2-methyl-1,3-propanediol dimethacrylate | 86168-85-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-methyl-1,3-propanediol dimethacrylate
• 英文别名: [2-Methyl-3-(2-methylprop-2-enoyloxy)propyl] 2-methylprop-2-enoate
• CAS: 86168-85-6
• 化学式: C₁₂H₁₈O₄
• 分子量: 226.273
• InChiKey: WPMFZXJYQLIHBM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  16
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-甲基-1,3-丙二醇 、 甲基丙烯酸甲酯 在 Novozyme 435 作用下， 以 2-甲基-2-丁醇 为溶剂， 反应 120.0h， 生成 2-methyl-1,3-propanediol dimethacrylate 、 (3-Hydroxy-2-methylpropyl) 2-methylprop-2-enoate
  参考文献：
  名称：

  Hydroxy functional acrylate and methacrylate monomers prepared via lipase—catalyzed transacylation reactions

  摘要：

  Candida antarctica lipase B (CAL-B, Novozyme 435) catalyzes the transacylation of methyl acrylate and methyl methacrylate with diols and triols in 2-methyl-2-butanol at 50 degrees C. Under the experimental conditions, up to 70 mol% of the acyl donor methyl acrylate was converted. Methyl methacrylate is the less efficient acyl donor (up to 60 mol%) due to the higher sterical hindrance in the enzymatic transacylation. Under the reaction conditions high yields of the mono-acylated products are obtained, which contain minor amounts of bis(meth)acrylates. In addition it was observed that Novozyme 435 catalyzes regioselectively the acylation of the primary hydroxyl groups. In comparison with the chemical catalyzed route no selectivity was observed for unsubstituted diols. For substituted diols more mono-acylated product was formed in the lipase-catalyzed reaction than in the chemical catalyzed reaction. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcatb.2009.09.008

文献信息

• RESIN FOR TONER AND TONER
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20150099227A1

  公开（公告）日：2015-04-09

  The present invention provides a crystalline polyester resin for toner that has, when used as a resin for toner, a sharp melt property, excellent fixing performance and blocking property and a preferable charging performance. Provided is a crystalline polyester resin for toner, which is obtained by condensation polymerization of a dicarboxylic acid component containing at least one compound selected from the group consisting of terephthalic acid, 2,6-naphthalenedicarboxylic acid and derivatives thereof, and a diol component containing at least one compound selected from the group consisting of 2-methyl-1,3-propanediol, 2,2-dimethyl-1,3-propanediol and derivatives thereof, the crystalline polyester resin having a weight-average molecular weight of not less than 5000 and not more than 50000.

  本发明提供了一种用于制作墨粉的结晶聚酯树脂，当用作墨粉的树脂时，具有锐利的熔融特性，优异的固定性能和阻塞性能以及优选的充电性能。所提供的结晶聚酯树脂是通过含有苯二甲酸、2,6-萘二甲酸及其衍生物中至少一种化合物的二羧酸组分和含有2-甲基-1,3-丙二醇、2,2-二甲基-1,3-丙二醇及其衍生物中至少一种化合物的二元醇组分的缩聚聚合而得到的，该结晶聚酯树脂具有重均分子量不小于5000且不大于50000。
• PROCESS FOR PRODUCING METHACRYLIC RESIN MOLDING
  申请人：KURARAY CO., LTD.

  公开号：EP0402466A1

  公开（公告）日：1990-12-19

  A process for producing methacrylic resin mold- ings having excellent flaw resistance, weatherability, heat resistance, etc., which comprises bringing into contact (A) a preliminary reaction product obtained by polymerizing a composition of a hydrolyzate of alkoxysilane having (meth)acryloxy groups and silica sol to a reaction ratio of 15 to 60, with (8) a molding base material composed of a partially crosslinked acrylic gel polymer obtained by mixing (i) a resin material selected from the group consisting of an alkyl methacrytate monomer, a mixture of a predominant amount of alkyl methacrylate with an α, -ethylenically unsaturated monomer, and a syrup containing polymer thereof with (ii) a cross-linking polymerizable compound having at least two (meth)acryloyloxy groups in a proportion of 3 to 100 parts by weight of said crosslinkable compound per 100 parts by weight of said resin material, and partially polymerizing the mixture in the presence of a polymerization initiator till gel fraction reaches 15 to 50 %, and conducting polymerization under the condition giving a desired shape.

