蒽-2,7-二醇 | 25562-10-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 中文名称: 蒽-2,7-二醇
• 英文名称: 2,7-dihydroxyanthracene
• 英文别名: anthracene-2,7-diol；Anthracen-2,7-diol；2.7-Dioxy-anthracen
• CAS: 25562-10-1
• 化学式: C₁₄H₁₀O₂
• 分子量: 210.232
• InChiKey: PUFJLBYPDDCHKP-UHFFFAOYSA-N

物化性质

• 熔点：
  280-285 °C (decomp)
• 沸点：
  475.0±18.0 °C(Predicted)
• 密度：
  1.360±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 海关编码：
  2907299090

反应信息

• 作为反应物：
  描述：

  蒽-2,7-二醇 在 苯亚硒酸酐 作用下， 以 四氢呋喃 为溶剂， 以71%的产率得到anthracene-1,2,7,8-tetraone
  参考文献：
  名称：

  U型螺旋氮杂芳烃：合成，结构和性质。

  摘要：

  报道了一系列U形螺旋氮杂芳烃的合成和性质。获得了这些螺旋氮杂芳烃的晶体结构，并且固态结构明确显示出它们的螺旋性。

  DOI：

  10.1021/acs.joc.9b02895
• 作为产物：
  描述：

  蒽 在 Oxone 、 (1,5-cyclooctadiene)(methoxy)iridium(I) dimer 、 水 、 4,4'-二叔丁基-2,2'-二吡啶 作用下， 以 四氢呋喃 、 环己烷 、 丙酮 为溶剂， 反应 21.0h， 生成 蒽-2,7-二醇
  参考文献：
  名称：

  2,7-Diborylanthracene as a Useful Building Block for Extended π-Conjugated Aromatics

  摘要：

  以Ir为催化剂的蒽的直接二硼化反应产生了2,6-和2,7-二硼化蒽的1:1混合物，可以通过重结晶分离。使用2,7-二硼化蒽进行的铃木-宫浦交叉偶联反应生成了扩展的π-共轭的2,7-取代的蒽衍生物，作为宏环的构建基块。2,7-二(4-吡啶基)蒽和[Pd(dppp)(OTf)2]的1:1混合物自组装成一个[3 + 3]宏环。

  DOI：

  10.1246/cl.2011.941

文献信息

• COMPOUND OR ITS TAUTOMER, METAL COMPLEX COMPOUND, COLORED PHOTOSENSITIVE CURING COMPOSITION, COLOR FILTER, AND PRODUCTION
  申请人：MIZUKAWA Yuki

  公开号：US20120238752A1

  公开（公告）日：2012-09-20

  Provided is a colored photosensitive curing composition useful for color filters in primary colors, including blue, green, and red, having a high molar absorption coefficient and allowing a reduction in film thickness and superior color purity and fastness. A colored photosensitive curing composition, comprising, as its colorant, a dipyrromethene-based metal complex compound obtained from a metal or metal compound and a dipyrromethene-based compound represented by the following Formula (I): wherein in Formula (I), R 1 to R 6 each independently represent a hydrogen atom or a substituent group; and R 7 represents a hydrogen or halogen atom, or an alkyl, aryl or heterocyclic group.

  提供的是一种有用于原色彩色滤光片的彩色光敏固化组合物，包括蓝色、绿色和红色，具有高摩尔吸收系数，可减少薄膜厚度，具有优越的颜色纯度和牢固度。 一种彩色光敏固化组合物，包括作为其着色剂的从金属或金属化合物获得的基于二吡咯甲烷的金属配合物化合物和由以下式（I）表示的基于二吡咯甲烷的化合物，其中在式（I）中，R1至R6各自独立地表示氢原子或取代基；R7表示氢或卤素原子，或烷基、芳基或杂环基。
• Pyridone azo compound, tautomer thereof, and colorant-containing curable composition, color filter and manufacturing method thereof
  申请人：Araki Katsumi

  公开号：US20060293405A1

  公开（公告）日：2006-12-28

  The invention provides a pyridone azo compound represented by the following Formula (I) and a tautomer thereof. R 1 , R 3 and R 4 each independently represent a hydrogen atom, an alkyl group having 1 to 21 carbon atoms, an alkenyl group having 2 to 21 carbon atoms, an aryl group having 6 to 21 carbon atoms, an aralkyl group having 7 to 21 carbon atoms, or a substituent having a hetero atom; at least one of R 1 , R 3 and R 4 represents a substituent having a hetero atom; R 3 and R 4 may be formed into a heterocycle together with a jointly bonded nitrogen atom; and R 2 represents an alkyl group having 1 to 10 carbon atoms, a methoxymethyl group, or a trifluoromethyl group. The invention further provides a colorant-containing curable composition and a color filter which contain the pyridone azo compound of Formula (I) and/or a tautomer thereof as a colorant.

