2,3-Dicarboxy-9,10-diphenyl-anthracen | 52483-91-7

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: 2,3-Dicarboxy-9,10-diphenyl-anthracen
• 英文别名: 9.10-Diphenyl-anthracendicarbonsaeure-(2.3)；9,10-Diphenylanthracen-2,3-dicarbonsaeure；9,10-Diphenyl-1,2-anthracendicarbonsaeure；9,10-Diphenylanthracene-2,3-dicarboxylic acid
• CAS: 52483-91-7
• 化学式: C₂₈H₁₈O₄
• 分子量: 418.449
• InChiKey: MUEXEMYZXVIXPJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  32
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,3-Dicarboxy-9,10-diphenyl-anthracen 在 甲烷磺酸 、 乙酸酐 作用下， 生成 9-[2-(3-Carboxy-9,10-diphenyl)anthryl]-6-hydroxy-3H-xanthen-3-one
  参考文献：
  名称：

  Novel Fluorescent Probes for Singlet Oxygen

  摘要：

  The first fluorescent chemical traps for (1)O(2) have been developed. DPAXs react specifically with (1)O(2) to yield the corresponding endoperoxides, DPAX-EPs (see scheme; X = H, Cl, F). DPAXs scarcely fluoresce, while DPAX-EPs are strongly fluorescent. Since the fluorescence of these probes is unaffected by H(2)O(2), superoxide, and nitric oxide, they are useful for the selective detection of (1)O(2) in biological systems.

  DOI：

  10.1002/(sici)1521-3773(19991004)38:19<2899::aid-anie2899>3.0.co;2-m
• 作为产物：
  描述：

  dimethyl (3S,4R,5S,6R)-1,8-diphenyl-15,16-dioxapentacyclo[6.6.1.13,6.02,7.09,14]hexadeca-9,11,13-triene-4,5-dicarboxylate 在 氢氧化钾 、 硫酸 作用下， 以 1,4-二氧六环 、 甲醇 、 二氯甲烷 为溶剂， 生成 2,3-Dicarboxy-9,10-diphenyl-anthracen
  参考文献：
  名称：

  Novel Fluorescent Probes for Singlet Oxygen

  摘要：

  The first fluorescent chemical traps for (1)O(2) have been developed. DPAXs react specifically with (1)O(2) to yield the corresponding endoperoxides, DPAX-EPs (see scheme; X = H, Cl, F). DPAXs scarcely fluoresce, while DPAX-EPs are strongly fluorescent. Since the fluorescence of these probes is unaffected by H(2)O(2), superoxide, and nitric oxide, they are useful for the selective detection of (1)O(2) in biological systems.

  DOI：

  10.1002/(sici)1521-3773(19991004)38:19<2899::aid-anie2899>3.0.co;2-m