(7-hydroxy-2-oxoindolin-3-yl)<(13)C2>acetic acid | 110655-10-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: (7-hydroxy-2-oxoindolin-3-yl)<(13)C2>acetic acid
• CAS: 110655-10-2
• 化学式: C₁₀H₉NO₄
• 分子量: 209.164
• InChiKey: RBODBEHKWJZUBG-ARERNSRJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  15.0
• 可旋转键数：
  2.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  86.63
• 氢给体数：
  3.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  3-苄氧基-2-硝基苯基-乙酸 在 sodium hydride 、 溶剂黄146 、 锌 作用下， 反应 8.0h， 生成 (7-hydroxy-2-oxoindolin-3-yl)<(13)C2>acetic acid
  参考文献：
  名称：

  Lewer, Paul, Journal of the Chemical Society. Perkin transactions I, 1987, p. 753 - 758

  摘要：

  DOI：

文献信息

• Occurrence and metabolism of 7-hydroxy-2-indolinone-3-acetic acid in zea mays
  作者：Paul Lewer*、Robert S. Bandurski

  DOI：10.1016/s0031-9422(00)81790-2

  日期：1987.4

  7-Hydroxy-2-indolinone-3-acetic acid was identified as a catabolite of indole-3-acetic acid in germinating kernels of Zea mays and found to be present in amounts of ca 3.1 nmol/kernel. 7-Hydroxy-2-indolinone-3-acetic acid was shown to be a biosynthetic intermediate between 2-indolinone-3-acetic acid and 7-hydroxy-2-indolinone-3-acetic acid-7'-O-glucoside in both kernels and roots of Zea mays. Further metabolism of 7-hydroxy-2-[5-3H]-indolinone-3-acetic acid-7'-O-glucoside occurred to yield tritiated water plus, as yet, uncharacterized products.