| 140388-75-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 140388-75-6
• 化学式: C₂₇H₄₄IO₆Ru
• 分子量: 692.617
• InChiKey: IXDXFUCRQYIQGI-KXASFHRZSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 三甲基乙炔基硅 在 PdCl₂(PPh)2 、 CuI 作用下， 以 三乙胺 为溶剂， 以9.7%的产率得到Ru(2,2,6,6-tetramethylheptan-3,5-dionate)2(E-3-(1,4-bis(trimethylsilyl)-1-butene-3-ynyl)-2,4-pentanedionate)
  参考文献：
  名称：

  Formation of novel ene-yne substituted β-diketonato ruthenium(III) complexes by the Heck-like reactions on coordinated ligand

  摘要：

  Two new ene-yne substituted 2,4-pentanedionatoruthenium(III) complexes formed by the Heck-like reactions in the course of the Sonogashira reactions. The two complexes are structural isomers; one is [Ru(E-1,4-mBSima)(dpm)(2)] and another is [Ru(E-2,4-mBSima)(dpm)(2)], where E-1,4-mBSima is E-3-(1,4-bis(trimethylsilyl)-1-butene-3-ynyl)-2,4-pentanedionate, E-2,4-mBSima is E-3-(2,4-bis(trimethylsilyl)-1-butene-3-ynyl)-2,4-pentanedionate, and dpm is dipivaloylmethanate (2,2,6,6-tetramethylheptan-3,5-dionate). Both of complexes have been characterized by (1)H NMR and infrared spectroscopies, mass spectrometry, and electrochemistry. [Ru(E-1,4-mBSima)(dpm)(2)] has also been characterized by X-ray crystallography. The ruthenium(III) is coordinated in an octahedral arrangement by the oxygen atoms of three beta-diketonate ligands. The dihedral angle between the 2,4-pentanedionato chelate ring and the ene-yne plane on the E-1,4-mBSima ligand is 91 degrees. The ene-yne group in [Ru(E-1,4-mBSima)(dpm)(2)] is fixed either in the solution state suggested by the (1)H NMR spectrum with no symmetry. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.03.026
• 作为产物：
  描述：

  N-碘代丁二酰亚胺 、 [Ru(2,2,6,6-tetramethyl-3,5-heptanedionate)2(2,4-pentanedionate)] 以 苯 为溶剂， 以81%的产率得到
  参考文献：
  名称：

  Kasahara, Yuko; Hoshino, Yoshimasa; Kajitani, Masatsugu, Organometallics, 1992, vol. 11, # 5, p. 1968 - 1971

  摘要：

  DOI：