顺,顺-1,2,3,4-四氯-1,3-丁二烯 | 35380-72-4

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 中文名称: 顺,顺-1,2,3,4-四氯-1,3-丁二烯
• 英文名称: cis,cis-1,2,3,4-tetrachloro-1,3-butadiene
• 英文别名: (Z,Z)-1,2,3,4-tetrachlorobuta-1,3-diene；cis,cis-1,2,3,4-Tetrachlorbutadien；(Z,Z)-1,2,3,4-Tetrachlor-1,3-butadien；trans, trans-1,2,3,4-Tetrachlor-buta-1,3-dien；(1Z,3Z)-1,2,3,4-tetrachloro-buta-1,3-diene；1t,2,3,4t-tetrachloro-buta-1,3-diene；1t,2,3,4t-Tetrachlor-buta-1,3-dien；(Z,Z)-1,2,3,4-Tetrachlor-butadien；cis,cis-1,2,3,4-Tetrachlor-buta-1,3-dien；1,2,3,4-Tetrachloro-1,3-butadiene；(1Z,3Z)-1,2,3,4-tetrachlorobuta-1,3-diene
• CAS: 35380-72-4
• 化学式: C₄H₂Cl₄
• 分子量: 191.872
• InChiKey: RLWBAEORPSFLTH-CCAGOZQPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  8
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1,1,2,2,3,3,4,4-八氯丁烷 在 锌 作用下， 生成 顺,顺-1,2,3,4-四氯-1,3-丁二烯
  参考文献：
  名称：

  Botta; Mantica; Castellani, Magnetic Resonance in Chemistry, 1998, vol. 36, # 12, p. 885 - 891

  摘要：

  DOI：

文献信息

• INTEGRATED PROCESS FOR THE PRODUCTION OF Z-1,1,1,4,4,4-HEXAFLUORO-2-BUTENE
  申请人：THE CHEMOURS COMPANY FC, LLC

  公开号：US20160039728A1

  公开（公告）日：2016-02-11

  The present invention provides an efficient and cost effect synthesis route from a specific starting material of 2,3-dichloro-1,3-butadiene to the desired product of Z-1,1,1,4,4,4-hexafluoro-2-butene.

  本发明提供了一种高效且成本效益的合成路线，从2,3-二氯-1,3-丁二烯的特定起始材料到所需的Z-1,1,1,4,4,4-六氟-2-丁烯产物。
• Vinyl monomer compositions
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0182543A1

  公开（公告）日：1986-05-28

  Vinyl monomer compositions, especially useful as binders for polymer concrete and as impregnants or sealers for surface cure substrates, which upon application develop rapid surface cure, comprise low volatility vinyl monomers having dispersed therein diolefin rubber which is insoluble in said vinyl monomer, and at least one polyvalent metal catalyst.

  乙烯基单体组合物，尤其可用作聚合物混凝土的粘结剂和表面固化基材的浸渍剂或密封剂，在使用时可产生快速的表面固化，由低挥发性乙烯基单体（其中分散有不溶于所述乙烯基单体的二烯烃橡胶）和至少一种多价金属催化剂组成。
• Vinyl monomer composition with accelerated surface cure
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0522790A1

  公开（公告）日：1993-01-13

  Vinyl monomer compositions having accelerated surface cure characteristics are described. These compositions are prepared from a vinyl monomer or monomer mixtures such as blend of isobornyl methacrylate and hydroxypropyl methacrylate, a bulk phase polymerization catalyst system, a polyvalent metal oxidative surface phase catalyst, and a diolefin rubber dispersed in the vinyl monomer as a surface cure accelerator. These compositions are useful as sealers, healers and for polymer concrete.

  描述了具有加速表面固化特性的乙烯基单体组合物。这些组合物由乙烯基单体或单体混合物（如甲基丙烯酸异冰片酯和甲基丙烯酸羟丙酯的混合物）、体相聚合催化剂系统、多价金属氧化表面相催化剂以及分散在乙烯基单体中作为表面固化促进剂的二烯烃橡胶制备而成。这些组合物可用作密封剂、愈合剂和聚合物混凝土。
• Method for preparing hexafluorobutadiene
  申请人：Arkema France

  公开号：US10336669B2

  公开（公告）日：2019-07-02

  The present invention relates to a method for preparing hexafluorobutadiene comprising the following steps: (a) hydrodechlorinating hexachlorobutadiene to form a first stream comprising 1,2,3,4-tetrachlorobutadiene and optionally unreacted hexachlorobutadiene; (b) fluorinating the first stream comprising 1,2,3,4-tetrachlorobutadiene obtained in step (a) to form a second stream comprising 1,1,2,3,4,4-hexafluorobutane, (c) dehydrogenating the second stream comprising 1,1,2,3,4,4-hexafluorobutane to form a third stream comprising hexafluorobutadiene.

  本发明涉及一种制备六氟丁二烯的方法，包括以下步骤：(a) 对六氯丁二烯进行加氢脱氯处理，形成由 1,2,3,4-四氯丁二烯和任选未反应的六氯丁二烯组成的第一液流；(b) 将步骤(a)中获得的由 1,2,3,4-四氯丁二烯组成的第一液流氟化，形成由 1,1,2,3,4,4-六氟丁烷组成的第二液流， (c) 将由 1,1,2,3,4,4-六氟丁烷组成的第二液流脱氢，形成由六氟丁二烯组成的第三液流。
• Sex and Age Effects on Willingness to Communicate, Anxiety, Perceived Competence, and L2 Motivation Among Junior High School French Immersion Students
  作者：Peter D. MacIntyre、Susan C. Baker、Richard Clément、Leslie A. Donovan

  DOI：10.1111/1467-9922.00194

  日期：2002.9

  The present study involves a cross–sectional investigation of second–language (L2) communication among students in a junior high French late immersion program. The effects of language, sex, and grade on willingness to communicate (WTC), anxiety, and perceived communication competence, on frequency of communication in French, and on the attitude and motivation variables are examined globally and at each grade level. It was found that students’ L2 WTC, perceived competence, and frequency of communication in French increased from grades 7 to 8 and was maintained between grades 8 and 9, despite a drop in motivation between grades 7 and 8 and a steady level of anxiety across the three grades.