perfluoro-vinyl-perfluoromethyl ether | 116543-13-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: perfluoro-vinyl-perfluoromethyl ether
• 英文别名: Perfluorovinylmethyl ether；1,1,2,3,3-pentafluoro-3-(1,1,2,3,3-pentafluoroprop-2-enoxy)prop-1-ene
• CAS: 116543-13-6
• 化学式: C₆F₁₀O
• 分子量: 278.049
• InChiKey: DQQLQPFHERGYEK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  11

反应信息

• 作为反应物：
  描述：

  perfluoro-vinyl-perfluoromethyl ether 、 2-氯-4-氨基苯酚 在 二甲基亚砜 作用下， 以 水 、 甲苯 为溶剂， 生成 3-氯-4-[1,1,2-三氟-2-(三氟甲氧基)乙氧基]苯胺
  参考文献：
  名称：

  N-(2,6-difluorobenzoyl)-N'-3-chloro-4-[1,1,2-trifluoro-2-(trifluoromethoxy) ethoxy] phenyl urea having insecticidal activity

  摘要：

  公开号：

  EP0271923B1

文献信息

• Process for modifying a polymeric surface
  申请人：3M Innovative Properties Company

  公开号：US20030159915A1

  公开（公告）日：2003-08-28

  This invention concerns a process for modifying a polymeric substrate by contacting the surface with a photoreactive solution of an inorganic photochemical electron donor while irradiating the surface with actinic radiation. Patterns of modified and unmodified surfaces can be produced. Polymeric substrates with modified surfaces may be effectively bonded to polymer films to form composite articles. The process has particular applicability to the surface modification of fluorinated polymers.

  这项发明涉及一种通过将聚合物基底与无机光化学电子供体的光反应性溶液接触，并在表面照射活性辐射的过程来修改聚合物基底的方法。可以制备经过修改和未经修改的表面图案。具有修改表面的聚合物基底可以有效地与聚合物薄膜粘合，形成复合制品。该过程特别适用于氟化聚合物的表面改性。
• Curing compositions for fluoropolymers
  申请人：Grootaert M.A. Werner

  公开号：US20060135827A1

  公开（公告）日：2006-06-22

  A curative composition comprising a cation and an anion of the formula A n q− Q p m+ , wherein m, n, p, and q are positive integers, wherein m*p=n*q, wherein Q m+ is an organo onium, and A q− is an anion, provided that at least one A q− is selected from the formula: wherein each R independently is H, halo, alkyl, aryl, aralkyl, or cycloalkyl, and which also may be halogenated, fluorinated, or perfluorinated, wherein two or more of R and R′ groups may together form a ring, wherein each R group independently may contain one or more heteroatom(s), wherein R′ can be the same as R, with the proviso that R′ cannot be halo. Also provided are a fluoropolymer composition including this curative, a method of making a fluoropolymer, and fluoropolymer articles containing curable or cured fluoropolymer compositions.

  一种治疗性组合物，包括公式Anq-Qpm+的阳离子和阴离子，其中m、n、p和q是正整数，其中m*p=n*q，其中Qm+是一个有机阳离子，Aq-是一个阴离子，但至少有一个Aq-是从以下公式中选择的：其中每个R独立地是H、卤素、烷基、芳基、芳基烷基或环烷基，也可以是卤代、氟代或全氟代的，其中两个或两个以上的R和R'基可以组成一个环，其中每个R基独立地可以包含一个或多个杂原子，其中R'可以与R相同，但R'不能是卤素。还提供了包括该治疗剂的氟聚合物组合物，制备氟聚合物的方法以及含有可固化或已固化的氟聚合物组合物的氟聚合物制品。
• [EN] BRANCHED PERFLUOROVINYL ETHER COMPOUNDS, METHODS OF MAKING THE SAME, AND FLUOROPOLYMERS DERIVED FROM THE BRANCHED PERFLUOROVINYL ETHER COMPOUNDS<br/>[FR] COMPOSÉS D'ÉTHER DE PERFLUOROVINYLE RAMIFIÉ, LEURS PROCÉDÉS DE FABRICATION, ET FLUOROPOLYMÈRES DÉRIVÉS DES COMPOSÉS D'ÉTHER DE PERFLUOROVINYLE RAMIFIÉ
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2020044232A1

  公开（公告）日：2020-03-05

  Described herein is method of making branched perfluorinated compounds, specifically (CF3)2CFCF(CF3)OCF(CF3)C(=O)F and (CF3)2CFCF(CF3)OCF=CF2. Also disclosed herein is a fluoropolymer derived from the branched perfluorovinyl ether monomer and methods of making the fluoropolymer.

  本文描述了制备分支全氟化合物的方法，具体包括(CF3)2CFCF( )OCF( )C(=O)F和( )2CFCF( )OCF=CF2。本文还披露了从分支全氟乙烯醚单体衍生的氟聚合物及其制备方法。
• Bisaminophenyl-based curatives and amidine-based curatives and cure accelerators for perfluoroelastomeric compositions
  申请人：Greene, Tweed of Delaware, Inc.

  公开号：US20040214956A1

  公开（公告）日：2004-10-28

  Novel monoamidine, monoamidoxime and bisamidine curatives, co-curatives and cure accelerators are provided for use with perfluoroelastomeric compositions as well as novel synthesis methods for making monoamidine- and monoamidoxime-based curatives, co-curatives and cure accelerators. Also provided are diphenyl-based curatives, co-curatives and cure accelerators having sufficiently high molecular weight such that the melting temperature of the curatives, co-curatives and cure accelerators is no greater than about 240° C., and more preferably no greater than about 230° C.

  本发明提供了用于与全氟弹性体组合物一起使用的新型单氨基咪唑、单氨基肟和双咪唑治疗剂、共同治疗剂和治疗加速剂，以及用于制备基于单氨基咪唑和单氨基肟的治疗剂、共同治疗剂和治疗加速剂的新型合成方法。还提供了二苯基基治疗剂、共同治疗剂和治疗加速剂，其分子量足够高，使得治疗剂、共同治疗剂和治疗加速剂的熔点不大于约240℃，更好地不大于约230℃。
• Fluoropolymer bonding composition and method
  申请人：——

  公开号：US20030077454A1

  公开（公告）日：2003-04-24

  A multi-layer structure includes a layer of a fluoropolymer bonded to a substrate. The structure is prepared by exposing a bonding composition to actinic radiation, such as ultraviolet radiation, to form the bond. The bonding composition includes a light-absorbing electron donor.

  一种多层结构，包括一层氟聚合物与基底粘合。该结构是通过将粘合组成物暴露于光敏辐射，例如紫外线辐射，以形成粘合的。粘合组成物包括吸收光的电子给体。