N'-(4-aminobenzoyl)-3,4,5-trihexoxybenzohydrazide | 1365566-42-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N'-(4-aminobenzoyl)-3,4,5-trihexoxybenzohydrazide
• CAS: 1365566-42-2
• 化学式: C₃₂H₄₉N₃O₅
• 分子量: 555.758
• InChiKey: GXPUVNRWMCVGHS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  40
• 可旋转键数：
  20
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  112
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  没食子酸乙酯 在 sodium hydrogen sulfide 、 potassium carbonate 、 一水合肼 、 potassium iodide 作用下， 以 四氢呋喃 、 乙醇 、 丙酮 为溶剂， 生成 N'-(4-aminobenzoyl)-3,4,5-trihexoxybenzohydrazide
  参考文献：
  名称：

  Morphology tunable organogels based on dihydrazide derivatives

  摘要：

  We report on the organogels of a new series of compounds containing a dihydrazide unit in the rigid core and three long alkoxy chains. SEM images revealed that the morphologies of the xerogels strongly depend on the polarity of the gelling solvent. Textured spheroid-like morphologies were observed in the xerogels from low polar aromatic solvents such as benzene, whereas fibrous morphologies from ethanol. Further detailed analysis of their aggregation modes was conducted by FT-IR and X-ray diffraction measurement. The cooperation of hydrogen bonds, hydrophobic interactions and the van der Waals interactions should to be the key point of the self-assembly. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molliq.2012.07.001

文献信息

• Morphology tunable organogels based on dihydrazide derivatives
  作者：Binglian Bai、Jue Wei、Jian Zhao、Haitao Wang、Min Li

  DOI：10.1016/j.molliq.2012.07.001

  日期：2012.9

  We report on the organogels of a new series of compounds containing a dihydrazide unit in the rigid core and three long alkoxy chains. SEM images revealed that the morphologies of the xerogels strongly depend on the polarity of the gelling solvent. Textured spheroid-like morphologies were observed in the xerogels from low polar aromatic solvents such as benzene, whereas fibrous morphologies from ethanol. Further detailed analysis of their aggregation modes was conducted by FT-IR and X-ray diffraction measurement. The cooperation of hydrogen bonds, hydrophobic interactions and the van der Waals interactions should to be the key point of the self-assembly. (C) 2012 Elsevier B.V. All rights reserved.