1-[(3,5-二甲基-1,2,4-三唑-1-基)甲基]-3,5-二甲基-1,2,4-三唑 | 63400-39-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 中文名称: 1-[(3,5-二甲基-1,2,4-三唑-1-基)甲基]-3,5-二甲基-1,2,4-三唑
• 英文名称: bis(3,5-dimethyl-1,2,4-triazol-1-yl)methane
• 英文别名: 1H-1,2,4-Triazole, 1,1'-methylenebis[3,5-dimethyl-；1-[(3,5-dimethyl-1,2,4-triazol-1-yl)methyl]-3,5-dimethyl-1,2,4-triazole
• CAS: 63400-39-5
• 化学式: C₉H₁₄N₆
• 分子量: 206.25
• InChiKey: HWJDALSIXQVGMS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  61.4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1-[(3,5-二甲基-1,2,4-三唑-1-基)甲基]-3,5-二甲基-1,2,4-三唑 以 乙二醇二甲醚 、 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  含双（三唑-1-基）甲烷的6族金属羰基金属配合物的合成和反应活性：键配位聚合物

  摘要：

  双（3,5-二甲基-1,2,4-三唑-1-基）甲烷CH 2（3,5-Me 2 Tz）2与M（CO）6（M = Cr，Mo或W）在回流的DME中以中等收率生成CH 2（3,5-Me 2 Tz）2 M（CO）4。通过X射线分析确定的晶体结构表明，双（3，5-二甲基-1，2，4-三唑-1-基）甲烷充当螯合的二齿配体，在这些配合物中具有两个内齿氮原子。配合物CH 2（3,5-Me 2 Tz）2 M（CO）4（M = Mo或W）与R 2 SnX 2的反应比例分别为1：1或1：2的（R = Ph或Me; X = Cl或Br）仅产生1：1的加合物。在这些加合物中，双（3,5-二甲基-1,2,4-三唑-1-基）甲烷可通过三唑环4位上的齿外氮原子与锡原子配位，形成键合配位聚合物。可能是由于三唑环上4位外氮原子对有机锡受体的供体较弱，这些加合物在溶液中可能解离。CH 2（3,5-Me 2 Tz）2 W（CO）4

  DOI：

  10.1016/s0022-328x(01)01192-5

文献信息

• Near infrared radiation-absorbing composition, near infrared radiation cut-off filter and production method therefor, and camera module and production method therefor
  申请人：FUJIFILM Corporation

  公开号：US10184052B2

  公开（公告）日：2019-01-22

  An object of the present invention is to provide a near infrared radiation-absorbing composition having favorable shielding properties in a near infrared range when used to produce cured films, a near infrared radiation cut-off filter and a production method therefor, and a camera module and a production method therefor. The near infrared radiation-absorbing composition including a copper complex formed by reacting a compound (A) having two or more coordinating atoms that form bonds using unshared electron pairs with a copper component.

  本发明的目的是提供一种在用于生产固化薄膜时在近红外范围内具有良好屏蔽性能的近红外辐射吸收组合物、一种近红外辐射截止滤光片及其生产方法，以及一种相机模组及其生产方法。近红外辐射吸收组合物包括铜络合物，该铜络合物是由具有两个或两个以上配位原子的化合物（A）与铜成分反应形成的，该化合物具有两个或两个以上配位原子，这些配位原子利用未共享电子对形成键。
• Novel five- and six-coordinate diorganotin(IV) complexes with bis(triazol-1-yl)alkanes: linkage coordination polymers
  作者：Liang-Fu Tang、Zhi-Hong Wang、Jian-Fang Chai、Wen-Li Jia、Yu-Ming Xu、Ji-Tao Wang

  DOI：10.1016/s0277-5387(00)00457-5

  日期：2000.9

  A novel poly(triazol-1-yl)alkane ligand, bis(3,5-dimethyl-1,2,4-triazol-1-yl)methane CH2(3,5-Me(2)Tz)(2), has been synthesized under phase transfer catalytic conditions. This ligand as well as bis(1,2,4-triazol-1-yl)methane CH(2)Tz(2) and 1,2-bis(1,2,4-triazol-1-yl)ethane (CH2)(2)Tz(2) reacts with diphenyltin(IV) halides to yield novel five- and six-coordinate diorganotin complexes. The crystal structure of (CH(2)Tz(2))SnPh2Br2 determined by X-ray analysis shows that bis(triazol-1-yl)methane coordinates to the tin atom through exodentate nitrogen atoms on the 4-position of triazole rings to form linkage coordination polymers, which leads to a bridging instead of a general chelating metal coordination. Possibly owing to the hindrance of methyl groups in the triazole ring of CH2(3,5-Me(2)Tz)(2), this ligand is a weaker donor to an organotin acceptor than CH(2)Tz(2). In the hydrolysis product [SnPh2Br2(H2O)].(CH,(3,5-Me(2)Tz)(2)), the tin atom is five-coordinate with a trigonal bipyramid geometry, and the aqua ligand is simultaneously connected to the exonitrogen atoms of two adjacent CH2(3,5-Me(2)Tz) molecules through hydrogen bonding. (C) 2000 Elsevier Science Ltd. All rights reserved.
• NEAR INFRARED RADIATION-ABSORBING COMPOSITION, NEAR INFRARED RADIATION CUT-OFF FILTER AND PRODUCTION METHOD THEREFOR, AND CAMERA MODULE AND PRODUCTION METHOD THEREFOR
  申请人：FUJIFILM Corporation

  公开号：US20160304730A1

  公开（公告）日：2016-10-20

  An object of the present invention is to provide a near infrared radiation-absorbing composition having favorable shielding properties in a near infrared range when used to produce cured films, a near infrared radiation cut-off filter and a production method therefor, and a camera module and a production method therefor. The near infrared radiation-absorbing composition including a copper complex formed by reacting a compound (A) having two or more coordinating atoms that form bonds using unshared electron pairs with a copper component.
• NEAR INFRARED RAY ABSORBENT COMPOSITION, NEAR INFRARED RAY CUT FILTER, SOLID IMAGE PICKUP ELEMENT, AND CAMERA MODULE
  申请人：FUJIFILM Corporation

  公开号：US20170227690A1

  公开（公告）日：2017-08-10

  Provided are a near infrared ray absorbent composition which can form a cured film having excellent near infrared ray shielding properties, a near infrared ray cut filter, a manufacturing method of a near infrared ray cut filter, a solid image pickup element, and a camera module. The near infrared ray absorbent composition includes a copper complex that is other than a copper phthalocyanine complex and has a maximum absorption wavelength in a wavelength range of 700 to 1,200 nm and in which a molar light absorption coefficient at the maximum absorption wavelength is greater than or equal to 100 (L/mol·cm).
• NEAR INFRARED ABSORBING COMPOSITION, NEAR INFRARED CUT FILTER, METHOD OF MANUFACTURING NEAR INFRARED CUT FILTER, DEVICE, METHOD OF MANUFACTURING COPPER-CONTAINING POLYMER, AND COPPER-CONTAINING POLYMER
  申请人：FUJIFILM Corporation

  公开号：US20180094086A1

  公开（公告）日：2018-04-05

  The near infrared absorbing composition includes: a copper-containing polymer having a copper complex site at a polymer side chain; and a solvent, in which the copper complex site includes a site multidentate-coordinated to a copper atom and at least one selected from the group consisting of a site monodentate-coordinated to a copper atom and a counter ion to a copper complex skeleton, and a polymer main chain and a copper atom at the copper complex site are bonded to each other through the site monodentate-coordinated to a copper atom or the counter ion.