dimethylaminoethenol

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: dimethylaminoethenol
• 英文别名: 1-(Dimethylamino)ethenol
• 化学式: C₄H₉NO
• 分子量: 87.1216
• InChiKey: NVLNZFLRJJQWMO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  6
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  23.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  烯丙醇 、 dimethylaminoethenol 生成 4-pentenoic acid N,N-dimethylamide
  参考文献：
  名称：

  Degradation of cellulosic materials by heating in DMAc/LiCl

  摘要：

  N,N-Dimethylacetamide (DMAc, 1)/lithium chloride is a frequently used solvent system for cellulosic materials. Heating or refluxing insoluble samples in DMAc/LiCl represents a common protocol for facilitating the subsequent dissolution. It is shown by kinetics using gel permeation chromatography (GPC) that the improved solubility is not caused by an alleged 'activation' of the pulp, but by progressing degradation of the cellulosic material. Ketene aminal 2 and N,N-dimethylketeniminium ions (3), the latter being known as reagent for cleavage of ethers and acetals, have been demonstrated to be present in DMAc and DMAc/LiCl at elevated temperatures by specific trapping of these intermediates in a Claisen rearrangement and in a thermal [2+2]-cycloaddition, respectively. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(02)01767-7

文献信息

• Degradation of cellulosic materials by heating in DMAc/LiCl
  作者：Antje Potthast、Thomas Rosenau、Herbert Sixta、Paul Kosma

  DOI：10.1016/s0040-4039(02)01767-7

  日期：2002.10

  N,N-Dimethylacetamide (DMAc, 1)/lithium chloride is a frequently used solvent system for cellulosic materials. Heating or refluxing insoluble samples in DMAc/LiCl represents a common protocol for facilitating the subsequent dissolution. It is shown by kinetics using gel permeation chromatography (GPC) that the improved solubility is not caused by an alleged 'activation' of the pulp, but by progressing degradation of the cellulosic material. Ketene aminal 2 and N,N-dimethylketeniminium ions (3), the latter being known as reagent for cleavage of ethers and acetals, have been demonstrated to be present in DMAc and DMAc/LiCl at elevated temperatures by specific trapping of these intermediates in a Claisen rearrangement and in a thermal [2+2]-cycloaddition, respectively. (C) 2002 Elsevier Science Ltd. All rights reserved.