2-benzyl-2-N,N-dimethylamino-1-[4-piperazinophenyl]-1-butanone | 886463-08-7

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 直链 1,3-二芳基丙烷
• 英文名称: 2-benzyl-2-N,N-dimethylamino-1-[4-piperazinophenyl]-1-butanone
• 英文别名: 2-Benzyl-2-(dimethylamino)-1-(4-piperazin-1-ylphenyl)butan-1-one
• CAS: 886463-08-7
• 化学式: C₂₃H₃₁N₃O
• 分子量: 365.519
• InChiKey: LVQOALLLRKRQRK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  27
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  35.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  乙氧基化三羟甲基丙烷三丙烯酸酯 、 2-benzyl-2-N,N-dimethylamino-1-[4-piperazinophenyl]-1-butanone 反应 7.0h， 以57 g的产率得到
  参考文献：
  名称：

  TW2019/43706

  摘要：

  公开号：
• 作为产物：
  描述：

  2-dimethylamino-1-4-fluorophenyl-1-butanone 在 potassium carbonate 作用下， 以 二甲基亚砜 、 异丙醇 为溶剂， 反应 27.0h， 生成 2-benzyl-2-N,N-dimethylamino-1-[4-piperazinophenyl]-1-butanone
  参考文献：
  名称：

  TW2019/43706

  摘要：

  公开号：

文献信息

• TRI-FUNCTIONAL UV-ABSORBING COMPOUNDS AND USE THEREOF
  申请人：Domschke Angelika Maria

  公开号：US20100168359A1

  公开（公告）日：2010-07-01

  Described herein are tri-functional compounds useful in the production of ophthalmic lenses. The compounds are composed of UV absorber having a polymerization initiator directly or indirectly bonded to the ultraviolet absorber, and an olefinic group directly or indirectly bonded to the ultraviolet absorber. Also described herein are polymers and ophthalmic lenses produced from the tri-functional compounds described herein.

  本文描述了一种在生产眼镜镜片中有用的三功能化合物。这些化合物由具有聚合引发剂直接或间接连接到紫外线吸收剂的UV吸收剂以及直接或间接连接到紫外线吸收剂的烯烃基组成。本文还描述了从所述三功能化合物制备的聚合物和眼镜镜片。
• Piperazino Based Photoinitiators
  申请人：Herlihy Lawrence Shaun

  公开号：US20080045620A1

  公开（公告）日：2008-02-21

  Compounds of formula (I): [where: the substituents R 1 are individually selected from C 1 -C 10 alkyl groups and optionally substituted benzyl groups; the substituents R 2 are individually selected from alkyl groups or, together with the nitrogen atom to which they are attached, represent a nitrogen-containing heterocyclic group; Z is selected from C 6 -C 10 arylene groups groups of formula —(CHR 3 ) n —, where R 3 is hydrogen, hydroxy or a C 1 -C 4 alkyl group, and n is 0 to 6; Y is carbonyl or a residue of a mono- or poly-hydroxy compound; and x is 1 to 6; and esters thereof] are useful as multi-functional photoinitiators for use in coating compositions to be cured by radiant energy.

  公式（I）的化合物：[其中：取代基R1分别选自C1-C10烷基和可选取代苯基；取代基R2分别选自烷基或与它们连接的氮原子一起表示含氮杂环基团；Z选自C6-C10芳基烷基团的公式-（CHR3）n-，其中R3为氢，羟基或C1-C4烷基，n为0到6；Y为羰基或单或多羟基化合物的残基；x为1到6；以及它们的酯]在由辐射能固化的涂料组合物中作为多功能光引发剂是有用的。
• MICHAEL ADDITION REACTION PRODUCT AND ACTIVE ENERGY RAY-CURABLE COMPOSITION
  申请人：Fabian Kutzner

  公开号：US20120190846A1

  公开（公告）日：2012-07-26

  The present invention provides a Michael addition reaction product between a specified compound having a group which functions as a Michael donor and a monomer or polymer having a group which functions as a Michael acceptor, a photoinitiator containing the Michael addition reaction product, and an active energy ray-curable composition containing the photoinitiator. The compound having a group functioning as a Michael donor used in the present invention is a phenyl ketone derivative and is characterized by having an amino group or a mercapto group as the group functioning as a Michael donor.

  本发明提供了一种迈克尔加成反应产物，其由具有作为迈克尔供体的基团的特定化合物和具有作为迈克尔受体的基团的单体或聚合物之间的反应产生，其中包含迈克尔加成反应产物的光引发剂以及含有该光引发剂的活性能量射线可固化组合物。本发明中使用的具有作为迈克尔供体的基团的化合物是苯基酮衍生物，其特点是具有氨基基团或巯基基团作为作为迈克尔供体的基团。
• Fluorine-containing acetophenone derivative, fluroine based additive, curable composition including same, and cured product thereof
  申请人：DIC Corporation

  公开号：US10961405B2

  公开（公告）日：2021-03-30

  The invention provides a fluorine-containing acetophenone derivative which is useful as an additive that can impart excellent antifouling properties and scratch resistance to the surface of a cured coating and that also offers high transparency of the coating; a fluoroadditive and an active energy ray curable composition which each include the above derivative; a cured product of the composition; and an article having a cured coating of the composition. Specifically, this object is achieved by using a fluorine-containing acetophenone derivative, typically represented by the structural formula below, that is obtained by introducing an acryloyl group into a poly(perfluoroalkylene ether) chain and thereafter introducing, using Michael addition reaction, an α-aminoacetophenone-based structural unit capable of generating radical species by photocleavage

  本发明提供了一种含氟苯乙酮衍生物，该衍生物可用作添加剂，可赋予固化涂层表面优异的防污性能和抗划伤性，还可提供涂层的高透明度；一种氟添加剂和一种活性能量射线固化组合物，其中均包括上述衍生物；一种该组合物的固化产品；以及一种具有该组合物固化涂层的物品。具体地说，这一目标是通过使用含氟苯乙酮衍生物来实现的，该衍生物通常由以下结构式表示，它是通过将丙烯酰基引入聚（全氟烷基醚）链，然后利用迈克尔加成反应引入能够通过光裂解产生自由基的α-氨基苯乙酮结构单元而得到的
• WO2006/82477
  申请人：——

  公开号：——

  公开（公告）日：——