| 777076-14-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 777076-14-9
• 化学式: C₂₉H₃₇F₃N₂O₂Zn
• 分子量: 568.01
• InChiKey: JTGQFFSCLLENCG-ZIDOAPPPSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N-[4-[2,6-di(propan-2-yl)phenyl]imino-5,5,5-trifluoropent-2-en-2-yl]-2,6-diethylaniline 、 diethylzinc 、 溶剂黄146 以 not given 为溶剂， 生成
  参考文献：
  名称：

  High-Activity, Single-Site Catalysts for the Alternating Copolymerization of CO₂ and Propylene Oxide

  摘要：

  Despite recent advances regarding catalysts for CO2/epoxide copolymerization, the development of high-activity catalysts for alternating polymerization of CO2 and commodity epoxides, such as propylene oxide, remains a challenge. A new class of unsymmetrically substituted beta-diiminate zinc complexes is reported that exhibits unprecedented activity for CO2/propylene oxide copolymerization. The polymers formed are of high molecular weight (Mn approximately 35 kg/mol) and have narrow polydispersities (PDI approximately 1.1), consistent with a living polymerization.

  DOI：

  10.1021/ja028071g
• 作为试剂：
  描述：

  一氧化碳 、 (R)-(+)-环氧丙烷 在 、 [(meso-tetra(4-chlorophenyl)porphyrinato)Al(THF)2](+)[Co(CO)4](-) 作用下， 以 四氢呋喃 为溶剂， 50.0 ℃ 、5.86 MPa 条件下， 反应 15.0h， 生成 (R)-4-methyloxetan-2-one
  参考文献：
  名称：

  Carbonylative Polymerization of Propylene Oxide: A Multicatalytic Approach to the Synthesis of Poly(3-Hydroxybutyrate)

  摘要：

  We report a highly efficient method for the synthesis of poly(3-hydroxybutyrate) by the carbonylative polymerization of propylene oxide. The use of compatible epoxide carbonylation and lactone polymerization catalysts allows for a one-pot reaction that eliminates the need to isolate and purify the toxic beta-butyrolactone intermediate.

  DOI：

  10.1021/ja1049862