(+/-)-trans-cyclooctane-1,3-diol | 18952-35-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (+/-)-trans-cyclooctane-1,3-diol
• 英文别名: (+/-)-trans-Cyclooctan-1,3-diol；(1R,3R)-cyclooctane-1,3-diol
• CAS: 18952-35-7；101935-36-8
• 化学式: C₈H₁₆O₂
• 分子量: 144.214
• InChiKey: DNJRSNYMHOVSGB-HTQZYQBOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (+/-)-trans-cyclooctane-1,3-diol 生成 cis-Cyclooctan-1,3-diol
  参考文献：
  名称：

  Proximity Effects. IX. Solvolysis of trans-Cycloöctene Oxide

  摘要：

  DOI：

  10.1021/ja01571a075
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 乙醇 、 镍 作用下， 125.0 ℃ 、8.83 MPa 条件下， 生成 (1R,2R)-1,2-环辛烷二醇 、 (+/-)-trans-cyclooctane-1,3-diol
  参考文献：
  名称：

  Proximity Effects. IX. Solvolysis of trans-Cycloöctene Oxide

  摘要：

  DOI：

  10.1021/ja01571a075

文献信息

• Process for producing catalyst component for addition polymerization, catalyst for addition polymerization, and process for producing addition polymer
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2048168A2

  公开（公告）日：2009-04-15

  A process for producing an electron withdrawing group-containing metal compound (I) comprising contacting the following compounds (d), (e) and (f): (d) a compound of formula [4]:          M2L2d     [4] (e) a compound of formula [5]:          R3r-1T2H     |5], and (f) a compound of formula [6]:          R4(J2He-1)f     [6] wherein M2 represents an atom of Group XII, Groups III to XI or the lanthanide series of the Periodic Table; d represents a valence of M2; L2 represents a hydrogen atom, a halogen atom or a hydrocarbon group; when a plural number of L2's exist, they may be the same as or different from each other; R3 represents an electron-withdrawing group or a group containing an electron-withdrawing group; when a plural number of R3's exist, they may be the same as or different from each other; R4 represents an organic group having a valence of f; T2 and J2 each independently represent an atom of Group XV or XVI of the Periodic Table; r represents a valence of T2; e represents a valence of J2; and "f" is an integer of 2 to 10.

  一种生产含电子取基金属化合物(I)的工艺，包括将下列化合物(d)、(e)和(f)接触： (d) 式 [4] 的化合物： M2L2d [4］ (e) 式 [5] 的化合物： R3r-1T2H |5]、 和 (f) 式 [6] 的化合物： R4(J2He-1)f [6] 化合物 其中 M2 代表第 XII 族、第 III 至 XI 族或元素周期表中镧系元素的原子；d 代表 M2 的化合价；L2 代表氢原子、卤素原子或碳氢基团；当存在多个 L2 时，它们可以彼此相同或不同；R3 代表抽电子基团或含有抽电子基团的基团；R4 代表价数为 f 的有机基团；T2 和 J2 各自独立地代表元素周期表第 XV 或 XVI 族的原子；r 代表 T2 的价数；e 代表 J2 的价数；"f "为 2 至 10 的整数。
• First catalyst component for addition polymerization, catalyst for addition polymerization, and process for producing addition polymer
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2048167A2

  公开（公告）日：2009-04-15

  An electron withdrawing group-containing metal compound (I) of the formula [7]: wherein M3 represents an atom of Group XII, Groups III to XI or the lanthanide series of the Periodic Table; when a plural number of M3's exist, they may be the same as or different from each other; T3 represents an atom of Group XIV, XV or XVI of the Periodic Table; when a plural number of T3's exist, they may be the same as or different from each other; R5 represents an electron-withdrawing group or a group containing an electron-withdrawing group; when a plural number of R5's exist, they may be the same as or different from each other; R6 represents a hydrocarbon group; when a plural number of R6's exist they may be the same as or different from each other; "g" represents a valence of M3; "s" represents a valence of T3; and "h" represents a number of 1 or more.

  式[7]的含电子萃取基团的金属化合物（I）： 其中 M3 代表元素周期表中第 XII 族、第 III 族至第 XI 族或镧系元素的原子；当存在多个 M3 时，它们可以彼此相同或不同；T3 代表元素周期表中第 XIV 族、第 XV 族或第 XVI 族的原子；当存在多个 T3 时，它们可以彼此相同或不同；R5 代表抽电子基团或含有抽电子基团的基团；当存在多个 R5 时，它们可以彼此相同或不同；R6 代表烃基；当存在多个 R6 时，它们可以彼此相同或不同；"g "代表 M3 的化合价；"s "代表 T3 的化合价；"h "代表 1 或以上的数字。
• Second catalyst component for addition polymerization, catalyst for addition polymerization, and process for producing addition polymer
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2048170A2

  公开（公告）日：2009-04-15

  An electron withdrawing group-containing metal compound (I) of formula [8]:          M4(X1R7i)t R8j-t     [8] wherein M4 represents an atom of Group XII, Groups III to XI or the lanthanide series of the Periodic Table; X1 represents an atom of Group XIV, XV or XVI of the Periodic Table; when a plural number of X1's exist, they may be the same as or different from each other; R7 represents an electron-withdrawing group or a group containing an electron-withdrawing group; when a plural number of R7's exist, they may be the same as or different from each other; R8 represents a hydrogen atom, a halogen atom or a hydrocarbon group; when a plural number of R8's exist, they may be the same as or different from each other; "j" represents a valence of M4; "t" represents a number satisfying 0

  式[8]的含电子萃取基团的金属化合物（I）： M4(X1R7i)t R8j-t [8]. 其中 M4 代表元素周期表中第 XII 族、第 III 族至第 XI 族或镧系元素的原子；X1 代表元素周期表中第 XIV 族、第 XV 族或第 XVI 族的原子；当存在多个 X1 时，它们可以彼此相同或不同；R7 代表抽电子基团或含有抽电子基团的基团；R8代表氢原子、卤素原子或碳氢基团；当存在复数个R8时，它们可以彼此相同或不同；"j "代表M4的化合价；"t "代表满足0