  一种用于生产具有优异的抗缺陷性、耐候性、耐热性等性能的甲基丙烯酸树脂模塑件的工艺、该工艺包括：(A) 将具有（甲基）丙烯酰氧基的烷氧基硅烷的水解物与硅溶胶按 15 至 60 的反应比聚合而成的组合物与(8) 由部分交联丙烯酸凝胶聚合物组成的模塑基础材料接触，该部分交联丙烯酸凝胶聚合物由以下树脂材料混合而成：(i) 选自甲基丙烯酸烷基单体、甲基丙烯酸烷基单体与α、-(ii)具有至少两个(甲基)丙烯酰氧基的可交联聚合化合物，其比例为每 100 重量份所述树脂材料中含 3 至 100 重量份所述可交联化合物，并在聚合引发剂存在下使混合物部分聚合，直至凝胶部分达到 15%至 50%，然后在可获得所需形状的条件下进行聚合。
• ACRYLIC COMPOSITION, MOLDING, CELLULAR PHONE KEY SHEET, AND LIGHT GUIDE
  申请人：Mitsubishi Rayon Co., Ltd.

  公开号：EP2612874A1

  公开（公告）日：2013-07-10

  An acrylic composition, which has excellent flexibility at low temperature and can form a formed body whose adhesion at room temperature is suppressed, the formed body of the acrylic composition, a key sheet of a mobile telephone, and a light guide obtained from the formed body are provided. The acrylic composition contains specific long chain di(meth)acrylate (A) and mono(meth)acrylate (B), and the glass-transformation temperature (TgDMS) of the polymer of the acrylic composition is 40°C or less. The formed body is obtained by polymerization of the acrylic composition, and the key sheet of the mobile telephone and the light guide are obtained from the formed body.

  本发明提供了一种丙烯酸组合物，该组合物在低温下具有优异的柔韧性，并能形成室温下粘附性受到抑制的成型体、丙烯酸组合物成型体、移动电话的按键片以及由成型体获得的导光板。丙烯酸组合物含有特定的长链二(甲基)丙烯酸酯 (A) 和单(甲基)丙烯酸酯 (B)，丙烯酸组合物聚合物的玻璃转化温度 (TgDMS) 为 40°C 或以下。通过聚合丙烯酸组合物可以得到成型体，移动电话的按键片和导光板就是从成型体中得到的。
• TONER RESIN AND TONER
  申请人：Canon Kabushiki Kaisha

  公开号：EP2985303A1

  公开（公告）日：2016-02-17

  The present invention provides a crystalline polyester resin for toner that has, when used as a resin for toner, a sharp melt property, excellent fixing performance and blocking property and a preferable charging performance. Provided is a crystalline polyester resin for toner, which is obtained by condensation polymerization of a dicarboxylic acid component containing at least one compound selected from the group consisting of terephthalic acid, 2,6-naphthalenedicarboxylic acid and derivatives thereof, and a diol component containing at least one compound selected from the group consisting of 2-methyl-1,3-propanediol, 2,2-dimethyl-1,3-propanediol and derivatives thereof, the crystalline polyester resin having a weight-average molecular weight of not less than 5000 and not more than 50000.

  本发明提供了一种墨粉用结晶聚酯树脂，当用作墨粉用树脂时，该树脂具有敏锐的熔融特性、优异的固定性能和阻塞性能，以及优越的充电性能。本发明提供了一种墨粉用结晶聚酯树脂，它是由含有至少一种从对苯二甲酸、2,6-萘二甲酸及其衍生物组成的组中选出的化合物的二羧酸组分和至少含有一种从对苯二甲酸、2,6-萘二甲酸及其衍生物组成的组中选出的化合物的二元醇组分缩合聚合而得、和二元醇组分，二元醇组分含有至少一种选自由 2-甲基-1,3-丙二醇、2,2-二甲基-1,3-丙二醇及其衍生物组成的组中的化合物，结晶聚酯树脂的重量平均分子量不小于 5000，不大于 50000。
• Verfahren zur Herstellung von Di(meth)acrylsäureestern
  申请人：Röhm GmbH & Co. KG

  公开号：EP1078913B1

  公开（公告）日：2004-03-24