(acetato)[2,8,12,18-tetrabutyl-3,7,13,17-tetramethyl-5,15-bis(2-thienyl)-21H,23H-porphinato]manganese(III) | 1582780-88-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: (acetato)[2,8,12,18-tetrabutyl-3,7,13,17-tetramethyl-5,15-bis(2-thienyl)-21H,23H-porphinato]manganese(III)
• CAS: 1582780-88-8
• 化学式: C₅₀H₅₉MnN₄O₂S₂
• 分子量: 867.114
• InChiKey: OBLKVRPCCOAGTF-NZDJUDTLSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  5,15-bis(2'-thienyl)-2,8,12,18-tetra-n-butyl-3,7,13,17-tetramethylporphine 、 manganese(II) acetate 以 N,N-二甲基甲酰胺 为溶剂， 生成 (acetato)[2,8,12,18-tetrabutyl-3,7,13,17-tetramethyl-5,15-bis(2-thienyl)-21H,23H-porphinato]manganese(III)
  参考文献：
  名称：

  Synthesis and investigation of 2,8,12,18-tetrabutyl-3,7,13,17-tetramethyl-5,15-bis(2-thienyl)-21H,23H-porphin and its complexes with manganese (III) acetate and chloride

  摘要：

  2,8,12,18-Tetrabutyl-3,7,13,17-tetramethyl-5,15-bis(2-thienyl)-21H,23H-porphin and its complexes with manganese(III) with additional acetate and chloride acido ligands were synthesized. Basing on the UV, IR, and NMR spectra and the kinetic properties of the proton transfer and the dissociation of free and coordinated porphyrin respectively it was established that in the change of porphyrin basicity at thienyl substitution the effect of the sulfur atom vacant d-orbitals involved in the conjugation was predominant. The stability of thienyl-substitued complexes of manganese(III) rises when the axial Cl- is replaced by acetate ion.

  DOI：

  10.1134/s1070428014020249