[10,20-bis[2,6-bis(n-hexoxy)phenyl]porphinato]zinc | 1033754-02-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [10,20-bis[2,6-bis(n-hexoxy)phenyl]porphinato]zinc
• CAS: 1033754-02-7
• 化学式: C₅₆H₆₈N₄O₄Zn
• 分子量: 926.57
• InChiKey: UWNVMRHBNUBPIK-PBHWLMJTSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [10,20-bis[2,6-bis(n-hexoxy)phenyl]porphinato]zinc 在 吡啶 、 N-溴代丁二酰亚胺(NBS) 作用下， 以 氯仿 为溶剂， 反应 2.0h， 以87%的产率得到[5,15-dibromo-10,20-bis[2,6-bis(n-hexoxy)phenyl]porphinato]zinc
  参考文献：
  名称：

  Cavity-Tailored, Self-Sorting Supramolecular Catalytic Boxes for Selective Oxidation

  摘要：

  Using a steric self-sorting strategy, the assembly of highly ordered and rigid supramolecular boxes possessing catalytic properties has been achieved in one step. The formation of these assemblies, comprising up to 18 porphyrin centers, was readily confirmed by sotution X-ray scattering in conjunction with fluorescent spectroscopy. Size-selective and enantioselective oxidation catalysis were both demonstrated.

  DOI：

  10.1021/ja804014y
• 作为产物：
  描述：

  10,20-bis-[2,6-bis(n-hexoxy)phenyl]porphyrin 在 zinc diacetate 作用下， 以452 mg的产率得到[10,20-bis[2,6-bis(n-hexoxy)phenyl]porphinato]zinc
  参考文献：
  名称：

  Cavity-Tailored, Self-Sorting Supramolecular Catalytic Boxes for Selective Oxidation

  摘要：

  Using a steric self-sorting strategy, the assembly of highly ordered and rigid supramolecular boxes possessing catalytic properties has been achieved in one step. The formation of these assemblies, comprising up to 18 porphyrin centers, was readily confirmed by sotution X-ray scattering in conjunction with fluorescent spectroscopy. Size-selective and enantioselective oxidation catalysis were both demonstrated.

  DOI：

  10.1021/ja804014y

文献信息

• Fast energy transfer within a self-assembled cyclic porphyrin tetramer
  作者：Rebecca A. Jensen、Richard F. Kelley、Suk Joong Lee、Michael R. Wasielewski、Joseph T. Hupp、David M. Tiede

  DOI：10.1039/b718628b

  日期：——

  The structure of a cyclic self-assembled tetramer of an asymmetric meso-ethynylpyridyl-functionalized Zn(II)–porphyrin was established by solution-phase X-ray scattering and diffraction; femtosecond transient absorption and anisotropy spectroscopies were used to (a) observe rapid energy transfer (3.8 ps−1) between porphyrin subunits and (b) establish that the transfer occurs between adjacent units.

  通过溶液相 X 射线散射和衍射，确定了不对称介乙炔基吡啶官能化 Zn(II)-卟啉的环状自组装四聚体结构；利用飞秒瞬态吸收和各向异性光谱 (a) 观察卟啉亚基之间的快速能量转移（3.8 ps-1），(b) 确定能量转移发生在相邻单元之间。