(Z)-2,6-dimethylocta-5,7-diene-2,3-diol | 132004-45-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (Z)-2,6-dimethylocta-5,7-diene-2,3-diol
• 英文别名: (5Z)-2,6-dimethyl-5,7-octadiene-2,3-diol；(5Z)-2,6-dimethylocta-5,7-diene-2,3-diol
• CAS: 132004-45-6
• 化学式: C₁₀H₁₈O₂
• 分子量: 170.252
• InChiKey: BTHAWHOTHGQIKC-VURMDHGXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (Z)-2,6-dimethylocta-5,7-diene-2,3-diol 、 丙酮 在 对甲苯磺酸 作用下， 反应 12.0h， 以2 mg的产率得到2,2,4,4-Tetramethyl-5-((Z)-3-methyl-penta-2,4-dienyl)-[1,3]dioxolane
  参考文献：
  名称：

  来自 Aster bakeranus 的单萜

  摘要：

  摘要 Aster bakeranus 的地上部分提供了 6,7-dihydroxy-6,7-dihydro-cis-ocimene。

  DOI：

  10.1016/0031-9422(83)80244-1
• 作为产物：
  描述：

  Carbonic acid (E)-6,7-dihydroxy-3,7-dimethyl-oct-2-enyl ester ethyl ester 在 palladium diacetate 吡啶 、 sodium methylate 、 三苯基膦 作用下， 反应 41.0h， 生成 (Z)-2,6-dimethylocta-5,7-diene-2,3-diol
  参考文献：
  名称：

  钯（0）催化合成顺式和反式芳基氧化物

  摘要：

  在Pd 2（dba）3与各种配体结合存在下，由（Z）-或（E）-6,7-二羟基-3,7-二甲基-辛-2-烯基碳酸酯获得芳樟醇氧化物。

  DOI：

  10.1016/s0040-4020(97)00130-0

文献信息

• USE OF ESSENTIAL OILS, SUPERCRITICAL EXTRACTS AND AQUEOUS RESIDUES GENERATED DURING A PROCESS FOR OBTAINING ORGANIC EXTRACTS FROM THE ARTEMISIA ABSINTHIUM L PLANT
  申请人：Consejo Superior De Investigaciones Científicas (CSIC)

  公开号：EP2826372A1

  公开（公告）日：2015-01-21

  The present invention starts with a method for obtaining organic extracts of the Artemisia absinthium L. plant, which includes: a methodology phase for producing said plant, an extraction phase during which said essential oil and a non-volatile extract are obtained, and a phase of extracting supercritical extracts with CO2, and refers specifically to the use of the essential oil and/or the supercritical extract extracted as fungicides against phytopathogenic fungi. For said purpose, the Artemisia absinthium L. plant is used, specifically the Candial variety from Teruel and/or Sierra Nevada in Spain. The present invention also relates to the aqueous residue generated during said method, which includes an organic compound which in turn contains (Z)-2,6-dimethylocta-5,7-diene-2,3-diol as an active organic compound against nematodes. The method for obtaining said organic portion and the corresponding active organic component thereof is protected by the present application.

  本发明首先提出了一种获得苦艾蒿有机萃取物的方法，该方法包括：生产苦艾蒿的方法阶段，获得精油和非挥发性萃取物的萃取阶段，以及用二氧化碳萃取超临界萃取物的阶段，具体是指将萃取的精油和/或超临界萃取物用作杀真菌剂，以对抗植物病原真菌。为此，本发明使用了苦艾蒿（Artemisia absinthium L.）植物，特别是来自西班牙特鲁埃尔（Teruel）和/或内华达山脉（Sierra Nevada）的坎迪亚尔（Candial）品种。本发明还涉及在上述方法中产生的水性残留物，其中包括一种有机化合物，该有机化合物又含有 (Z)-2,6-dimethylocta-5,7-diene-2,3-diol 作为抗线虫的活性有机化合物。获得所述有机部分及其相应活性有机成分的方法受本申请保护。
• Anisimov, A. V.; Chau, Fan Len; Tarakanova, A. V., Journal of Organic Chemistry USSR (English Translation), 1992, vol. 28, # 7.1, p. 1105 - 1108
  作者：Anisimov, A. V.、Chau, Fan Len、Tarakanova, A. V.、Lebedev, M. Yu.、Berentsveig, V. V.

  DOI：——

  日期：——
• USE OF ESSENTIAL OILS, SUPERCRITICAL EXTRACTS AND AQUEOUS RESIDUES GENERATED DURING A PROCESS FOR OBTAINING ORGANIC EXTRACTS FROM THE ARTEMISIA ABSINTHIUM L. PLANT
  申请人：González Coloma Azucena

  公开号：US20150030706A1

  公开（公告）日：2015-01-29

  The present invention starts with a method for obtaining organic extracts of the Artemisia absinthium L. plant, which includes: a methodology phase for producing said plant, an extraction phase during which said essential oil and a non-volatile extract are obtained, and a phase of extracting supercritical extracts with CO 2 , and refers specifically to the use of the essential oil and/or the supercritical extract extracted as fungicides against phytopathogenic fungi. For said purpose, the Artemisia absinthium L. plant is used, specifically the Candial variety from Teruel and/or Sierra Nevada in Spain. The present invention also relates to the aqueous residue generated during said method, which includes an organic compound which in turn contains (Z)-2,6-dimethylocta-5,7-diene-2,3-diol as an active organic compound against nematodes. The method for obtaining said organic portion and the corresponding active organic component thereof is protected by the present application.
• [EN] USE OF ESSENTIAL OILS, SUPERCRITICAL EXTRACTS AND AQUEOUS RESIDUES GENERATED DURING A PROCESS FOR OBTAINING ORGANIC EXTRACTS FROM THE ARTEMISIA ABSINTHIUM L. PLANT<br/>[ES] USO DE ACEITES ESENCIALES, EXTRACTOS SUPERCRÍTICOS Y RESIDUOS ACUOSOS GENERADOS EN UN PROCESO DE OBTENCIÓN DE EXTRACTOS ORGÁNICOS DE LA PLANTA ARTEMISIA ABSINTHIUM L<br/>[FR] UTILISATION D'HUILES ESSENTIELLES, D'EXTRAITS SUPERCRITIQUES ET DE RÉSIDUS AQUEUX PRODUITS LORS D'UN PROCESSUS D'OBTENTION D'EXTRAITS ORGANIQUES DE LA PLANTE ARTEMISIA ABSINTHIUM L
  申请人：CONSEJO SUPERIOR INVESTIGACION

  公开号：WO2013135915A1

  公开（公告）日：2013-09-19

  La presente invención parte de un procedimiento de obtención de extractos orgánicos de la planta Artemisia absinthium L., que comprende: una fase de metodología de producción de dicha planta, una fase de extracción en la que se obtiene dicho aceite esencial y un extracto no volátil, y una fase de extracción con CO2 de extractos supercríticos, y se refiere concretamente al uso del aceite esencial y/o del extracto supercrítico extraídos como fungicida frente a hongos fitopatógenos. Para ello se emplea la planta Artemisiaabsinthium L., variedad Candial procedente de Teruel y/o de Sierra Nevada. También es otro objeto de la presente memoria el residuo acuoso generado en dicho procedimiento que comprende un componente orgánico que contiene a su vez (Z) -2, 6-dimetillocta-5, 7-diene-2, 3- diol como compuesto orgánico activo frente a los nemátodos. El método de obtención de dicha parte orgánica y de su correspondiente componente orgánico activo es objeto de rotección de esta solicitud.