1-Methoxymethyl-3-methyl-2-imidazolidinon | 6200-20-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑烷类
• 英文名称: 1-Methoxymethyl-3-methyl-2-imidazolidinon
• 英文别名: 1-(Methoxymethyl)-3-methylimidazolidin-2-one
• CAS: 6200-20-0
• 化学式: C₆H₁₂N₂O₂
• 分子量: 144.173
• InChiKey: GKWFIHKRSBCSMW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.5
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  32.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-Methoxymethyl-3-methyl-2-imidazolidinon 在 potassium tert-butylate 、 氢溴酸 作用下， 以 四氢呋喃 为溶剂， 反应 4.17h， 生成 1-Methyl-3-(2-phenylvinyl)-2-imidazolidinon
  参考文献：
  名称：

  Reuther, Wolfgang; Ruland, Alfred, Liebigs Annalen der Chemie, 1982, # 2, p. 372 - 375

  摘要：

  DOI：

文献信息

• 1,3-Dialkyl-2-imidazolidinones and a manufacturing process therefor
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP0992497A1

  公开（公告）日：2000-04-12

  1,3-dialkyl-2-imidazolidinones are made by a process involving a direct one-step reaction from industrially available alkylene carbonate, N-alkylethanolamine or 1,2-diol; the process can minimize formation of solid material and can be readily conducted in a large-scale industrial production with high yield and few byproducts. The process is characterized in that alkylene carbonate, N-alkylethanolamine or 1,2-diol is reacted with monoalkylamine and carbon dioxide, alkylcarbamate alkylamine salt, and/or 1,3-dialkyurea, by heating them at 50°C or higher in a reactor whose area in contact with at least part of the reactants and/or products is made of a metal comprising titanium or zirconium and/or an oxide thereof, or an inorganic glass.

  1,3-二烷基-2-咪唑烷酮是由工业上可获得的碳酸亚烷基酯、N-烷基乙醇胺或 1,2-二醇直接一步反应制得的；该工艺可最大限度地减少固体物质的形成，并易于进行大规模工业生产，产量高，副产品少。该工艺的特点是：碳酸亚烷基酯、N-烷基乙醇胺或 1,2-二醇与单烷基胺和二氧化碳、烷基氨基甲酸酯烷基胺盐和/或 1,3-二基脲在 50°C 或更高温度下在反应器中加热反应，反应器与至少部分反应物和/或产物接触的区域由钛或锆和/或其氧化物组成的金属或无机玻璃制成。
• 1,3-dialkyl-2-imidazolidinones and a manufacturing process therefor
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP1148051A2

  公开（公告）日：2001-10-24

  1,3-dialkyl-2-imidazolidinones are made by a process involving a direct one-step reaction from industrially available alkylene carbonate, N-alkylethanolamine or 1,2-diol; the process can minimize formation of solid material and can be readily conducted in a large-scale industrial production with high yield and few byproducts. The process is characterized in that alkylene carbonate, N-alkylethanolamine or 1,2-diol is reacted with monoalkylamine and carbon dioxide, alkylcarbamate alkylamine salt, and/or 1,3-dialkyurea, by heating them at 50°C or higher in a reactor whose area in contact with at least part of the reactants and/or products is made of a metal comprising titanium or zirconium and/or an oxide thereof, or an inorganic glass.

  1,3-二烷基-2-咪唑烷酮是由工业上可获得的碳酸亚烷基酯、N-烷基乙醇胺或 1,2-二醇直接一步反应制得的；该工艺可最大限度地减少固体物质的形成，并易于进行大规模工业生产，产量高，副产品少。该工艺的特点是：碳酸亚烷基酯、N-烷基乙醇胺或 1,2-二醇与单烷基胺和二氧化碳、烷基氨基甲酸酯烷基胺盐和/或 1,3-二基脲在 50°C 或更高温度下在反应器中加热反应，反应器与至少部分反应物和/或产物接触的区域由钛或锆和/或其氧化物组成的金属或无机玻璃制成。
• RESIST COMPOSITION, METHOD FOR FORMING RESIST PATTERN, AND POLYPHENOL COMPOUND USED THEREIN
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：EP3279190A1

  公开（公告）日：2018-02-07

  The present invention is a compound represented by the following general formula (1).

  本发明是由以下通式（1）代表的化合物。
• Manufactoring process for 1,3-Dialkyl-2-imidazolinones
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP0992497B1

  公开（公告）日：2003-12-17
• US6492528B1
  申请人：——

  公开号：US6492528B1

  公开（公告）日：2002-12-10