  该发明提供了一种由以下式（I）表示的吡啶酮偶氮化合物及其互变异构体。其中，R1、R3和R4分别独立表示氢原子、具有1至21个碳原子的烷基基团、具有2至21个碳原子的烯基基团、具有6至21个碳原子的芳基基团、具有7至21个碳原子的芳基烷基基团或具有杂原子的取代基；R1、R3和R4中至少一个表示具有杂原子的取代基；R3和R4可以与共价键合的氮原子一起形成杂环；R2表示具有1至10个碳原子的烷基基团、甲氧基甲基基团或三氟甲基基团。该发明还提供了一种含色料的可固化组合物和一种含有式（I）中的吡啶酮偶氮化合物和/或其互变异构体作为色料的彩色滤光片。
• COLORED CURABLE COMPOSITION, COLOR FILTER AND METHOD OF PRODUCING THE SAME, AND DIPYRROMETHENE METAL COMPLEX COMPOUND AND TAUTOMER THEREOF
  申请人：MIZUKAWA Yuki

  公开号：US20120315579A1

  公开（公告）日：2012-12-13

  A colored curable composition is provided which has good developability, has excellent color purity, can be formed into a thin film, and has a high absorption coefficient. The colored curable composition includes at least one of specific dipyrromethene metal complex compounds and tautomers thereof. Also, a colored curable composition suitable for forming a color filter which is used in a liquid crystal display device or a solid-state imaging device, and a color filter using the colored curable composition and a method of producing the same are provided.

  提供一种有良好可开发性、具有优异色纯度、可形成薄膜且具有高吸收系数的着色可固化组合物。该着色可固化组合物包括至少一种特定的二吡咯甲烷金属配合物化合物和其互变异构体。此外，还提供了一种适用于形成用于液晶显示器或固态成像器件中的颜色滤光片的着色可固化组合物，以及使用该着色可固化组合物的颜色滤光片和生产方法。
• Azo compound, colorant-containing curable composition, color filter and color filter production method
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：US20040260075A1

  公开（公告）日：2004-12-23

  The present invention provides an azo compound represented by the following general formula (I) and a colorant-containing curable composition containing a binder and an azo compound represented by the following general formula (I): 1 wherein R 1 represents a C 1-21 alkyl, a C 1-10 perfluoroalkyl, a C 2-21 alkenyl, a C 1-21 aryl, a C 1-21 aralkyl, a C 1-21 alkylamino, a C 1-21 aralkylamino, a C 1-21 arylamino, methacryloylamino, or ethoxycarbonylamino; R 2 represents a single bond, —CH 2 —, —CH 2 CH 2 —, —CH 2 CH 2 CH 2 — or —CH 2 CH 2 CH 2 CH 2 —; R 3 represents H, a C 1-21 alkyl, a halogen, OH, or a C 1-21 , alkoxy; R 4 represents a C 1-21 alkyl, a C 2-21 alkenyl, a C 1-21 aryl, a C 1-21 aralkyl or additionally H in the case of the colorant-containing curable composition; R 5 represents H, a metal cation, or a cation of a nitrogen-containing compound; m=1 or 2 (additionally 0 in case of the colorant containing curable composition); and n=0 to 4.

  本发明提供了一种由以下通用式（I）表示的偶氮化合物以及包含颜料的可固化组合物，该组合物包含一种由以下通用式（I）表示的粘合剂和偶氮化合物：1其中R1代表C1-21烷基、C1-10全氟烷基、C2-21烯基、C1-21芳基、C1-21芳基烷基、C1-21烷基氨基、C1-21芳基烷基氨基、C1-21芳基氨基、甲基丙烯酰氨基或乙氧羰基氨基；R2代表单键，-CH2-，-CH2CH2-，-CH2CH2CH2-或-CH2CH2CH2CH2-；R3代表H、C1-21烷基、卤素、OH或C1-21烷氧基；R4代表C1-21烷基、C2-21烯基、C1-21芳基、C1-21芳基烷基，或在包含颜料的可固化组合物中另外表示H；R5代表H、金属阳离子或含氮化合物的阳离子；m=1或2（在包含颜料的可固化组合物中另外为0）；n=0至4。
• Azo compound, colored curable composition, color filter and manufacturing method thereof
  申请人：Aizawa Taeko

  公开号：US20070037076A1

  公开（公告）日：2007-02-15

  A pyrimidine azo compound represented by the following formula (I), or a tautomer thereof: wherein in formula (I), R 1 represents a heterocyclic group, and R 2 represents a hydrogen atom or a substituent; R 3 , R 4 , R 5 , R 6 , R 7 , and R 8 each independently represent a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, an acyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a carbamoyl group, an alkylsulphonyl group, an arylsulphonyl group, or a sulfamoyl group; and R 3 and R 4 , R 5 and R 6 ; and R 7 and R 8 may be mutually bonded to form a 5-, 6-, or 7-membered ring.

  一种由以下式（I）表示的嘧啶偶氮化合物，或其互变异构体：其中在式（I）中，R1代表一个杂环基团，R2代表氢原子或取代基；R3、R4、R5、R6、R7和R8各自独立地代表氢原子、烷基基团、烯基基团、炔基基团、芳基、杂环基团、酰基、烷氧羰基、芳氧羰基、氨基甲酰基、烷基磺酰基、芳基磺酰基或磺酰胺基；且R3和R4、R5和R6；以及R7和R8可以相互连接形成5、6或7成员环。