1-溴-2-戊氧基苯 | 63076-60-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: 1-溴-2-戊氧基苯
• 英文名称: n-Pentyl-o-bromphenylether
• 英文别名: 1-bromo-2-pentyloxybenzene；2-Bromophenylpentyl ether；1-bromo-2-pentoxybenzene
• CAS: 63076-60-8
• 化学式: C₁₁H₁₅BrO
• 分子量: 243.143
• InChiKey: YSRFGWMXCZGDNQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-溴-2-戊氧基苯 在 magnesium 、 三氯化磷 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Synthesis, structure, and ethylene polymerization behavior of nickel complexes based on benzoylmethylenetri(2-alkoxylphenyl)phosphorane

  摘要：

  在 PPh3 的存在下，通过用 Ni(cod)2 处理稳定的苯甲酰亚甲基三(2-烷氧基苯基)磷烷，制备出了几种新的镍络合物。X 射线衍射研究表明，Ni(II) 周围的几何形状为扭曲的正方形。经 Ni(cod)2 处理后，镍络合物对乙烯聚合具有足够的稳定性。磷上 2- 烷氧基芳基取代基的存在提高了催化活性。当使用三（2-异丙氧基苯基）磷烷（5e）时，活性最高（2.1 × 106 g mol-1 h-1），比相应的 SHOP 催化剂高一个数量级。核磁共振分析表明，聚乙烯主要含有末端双键，具有很高的线性。

  DOI：

  10.1039/c2dt12052f
• 作为产物：
  描述：

  戊氧基苯 在 溴 、 Sodium 3-((2,2-Diheptadecyl-1,3-dioxolan-4-yl)methoxy)-1-propanesulfonate 作用下， 以 水 、 乙腈 为溶剂， 反应 0.08h， 生成 4-正戊氧基溴苯 、 1-溴-2-戊氧基苯
  参考文献：
  名称：

  Jaeger, David A.; Clennan, Malgorzata Wegrzyn; Jamrozik, Janusz, Journal of the American Chemical Society, 1990, vol. 112, # 3, p. 1171 - 1176

  摘要：

  DOI：

文献信息

• Synthesis and optical and transport properties of a phenyl-substituted polythiophene
  作者：Siraye E. Debebe、Desta A. Gedefaw、Wendimagegn Mammo、Teketel Yohannes、Francesca Tinti、Alberto Zanelli、Valeria Fattori、Nadia Camaioni

  DOI：10.1002/pola.24701

  日期：2011.6.15

  The synthesis and characterization of a novel polythiophene substituted with a 2′‐pentyloxy‐5′‐(1″′‐oxooctyl) phenyl group (PPOPT) is reported. The bulk transport properties of thin films of PPOPT are investigated by admittance spectroscopy. The dramatic effect of the phenyl side chain on the mobility of positive carriers in films of PPOPT is described. The photophysics of PPOPT in both solution and

  报道了一种新型的被2'-戊氧基-5'-（1'''-氧辛基）苯基（PPOPT）取代的聚噻吩的合成和表征。通过导纳光谱研究了PPOPT薄膜的整体传输性能。描述了苯基侧链对PPOPT薄膜中正载流子迁移率的巨大影响。还研究了溶液和薄膜中PPOPT的光物理性质，并将其与取代基驱动的链内和链间排列相关。©2011 Wiley Periodicals，Inc. J Polym Sci A部分：Polym Chem，2011年
• π-Conjugated Triphenylene Twins Exhibiting Polymesomorphism Including the Nematic Phase
  作者：Sanjay Kumar Varshney、Hideo Takezoe、Veena Prasad、D. S. Shankar Rao

  DOI：10.1080/15421400902987677

  日期：2009.12.7

  Novel discotic liquid crystals possessing two triphenylene (TP) mesogenic cores covalently connected via a rigid spacer, i.e., -conjugated ethynyl- or butadiynyl-bridge, (TP twins) are reported. The TP twins are categorized by the lengths of -substituted chains (R2 and R3) and peripheral alkoxy or branched aliphatic chains (R1 and R4). Three varieties of TP twins are prepared: A) TP twins having identical -substituted and peripheral chains (R1=R2=R3=R4), B) equivalent TP entities having a -substituted chain (R2=R3) and peripheral chains (R1=R4) of different length from the substitution, and C) TP twins with different TP entities having the same -substituted and peripheral alkoxy chains (R1=R2, R3=R4). The phase behavior is characterized by differential scanning calorimetry (DSC), polarizing optical microscopy (POM) and X-ray diffraction (XRD) studies. These TP twins exhibit a discotic nematic (N) and/or columnar rectangular (Colr) mesophases over a wide temperature range. We found that the relative length of rigid spacer and -substituted alkoxy chains play an important role in the creation of the molecular self-assembly and formation of the mesophases. To the best of our knowledge, this is the first report of TP twins exhibiting polymesomorphism.
• Synthesis and Liquid-Crystalline Properties of β-Bromopentakis(Alkoxy) Triphenylene: Reactivity of VOCl₃, MoCl₅, and FeCl₃as Oxidants
  作者：Sanjay Kumar Varshney、Hiroki Nagayama、D. S. Shankar Rao、Hideo Takezoe

  DOI：10.1080/15421406.2010.504514

  日期：2010.10.14

  We present a simple synthetic strategy leading to nonsymmetrical functionalized hexasubstituted triphenylene. Further, new -bromopentakis(alkoxy)triphenylene was synthesized applying this strategy and reactivity of oxidizing agents such as VOCl3, MoCl5, and FeCl3 was investigated. The liquid-crystalline properties were studied by polarizing optical microscope (POM), differential scanning calorimetry (DSC), and X-ray diffraction (XRD) studies. The higher homologues exhibit a columnar hexagonal (Colh) phase, whereas lower homologues also exhibit a columnar hexagonal plastic (Colhp) phase. These mesophases are stable below and above the ambient temperature. We studied the effect of polar substitution on molecular self-assembly and found that a bromo bulky substituent at the -position of pentakis(alkoxy)triphenylenes stabilized the intra- or intermolecular interaction between the cores to form columnar mesophases.
• Micellar effects on the monohalogenation of n-pentyl phenyl ether
  作者：David A. Jaeger、Raymond E. Robertson

  DOI：10.1021/jo00440a022

  日期：1977.9
• 2-PYRIDINE CARBOXAMIDE DERIVATIVES AS SODIUM CHANNEL MODULATORS
  申请人：Pfizer Limited

  公开号：EP2183241B1

  公开（公告）日：2012-12-19