2-hydroxymethyl-cyclooctanol | 42824-57-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-hydroxymethyl-cyclooctanol
• 英文别名: 2-(Hydroxymethyl)cyclooctanol；2-(hydroxymethyl)cyclooctan-1-ol
• CAS: 42824-57-7
• 化学式: C₉H₁₈O₂
• 分子量: 158.241
• InChiKey: FIIMYZAPDBDGHR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-氧-1-环辛烷羧酸 在 lithium aluminium tetrahydride 作用下， 生成 2-hydroxymethyl-cyclooctanol
  参考文献：
  名称：

  The Prins Reaction of Cyclooctene and Cyclododecene

  摘要：

  在40°C下，研究了硫酸催化的环八烯或环十二烯与甲醛在醋酸中缩合反应的产物。环八烯的反应产生了4,5-六亚甲基-1,3-二噁烷、2-环八烯基甲基醋酸酯和1-乙氧基-2-乙酰氧基甲基环八烷的混合物，而环十二烯的反应则产生了一些环醚，其中一个被鉴定为3-氧双环[10,3,0]-6-十五烯，其他的被估计为15-乙酸氧基-3-氧双环[9,3,1]十五烷和12,17-二氧三环[13,3,0,010,14]-2-十八烯。

  DOI：

  10.1246/bcsj.46.2512

文献信息

• Noxious-insect repellent
  申请人：Kanebo, Ltd.

  公开号：US06372804B1

  公开（公告）日：2002-04-16

  Disclosed is a method of repelling noxious insects comprising the step of exposing said noxious insects to a composition containing from 0.1 to 90 wt. %, based on the total weight of the composition, of at least one of 2-(1-hydroxyalkyl)cycloalkanols represented by the following formulae (9) and (10): wherein R4 is a straight-chain or branched, saturated or unsaturated, hydrocarbon radical having 1-8 carbon atoms and R5 and R6 are hydrogens or lower alkyl groups having at most 3 carbon atoms and the sum of the carbon atoms of R5 and R6 is 0-3.

  揭示了一种驱逐有害昆虫的方法，包括将所述有害昆虫暴露在一种组成物中，该组成物含有按照以下式（9）和（10）表示的至少一种2-(1-羟基烷基)环烷醇，其含量为总组成物重量的0.1至90重量％。其中，R4是具有1-8个碳原子的直链或支链、饱和或不饱和的烃基，R5和R6是氢或最多有3个碳原子的低碳基团，R5和R6的碳原子数之和为0-3。
• Method for the production of n-alkenyl amides
  申请人：——

  公开号：US20030036659A1

  公开（公告）日：2003-02-20

  A process for preparing N-alkenyl-amides by reacting the corresponding NH-amides with acetylenes in the liquid phase in the presence of basic alkali metal compounds and of a cocatalyst comprises using as the cocatalyst diols of the general formula (I) 1 where X is branched or unbranched alkylene selected from the group consisting of 2 where R 1 to R 6 are independently hydrogen or C 1 - to C 4 -alkyl; or branched or unbranched cyclic alkylene of 3 to 14 carbon atoms including 3 to 12 ring carbon atoms, their monoalkenyl ethers, their dialkenyl ethers or mixtures thereof.

  一种制备N-烯基酰胺的方法，包括在液相中在碱性金属化合物和辅催化剂的存在下，将相应的NH-酰胺与乙炔反应，其中所述辅催化剂为通式（I）1的二醇，其中X是从2中选择的支链或直链烷基，所述2选自以下组：其中R1至R6独立地为氢或C1至C4烷基；或者3至14个碳原子的支链或直链环烷基，包括3至12个环碳原子，它们的单烯基醚，双烯基醚或其混合物。
• PHOTOPOLYMERIZABLE VINYL ETHER BASED MONOMERIC FORMULATIONS AND POLYMERIZABLE COMPOSITIONS WHICH MAY INCLUDE CERTAIN NOVEL SPIROORTHOCARBONATES
  申请人：——

  公开号：US20020013380A1

  公开（公告）日：2002-01-31

  Photopolymerizable compositions are provided which are the reaction products of a vinyl ether, a photoinitiator system comprising an iodonium salt, a visible light sensitizer, and an electron donor compound. These monomeric/oligomeric compositions may also include epoxides, polyols, spiroorthocarbonates. One embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, a spiroorthocarbonate, and a photoinitiator system. Another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, and a photoinitiator system. Still another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, a spiroorthocarbonate, and a photoinitiator system. Still further, another embodiment of the present invention is certain novel spiroorthocarbonate compounds. Each of these novel spiroorthocarbonate compounds include at least one epoxy group as a substituent.

  提供了光聚合组合物，其为乙烯醚、包括碘化物盐、可见光敏化剂和电子供体化合物的光引发剂体系的反应产物。这些单体/低聚物组合物还可以包括环氧化合物、多元醇、螺环正交碳酸酯。本发明的一种实施例是由乙烯醚、螺环正交碳酸酯和光引发剂体系组成的聚合物组合物。本发明的另一种实施例是由乙烯醚、环氧化合物、多元醇和光引发剂体系组成的聚合物组合物。本发明的另一种实施例是由乙烯醚、环氧化合物、多元醇、螺环正交碳酸酯和光引发剂体系组成的聚合物组合物。此外，本发明的另一种实施例是某些新型螺环正交碳酸酯化合物。这些新型螺环正交碳酸酯化合物中，每个化合物都包括至少一个环氧基团作为取代基。
• Novel spiroorthocarbonates
  申请人：The Curators of the University of Missouri

  公开号：US20030119931A1

  公开（公告）日：2003-06-26

  Photopolymerizable compositions are provided which are the reaction products of a vinyl ether, a photoinitiator system comprising an iodonium salt, a visible light sensitizer, and an electron donor compound. These monomeric/oligomeric compositions may also include epoxides, polyols, spiroorthocarbonates. One embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, a spiroorthocarbonate, and a photoinitiator system. Another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, and a photoinitiator system. Still another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, a spiroorthocarbonate, and a photoinitiator system. Still further, another embodiment of the present invention is certain novel spiroorthocarbonate compounds. Each of these novel spiroorthocarbonate compounds include at least one epoxy group as a substituent.

  提供了光固化组合物，它们是乙烯醚、包含碘鎓盐、可见光敏化剂和电子供体化合物的光引发剂体系的反应产物。这些单体/低聚物组合物还可以包括环氧化物、多元醇、螺内酯碳酸酯。本发明的一种实施方式是由乙烯醚、螺内酯碳酸酯和光引发剂体系组成的聚合物组合物。本发明的另一种实施方式是由乙烯醚、环氧化物、多元醇和光引发剂体系组成的聚合物组合物。本发明的另一种实施方式是由乙烯醚、环氧化物、多元醇、螺内酯碳酸酯和光引发剂体系组成的聚合物组合物。此外，本发明的另一种实施方式是一些新型螺内酯碳酸酯化合物。这些新型螺内酯碳酸酯化合物中的每一种都包括至少一个环氧基团作为取代基。
• US6130255A
  申请人：——

  公开号：US6130255A

  公开（公告）日：2000-10-10