5,11,17,23-Tetrabromocalix[4]arene | 160976-71-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 芳基卤化物
• 英文名称: 5,11,17,23-Tetrabromocalix[4]arene
• 英文别名: 5,11,17,23-Tetrabromopentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(25),3(28),4,6,9(27),10,12,15,17,19(26),21,23-dodecaene
• CAS: 160976-71-6
• 化学式: C₂₈H₂₀Br₄
• 分子量: 676.083
• InChiKey: NXCJSULWJSWPLS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.4
• 重原子数：
  32
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  5,11,17,23-Tetrabromocalix[4]arene 在 氘代甲醇-d 、 叔丁基锂 作用下， 以 四氢呋喃 、 正戊烷 为溶剂， 生成 5,11,17,23-Tetradeuteriopentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(25),3(28),4,6,9(27),10,12,15,17,19(26),21,23-dodecaene
  参考文献：
  名称：

  Synthesis of [1.1.1.1]Metacyclophane Macrocycle

  摘要：

  Additions of organodilithium reagents to dialdehydes allow for construction of [1.1.1.1]metacyclophane macrocycle in similar to 40% yield in the ring forming step, without resort to standard high dilution techniques. The present methodology is complementary to the conventional condensations leading to phenol- and resorcinol-based cyclotetramers.

  DOI：

  10.1021/jo00104a027
• 作为产物：
  描述：

  1,3,5-三溴苯 在 磷化氢 、 正丁基锂 、 碘 、 叔丁基锂 作用下， 以 四氢呋喃 、 乙醚 、 正己烷 、 溶剂黄146 、 正戊烷 为溶剂， 反应 108.5h， 生成 5,11,17,23-Tetrabromocalix[4]arene
  参考文献：
  名称：

  Synthesis of [1.1.1.1]Metacyclophane Macrocycle

  摘要：

  Additions of organodilithium reagents to dialdehydes allow for construction of [1.1.1.1]metacyclophane macrocycle in similar to 40% yield in the ring forming step, without resort to standard high dilution techniques. The present methodology is complementary to the conventional condensations leading to phenol- and resorcinol-based cyclotetramers.

  DOI：

  10.1021/jo00104a027

文献信息

• Rajca Andrzej, Padmakumar Radhavaukaimal, Smithhisler Donald J., Desai Sh+, J. Org. Chem, 59 (1994) N 25, S 7701- 7703
  作者：Rajca Andrzej, Padmakumar Radhavaukaimal, Smithhisler Donald J., Desai Sh+

  DOI：——

  日期：——
• ORGANIC LIGHT EMITTING DISPLAY DEVICES AND METHODS OF MANUFACTURING ORGANIC LIGHT EMITTING DISPLAY DEVICES
  申请人：Lim Jin-O

  公开号：US20130001530A1

  公开（公告）日：2013-01-03

  An organic light emitting display device comprising a first electrode; a hole transport layer, an emitting layer and an electron transport layer disposed sequentially on the first electrode; and a second electrode formed on the electron transport layer, wherein the emitting layer comprises a host material comprising a calixarene compound represented by Chemical Formula (1) wherein, in the Chemical Formula (1), each of R 1 to R 4 independently represents hydrogen, deuterium, a substituted or unsubstituted C 1 -C 50 alkyl group, a substituted or unsubstituted C 3 -C 50 cycloalkyl group, a substituted or unsubstituted C 1 -C 50 alkoxy group, a substituted or unsubstituted C 5 -C 50 aryloxy group, a substituted or unsubstituted C 5 -C 50 arylthio group, a unsubstituted C 6 -C 60 aryl group, a C 6 -C 60 aryl group substituted with an aryl group, a C 6 -C 60 aryl group substituted with a polyaromatic group, a C 5 -C 50 amino group substituted with an aryl group, a C 4 -C 60 unsubstituted heteroaryl group, a C 4 -C 60 heteroaryl group substituted with an aryl group, a C 6 -C 60 unsubstituted and condensed polyaromatic group, a C 6 -C 60 unsubstituted and non-condensed polyaromatic group, a C 6 -C 60 condensed polyaromatic group substituted with an aromatic group, a C 6 -C 60 non-condensed polyaromatic group substituted with an aromatic group, a cyano group, a nitro group, a hydroxyl group or a carboxylic group and a dopant material and an method producing the same.
• US9203031B2
  申请人：——

  公开号：US9203031B2

  公开（公告）日：2015-12-01
• Synthesis of [1.1.1.1]Metacyclophane Macrocycle
  作者：Andrzej Rajca、Raghavakaimal Padmakumar、Donald J. Smithhisler、Shailesh R. Desai、Charles R. Ross、John J. Stezowski

  DOI：10.1021/jo00104a027

  日期：1994.12

  Additions of organodilithium reagents to dialdehydes allow for construction of [1.1.1.1]metacyclophane macrocycle in similar to 40% yield in the ring forming step, without resort to standard high dilution techniques. The present methodology is complementary to the conventional condensations leading to phenol- and resorcinol-based cyclotetramers.