1-{2-methyl-5-[4-(methoxymethoxy)phenyl]thien-3yl}-2-(2-methyl-5-phenylthien-3-yl)perfluorocyclopentene | 1185478-94-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1-{2-methyl-5-[4-(methoxymethoxy)phenyl]thien-3yl}-2-(2-methyl-5-phenylthien-3-yl)perfluorocyclopentene
• 英文别名: 3-[3,3,4,4,5,5-Hexafluoro-2-[5-[4-(methoxymethoxy)phenyl]-2-methylthiophen-3-yl]cyclopenten-1-yl]-2-methyl-5-phenylthiophene；3-[3,3,4,4,5,5-hexafluoro-2-[5-[4-(methoxymethoxy)phenyl]-2-methylthiophen-3-yl]cyclopenten-1-yl]-2-methyl-5-phenylthiophene
• CAS: 1185478-94-7
• 化学式: C₂₉H₂₂F₆O₂S₂
• 分子量: 580.615
• InChiKey: RZRMRVAZOVOZAC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.2
• 重原子数：
  39
• 可旋转键数：
  7
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  74.9
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  1-{2-methyl-5-[4-(methoxymethoxy)phenyl]thien-3yl}-2-(2-methyl-5-phenylthien-3-yl)perfluorocyclopentene 在 盐酸 作用下， 以 四氢呋喃 、 水 为溶剂， 以92%的产率得到1-[2-methyl-5-(4-hydroxyphenyl)thien-3yl]-2-(2-methyl-5-phenylthien-3-yl)perfluorocyclopentene
  参考文献：
  名称：

  Solvent effect on photochromism of a dithienylperfluorocyclopentene having diethylamino group

  摘要：

  Some photochromic diarylethenes having polar substituents were synthesized, and their photochromic behavior was examined. They exhibited photochromism with the similar photoreactivity in a non-polar solvent. However, the photocyclization quantum yield of dithienylperfluorocyclopentene having diethylamino group was found to decrease in polar solvents. The yield in acetonitrile was estimated to be 60 times smaller than that in hexane. The yields determined in various solvents were found to be correlated with the solvent polarity parameter E-T(30). Such an effect was not observed in dithienylfluorocyclopentenes bearing methoxy or acetoxy group and in non-fluorinated dithienylcyclopentene bearing diethylamino group. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2009.05.053
• 作为产物：
  描述：

  生成 1-{2-methyl-5-[4-(methoxymethoxy)phenyl]thien-3yl}-2-(2-methyl-5-phenylthien-3-yl)perfluorocyclopentene
  参考文献：
  名称：

  光致变色纳米粒子混合物中的波长选择和高对比度多色荧光光开关

  摘要：

  在此，我们报告了在两种不同的发射色光致变色纳米粒子的混合物中，白色，橙色，青色和深色之间的波长选择性和高对比度多色荧光光电转换，该纳米粒子由不同对的光开关单元和一个荧光单位。

  DOI：

  10.1039/c7cc02938a

文献信息

• Solvent effect on photochromism of a dithienylperfluorocyclopentene having diethylamino group
  作者：Seiya Kobatake、Yuko Terakawa、Hiroyuki Imagawa

  DOI：10.1016/j.tet.2009.05.053

  日期：2009.8

  Some photochromic diarylethenes having polar substituents were synthesized, and their photochromic behavior was examined. They exhibited photochromism with the similar photoreactivity in a non-polar solvent. However, the photocyclization quantum yield of dithienylperfluorocyclopentene having diethylamino group was found to decrease in polar solvents. The yield in acetonitrile was estimated to be 60 times smaller than that in hexane. The yields determined in various solvents were found to be correlated with the solvent polarity parameter E-T(30). Such an effect was not observed in dithienylfluorocyclopentenes bearing methoxy or acetoxy group and in non-fluorinated dithienylcyclopentene bearing diethylamino group. (C) 2009 Elsevier Ltd. All rights reserved.
• Wavelength-selective and high-contrast multicolour fluorescence photoswitching in a mixture of photochromic nanoparticles
  作者：Sanae Ishida、Tuyoshi Fukaminato、Daichi Kitagawa、Seiya Kobatake、Sunnam Kim、Tomonari Ogata、Seiji Kurihara

  DOI：10.1039/c7cc02938a

  日期：——

  Herein, we report on wavelength-selective and high-contrast multicolour fluorescence photoswitching between white-, orange-, cyan-, and dark-colours in a mixture of two distinguishable emission-coloured photochromic nanoparticles composed of different pairs of a photoswitching unit and a fluorescence unit.

  在此，我们报告了在两种不同的发射色光致变色纳米粒子的混合物中，白色，橙色，青色和深色之间的波长选择性和高对比度多色荧光光电转换，该纳米粒子由不同对的光开关单元和一个荧光单位。