N，N'-二庚基-3,4,9,10-per二羧酰亚胺 | 95689-91-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 中文名称: N，N'-二庚基-3,4,9,10-per二羧酰亚胺
• 中文别名: N,N'-双(N-庚基)-3,4,9,10-二甲酰亚胺；N,N'-双(N-庚基)-3,4,9,1-二甲酰亚胺
• 英文名称: N,N'-diheptyl-3,4,9,10-perylenebiscarboximide
• 英文别名: HepPTC；7,18-diheptyl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone
• CAS: 95689-91-1
• 化学式: C₃₈H₃₈N₂O₄
• 分子量: 586.731
• InChiKey: WXLGICNTPAGZCR-UHFFFAOYSA-N

物化性质

• 熔点：
  207-214°C

计算性质

• 辛醇/水分配系数(LogP)：
  9.5
• 重原子数：
  44
• 可旋转键数：
  12
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  74.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  庚胺 、 3,4,9,10-苝四羧酸二酐 以 水 为溶剂， 反应 24.33h， 生成 N，N'-二庚基-3,4,9,10-per二羧酰亚胺
  参考文献：
  名称：

  绿色环保高效合成synthesis和萘二酰亚胺

  摘要：

  绿色的一锅法水热路线可定量生成高纯度的荧光双酰亚胺染料，而无需催化剂或有机溶剂。

  DOI：

  10.1039/c6cc06567h

文献信息

• Flexible fabric antenna system comprising conductive polymers and method of making same
  申请人：University of Connecticut

  公开号：US11043728B2

  公开（公告）日：2021-06-22

  Disclosed herein are flexible metal-free antenna systems using fabric coated with electrically conductive polymers.

  本文公开了使用涂有导电聚合物的织物的柔性无金属天线系统。
• Organic Field-effect Transistors based on Disubstituted Perylene Diimides: Effect of Alkyl Chains on the Device Performance
  作者：Alexander V. Mumyatov、Lidiya I. Leshanskaya、Denis V. Anokhin、Nadezhda N. Dremova、Pavel A. Troshin

  DOI：10.1016/j.mencom.2014.09.020

  日期：2014.9

  The preparation and systematic investigation of n-type semiconductor materials based on disubstituted perylene diimides (PDIs) possessing alkyl chains with variable length (from C-4 to C-12) are reported. It was shown that electrical characteristics of field-effect transistors can be tuned by changing the length of the alkyl chains in the PDIs used as semiconductor materials.
• Liquid Crystalline Perylene Diimides:  Architecture and Charge Carrier Mobilities
  作者：Corien W. Struijk、Alexander B. Sieval、Jarno E. J. Dakhorst、Marinus van Dijk、Peter Kimkes、Rob B. M. Koehorst、Harry Donker、Tjeerd J. Schaafsma、Stephen J. Picken、Anick M. van de Craats、John M. Warman、Han Zuilhof、Ernst J. R. Sudhölter

  DOI：10.1021/ja000991g

  日期：2000.11.1

  The phase behavior of three N-alkyl-substituted perylene diimide derivatives is examined by differential scanning calorimetry and polarized optical microscopy. The occurrence of multiple phase transitions indicates several crystalline and several liquid crystalline phases. X-ray diffraction measurements show that the liquid crystalline phases display high structural ordering in all three dimensions: smectic layers are formed, and within these smectic layers an additional ordering in columns is observed. Molecular modeling confirms this result and substantiates smectic ordering with interdigitating alkyl chains that determine the distance between the smectic layers. The ordering in columns is favored by pi-pi interactions between the cofacially oriented perylene molecules and by the elliptic shape of the molecule. Finally, intermolecular dipole-dipole interactions between the carbonyl groups of the imide moieties cause the perylene molecules to orient on average with a slight rotation between neighboring molecules within a columnar stack. Following the determination of the electronic transition dipole moment, this orientation, which still involves substantial pi-pi interactions, could be confirmed by UV/vis spectroscopy of perylene aggregates. To gauge the potential of these materials as organic semiconductors, the charge carrier mobility of one of the perylene derivatives has been measured by pulse-radiolysis time-resolved microwave conductivity. A value in excess of 0.1 cm(2) V-1 s(-1) is found in the liquid crystalline phase, and a value in excess of 0.2 cm(2) V-1 s(-1) is found for the crystalline phase. These values are comparable with the highest values previously found for other discotic materials.
• NAPHTHALENEHYDRAZAMIMIDES AND PERYLENEHYDRAZAMIMIDES
  申请人：Ciba Specialty Chemicals Holding Inc.

  公开号：EP1141140B1

  公开（公告）日：2002-09-04
• CONDUCTIVE POLYMER ELECTRODES, WIRING ELEMENTS, AND USE THEREOF IN HEALTH AND SPORTS MONITORING
  申请人：University of Connecticut

  公开号：US20180014780A1

  公开（公告）日：2018-01-18

  Disclosed herein are conductive polymer electrodes and wiring elements for use as the conductive element in health monitoring applications, and more specifically to conductive polymer fabric electrodes or conductive polymer fabric wiring elements for use as the conductive element in pads for health monitoring applications and other wearable monitoring systems.