| 1523583-38-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• CAS: 1523583-38-1
• 化学式: C₄₉H₇₃N₃O₆
• 分子量: 800.135
• InChiKey: HCXCUGLSIGBIEW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.24
• 重原子数：
  58.0
• 可旋转键数：
  33.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.63
• 拓扑面积：
  104.14
• 氢给体数：
  0.0
• 氢受体数：
  7.0

反应信息

• 作为反应物：
  描述：

  、 5,11,17,23-tetra-tert-butyl-25,27-dihydroxy-26,28-dipropargylcalix[4]arene 在 copper(ll) sulfate pentahydrate 、 sodium ascorbate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 10.0h， 以81%的产率得到5,11,17,23-Tetratert-butyl-26,28-bis[[1-[6-(3,6,7,10,11-pentapentoxytriphenylen-2-yl)oxyhexyl]triazol-4-yl]methoxy]pentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(24),3,5,7(28),9,11,13(27),15(26),16,18,21(25),22-dodecaene-25,27-diol
  参考文献：
  名称：

  Synthesis, complexation, and mesomorphism of novel calixarene-linked discotic triphenylene based on click chemistry

  摘要：

  The novel calixarene-linked discotic triphenylene 5a and 5b were synthesized in good yields via click chemistry. Structural and conformational characterization of new compounds had been achieved by NMR, MS, and elemental analysis. Their liquid crystalline behaviors before and after complexation were studied by polarizing optical microscopy, differential scanning calorimetry, and X-ray diffraction. The neat compounds 5a and 5b showed mesophase but the complexes of 5a and 5b with metallic salts exhibited no liquid crystal behaviors. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.11.008
• 作为产物：
  描述：

  2-hydroxy-3,6,7,10,11-pentapentyloxytriphenylene 在 sodium azide 、 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 、 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Synthesis, complexation, and mesomorphism of novel calixarene-linked discotic triphenylene based on click chemistry

  摘要：

  The novel calixarene-linked discotic triphenylene 5a and 5b were synthesized in good yields via click chemistry. Structural and conformational characterization of new compounds had been achieved by NMR, MS, and elemental analysis. Their liquid crystalline behaviors before and after complexation were studied by polarizing optical microscopy, differential scanning calorimetry, and X-ray diffraction. The neat compounds 5a and 5b showed mesophase but the complexes of 5a and 5b with metallic salts exhibited no liquid crystal behaviors. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.11.008

文献信息

• Novel columnar liquid crystalline oligomers: Triphenylene tetramers with rigid aromatic Schiff-bases and hydrogen-bonding spacers via click chemistry
  作者：Shengjie Jiang、Hongyu Guo、Shuyun Zhu、Fafu Yang

  DOI：10.1016/j.molliq.2017.04.007

  日期：2017.6

  Three novel triphenylene tetramers with triazole bridges, rigid aromatic Schiff-bases and hydrogen-bonding spacers were designed and synthesized in yield of 73–78%. Their structures were confirmed by IR, NMR and MS. Their mesomorphic properties were studied by polarizing optical microscopy, differential scanning calorimetry and X-ray diffraction. These novel triphenylene tetramers possessed the hexagonal

  设计并合成了三种具有三唑桥，刚性芳族席夫碱和氢键间隔基的新型三亚苯基四聚物，产率为73-78％。它们的结构通过IR，NMR和MS确认。通过偏光光学显微镜，差示扫描量热法和X射线衍射研究了它们的介晶性质。这些新型的三亚苯基四聚体具有六方柱状中间相，并具有出色的介晶性质，其熔点为30-60°C，这是在室温附近首次发现的三亚苯基四聚体。这项研究表明，可以通过间隔基的结构方便地调节三亚苯基低聚物的介晶性质。