2,2-Diallyl-malonic acid diallyl ester | 502850-33-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2,2-Diallyl-malonic acid diallyl ester
• 英文别名: Bis(prop-2-enyl) 2,2-bis(prop-2-enyl)propanedioate；bis(prop-2-enyl) 2,2-bis(prop-2-enyl)propanedioate
• CAS: 502850-33-1
• 化学式: C₁₅H₂₀O₄
• 分子量: 264.321
• InChiKey: QXFZDMFDJDFYIK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  19
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,2-Diallyl-malonic acid diallyl ester 在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 为溶剂， 反应 4.0h， 生成 2,2-diallyl-1,3-propanediol
  参考文献：
  名称：

  Unusual macrocyclic spirocycles from tandem metathesis reactions

  摘要：

  This letter details the formation of 18-membered macrocyclic spirocyclic esters and ethers from readily prepared tetraene precursors via tandem metathesis reactions. Factors which control the course of these transition metal catalysed processes are discussed and the crystal structures of the novel macrocycles obtained are delineated. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(02)01909-3
• 作为产物：
  描述：

  丙二酸二烯丙酯 、 3-溴丙烯 在 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 生成 2,2-Diallyl-malonic acid diallyl ester
  参考文献：
  名称：

  Unusual macrocyclic spirocycles from tandem metathesis reactions

  摘要：

  This letter details the formation of 18-membered macrocyclic spirocyclic esters and ethers from readily prepared tetraene precursors via tandem metathesis reactions. Factors which control the course of these transition metal catalysed processes are discussed and the crystal structures of the novel macrocycles obtained are delineated. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(02)01909-3

文献信息

• Unusual macrocyclic spirocycles from tandem metathesis reactions
  作者：Robert A.J. Wybrow、Leigh A. Johnson、Benoit Auffray、Wesley J. Moran、Harry Adams、Joseph P.A. Harrity

  DOI：10.1016/s0040-4039(02)01909-3

  日期：2002.10

  This letter details the formation of 18-membered macrocyclic spirocyclic esters and ethers from readily prepared tetraene precursors via tandem metathesis reactions. Factors which control the course of these transition metal catalysed processes are discussed and the crystal structures of the novel macrocycles obtained are delineated. (C) 2002 Elsevier Science Ltd. All rights reserved.