4,4'-dinitrodifurazanyl ether | 152845-81-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4,4'-dinitrodifurazanyl ether
• 英文别名: 4,4'-di(3-nitrofurazanyl) ether；1,2,5-Oxadiazole, 3,3'-oxybis[4-nitro-；3-nitro-4-[(4-nitro-1,2,5-oxadiazol-3-yl)oxy]-1,2,5-oxadiazole
• CAS: 152845-81-3
• 化学式: C₄N₆O₇
• 分子量: 244.08
• InChiKey: RBJTZDYBYKLCGS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.1
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  179
• 氢给体数：
  0
• 氢受体数：
  11

反应信息

• 作为反应物：
  描述：

  4,4'-dinitrodifurazanyl ether 在 氨 作用下， 以 苯 为溶剂， 125.0 ℃ 、1.52 MPa 条件下， 生成 3,4-二氨基呋扎
  参考文献：
  名称：

  摘要：

  The reactions of 3-nitro-4-R-furazans with ammonia were studied. The effect of the substituent R on the specific features of the nucleophilic substitution reaction observed was considered. The nitro group attached to the furazan ring can act as both the leaving group and the activating group facilitating the displacement of the second substituent (for example, OR' or N(NO2)R').

  DOI：

  10.1023/a:1020931511013
• 作为产物：
  描述：

  3,4-dinitrofurazan 在 sodium hydroxide 作用下， 以 乙腈 为溶剂， 反应 0.33h， 以51%的产率得到3-hydroxy-4-nitrofurazan
  参考文献：
  名称：

  Sheremetev; Kharitonova; Mantseva, Russian Journal of Organic Chemistry, 1999, vol. 35, # 10, p. 1525 - 1537

  摘要：

  DOI：

文献信息

• Synthesis and X-Ray Crystal Structure of Bis-3,3′-(nitro-NNO-azoxy)-difurazanyl Ether
  作者：Aleksei B. Sheremetev、Sergei E. Semenov、Vladimir S. Kuzmin、Yurii A. Strelenko、Sema L. Ioffe

  DOI：10.1002/(sici)1521-3765(19980615)4:6<1023::aid-chem1023>3.0.co;2-r

  日期：1998.6.15

  Two approaches to the synthesis of bis-3,3'-(nitro-NNO-azoxy)difurazanyl ether 2 have been tested, that is, varying the sequence of the introduction of the nitro-NNO-azoxy group and ether bridge. Difurazanyl ether formation through base-promoted transformation of nitrofurazans has been studied in which the nitro groups were activated by ortho electron-withdrawing substituents such as nitro-NNO-azoxy and tert-butyl-NNO-azoxy groups. The nitro-NNO-azoxy group was formed by destructive N-nitration of the tert-butyl-NNO-azoxy group. The X-ray crystal structure of 2 is reported.
• ——
  作者：A. B. Sheremetev、E. V. Mantseva、D. E. Dmitriev、F. S. Sirovskii

  DOI：10.1023/a:1015820318686

  日期：——

  The reactions of 4,4'-dinitrodifurazanyl ether 1 with Na salts of hydroxyfurazans 2a-e were studied. The nitrofurazanyl fragment is replaced by the more nucleophilic R-furazanyl group; the observed transetherification affords unsymmetrical derivatives of difurazanyl ether. The ratio of the rate constants for the successive reaction steps was determined.
• ——
  作者：A. B. Sheremetev、V. O. Kulagina、I. A. Kryazhevskikh、T. M. Melnikova、N. S. Aleksandrova

  DOI：10.1023/a:1020931511013

  日期：——

  The reactions of 3-nitro-4-R-furazans with ammonia were studied. The effect of the substituent R on the specific features of the nucleophilic substitution reaction observed was considered. The nitro group attached to the furazan ring can act as both the leaving group and the activating group facilitating the displacement of the second substituent (for example, OR' or N(NO2)R').
• Sheremetev; Kharitonova; Mantseva, Russian Journal of Organic Chemistry, 1999, vol. 35, # 10, p. 1525 - 1537
  作者：Sheremetev、Kharitonova、Mantseva、Kulagina、Shatunova、Aleksandrova、Mel'nikova、Ivanova、Dmitriev、Eman、Yudin、Kuz'min、Strelenko、Novikova、Lebedev、Khmel'nitskii

  DOI：——

  日期：——