| 191678-75-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• CAS: 191678-75-8
• 化学式: C₁₆H₃₉F₉O₉S₃Si₇
• 分子量: 839.262
• InChiKey: AGXMUHHPALZNLR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.87
• 重原子数：
  44.0
• 可旋转键数：
  12.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  130.11
• 氢给体数：
  0.0
• 氢受体数：
  9.0

反应信息

• 作为反应物：
  描述：

  在 potassium Sodium 、 phosphorus 、 lithium chloride 作用下， 以 乙醚 为溶剂， 反应 30.0h， 生成 2,2,3,3,4,5,5,6,6,7,7,8,8-Tridecamethyl-1-phospha-2,3,4,5,6,7,8-heptasila-bicyclo[2.2.2]octane
  参考文献：
  名称：

  Tridecamethyl-1-phospha- and tridecamethyl-1-arsa-2,3,4,5,6,7,8-heptasilabicyclo[2.2.2]octane

  摘要：

  The octaheterobicyclo[2.2.2]octanes MeSi(SiMe2SiMe2)(3)E(E=P, As) have been prepared in high yields (up to 50%) from the alkali metal phosphide or arsenide Na3E/K3E and the heptasilane MeSi(SiMe2SiMe2Cl)(3)[GRAPHICS]The cages were isolated by crystallization from heptane and the crystal structure of the arsenic compound was determined. The synthesis of the heptasilane MeSi(SiMe2SiMe2Cl)(3) is described too. All compounds were characterized by multinuclear NMR spectroscopy (H-1, Si-29, C-13, P-31) as well as elemental analysis.

  DOI：

  10.1016/s0022-328x(96)06822-2
• 作为产物：
  描述：

  三氟甲磺酸 、 1,1,2,2,3,4,4,5,5-Nonamethyl-1,5-diphenyl-3-(1,1,2,2-tetramethyl-2-phenyldisilanyl)pentasilane 以 正戊烷 为溶剂， 反应 2.0h， 生成
  参考文献：
  名称：

  Tridecamethyl-1-phospha- and tridecamethyl-1-arsa-2,3,4,5,6,7,8-heptasilabicyclo[2.2.2]octane

  摘要：

  The octaheterobicyclo[2.2.2]octanes MeSi(SiMe2SiMe2)(3)E(E=P, As) have been prepared in high yields (up to 50%) from the alkali metal phosphide or arsenide Na3E/K3E and the heptasilane MeSi(SiMe2SiMe2Cl)(3)[GRAPHICS]The cages were isolated by crystallization from heptane and the crystal structure of the arsenic compound was determined. The synthesis of the heptasilane MeSi(SiMe2SiMe2Cl)(3) is described too. All compounds were characterized by multinuclear NMR spectroscopy (H-1, Si-29, C-13, P-31) as well as elemental analysis.

  DOI：

  10.1016/s0022-328x(96)06822-2