1,1,2,2,3,4,4,5,5-Nonamethyl-1,5-diphenyl-3-(1,1,2,2-tetramethyl-2-phenyldisilanyl)pentasilane | 191678-74-7

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,1,2,2,3,4,4,5,5-Nonamethyl-1,5-diphenyl-3-(1,1,2,2-tetramethyl-2-phenyldisilanyl)pentasilane
• 英文别名: Tris[[dimethyl(phenyl)silyl]-dimethylsilyl]-methylsilane；tris[[dimethyl(phenyl)silyl]-dimethylsilyl]-methylsilane
• CAS: 191678-74-7
• 化学式: C₃₁H₅₄Si₇
• 分子量: 623.368
• InChiKey: BHODKCSHYUGQGE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.51
• 重原子数：
  38
• 可旋转键数：
  9
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,1,2,2,3,4,4,5,5-Nonamethyl-1,5-diphenyl-3-(1,1,2,2-tetramethyl-2-phenyldisilanyl)pentasilane 在 盐酸 、 砷化氢 、 三氯化铝 、 potassium Sodium 作用下， 反应 12.0h， 生成 2,2,3,3,4,5,5,6,6,7,7,8,8-Tridecamethyl-1-arsa-2,3,4,5,6,7,8-heptasila-bicyclo[2.2.2]octane
  参考文献：
  名称：

  Tridecamethyl-1-phospha- and tridecamethyl-1-arsa-2,3,4,5,6,7,8-heptasilabicyclo[2.2.2]octane

  摘要：

  The octaheterobicyclo[2.2.2]octanes MeSi(SiMe2SiMe2)(3)E(E=P, As) have been prepared in high yields (up to 50%) from the alkali metal phosphide or arsenide Na3E/K3E and the heptasilane MeSi(SiMe2SiMe2Cl)(3)[GRAPHICS]The cages were isolated by crystallization from heptane and the crystal structure of the arsenic compound was determined. The synthesis of the heptasilane MeSi(SiMe2SiMe2Cl)(3) is described too. All compounds were characterized by multinuclear NMR spectroscopy (H-1, Si-29, C-13, P-31) as well as elemental analysis.

  DOI：

  10.1016/s0022-328x(96)06822-2
• 作为产物：
  描述：

  二苯基四甲基二硅烷 在 lithium 作用下， 以 四氢呋喃 、 正庚烷 为溶剂， 反应 5.0h， 生成 1,1,2,2,3,4,4,5,5-Nonamethyl-1,5-diphenyl-3-(1,1,2,2-tetramethyl-2-phenyldisilanyl)pentasilane
  参考文献：
  名称：

  Tridecamethyl-1-phospha- and tridecamethyl-1-arsa-2,3,4,5,6,7,8-heptasilabicyclo[2.2.2]octane

  摘要：

  The octaheterobicyclo[2.2.2]octanes MeSi(SiMe2SiMe2)(3)E(E=P, As) have been prepared in high yields (up to 50%) from the alkali metal phosphide or arsenide Na3E/K3E and the heptasilane MeSi(SiMe2SiMe2Cl)(3)[GRAPHICS]The cages were isolated by crystallization from heptane and the crystal structure of the arsenic compound was determined. The synthesis of the heptasilane MeSi(SiMe2SiMe2Cl)(3) is described too. All compounds were characterized by multinuclear NMR spectroscopy (H-1, Si-29, C-13, P-31) as well as elemental analysis.

  DOI：

  10.1016/s0022-328x(96)06822-2

文献信息

• Dynamics of the Excited State of Polysilane Dendrimers:  Origin of the Broad Visible Emission of Branched Silicon Chains
  作者：Akira Watanabe、Masato Nanjo、Tomoyasu Sunaga、Akira Sekiguchi

  DOI：10.1021/jp010840f

  日期：2001.7.1

  The excited-state dynamics of polysilane dendrimers are studied using time-resolved emission spectroscopy. The time-resolved emission spectra of polysilane dendrimers showed two bands, one in the UV and one in the visible region. The former was assigned to the emission from the excited state at the linear Si-Si chain, and the latter was assigned to that at the branching points. The intramolecular energy

  使用时间分辨发射光谱研究了聚硅烷树枝状大分子的激发态动力学。聚硅烷树枝状大分子的时间分辨发射光谱显示出两条谱带，一条在紫外区，一条在可见光区。前者分配给线性Si-Si链的激发态发射，后者分配给分支点处的发射。两种激发态之间的分子内能量转移由发射时间曲线证明，其显示强度随着激光激发后延迟时间的增加而增加。可见光发射的光谱形状可以用高斯分布函数的拟合曲线表示，这表明配置坐标模型适用于具有分支点的Si-Si链的光物理过程。
• Tridecamethyl-1-phospha- and tridecamethyl-1-arsa-2,3,4,5,6,7,8-heptasilabicyclo[2.2.2]octane
  作者：Karl Hassler、Gerlinde M. Kollegger、Harald Siegl、Gerd Klintschar

  DOI：10.1016/s0022-328x(96)06822-2

  日期：1997.4

  The octaheterobicyclo[2.2.2]octanes MeSi(SiMe2SiMe2)(3)E(E=P, As) have been prepared in high yields (up to 50%) from the alkali metal phosphide or arsenide Na3E/K3E and the heptasilane MeSi(SiMe2SiMe2Cl)(3)[GRAPHICS]The cages were isolated by crystallization from heptane and the crystal structure of the arsenic compound was determined. The synthesis of the heptasilane MeSi(SiMe2SiMe2Cl)(3) is described too. All compounds were characterized by multinuclear NMR spectroscopy (H-1, Si-29, C-13, P-31) as well as elemental analysis.