjugated Materials and their Application to Red Fluorescent Organic Light-Emitting Diodes

  摘要：

  A series of donor-aromatic-donor type pi-conjugated materials were designed and synthesized. A device with the structure of ITO/NPB (50 nm)/Alq(3): 3 (1%) (30 nm)/Alq(3) (40 nm)/Liq (2 nm)/Al showed the luminous and power efficiencies of 3.57 cd/A and 1.65 lm/W at 20 mA/cm(2), respectively. The CIE coordinates of this device was (0.57, 0.41) at 7.0 V. This study demonstrates that the donor-aromatic-donor type pi-conjugated materials are the promising materials for applications in white OLEDs.

  DOI：

  10.1080/15421406.2012.689155
• 作为产物：
  描述：

  2,5-二甲基吡嗪 、 亚磷酸三乙酯 在 N-溴代丁二酰亚胺(NBS) 、 偶氮二异丁腈 作用下， 生成 2,5-di(diethoxyphosphorylmethyl)pyrazine
  参考文献：
  名称：

  A selective fluorescent sensor for Pb(II) in water

  摘要：

  A new fluorescent sensor (1) containing bis(2-pyridylmethyl)amine group as a binding moiety for Pb2+ was developed. Compound I shows selective response to Pb2+ over other metal ions in pH 7.0 HEPES buffer solution. The fluorescence intensity enhancement was ascribed to the complex formation between Pb2+ and 1 which blocked the photo-induced electron transfer process. (c) 2006 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tetlet.2006.10.060

文献信息

• A selective fluorescent sensor for Pb(II) in water
  作者：Fang-Ying Wu、Se Won Bae、Jong-In Hong

  DOI：10.1016/j.tetlet.2006.10.060

  日期：2006.12

  A new fluorescent sensor (1) containing bis(2-pyridylmethyl)amine group as a binding moiety for Pb2+ was developed. Compound I shows selective response to Pb2+ over other metal ions in pH 7.0 HEPES buffer solution. The fluorescence intensity enhancement was ascribed to the complex formation between Pb2+ and 1 which blocked the photo-induced electron transfer process. (c) 2006 Published by Elsevier Ltd.
• Synthesis of Donor-Aromatic-Donor Type π-conjugated Materials and their Application to Red Fluorescent Organic Light-Emitting Diodes
  作者：Eun Jae Na、Kum Hee Lee、Young Kwan Kim、Seung Soo Yoon

  DOI：10.1080/15421406.2012.689155

  日期：2012.9.5

  A series of donor-aromatic-donor type pi-conjugated materials were designed and synthesized. A device with the structure of ITO/NPB (50 nm)/Alq(3): 3 (1%) (30 nm)/Alq(3) (40 nm)/Liq (2 nm)/Al showed the luminous and power efficiencies of 3.57 cd/A and 1.65 lm/W at 20 mA/cm(2), respectively. The CIE coordinates of this device was (0.57, 0.41) at 7.0 V. This study demonstrates that the donor-aromatic-donor type pi-conjugated materials are the promising materials for applications in white OLEDs.