N,N'-didecyl-3,4,9,10-perylenetetracarboxylic diimide | 82531-04-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: N,N'-didecyl-3,4,9,10-perylenetetracarboxylic diimide
• 英文别名: N,N’-bis(decyl)-3,4:9,10-perylenebis(dicarboximide)；N,N'-di(decyl)-3,4,9,10-perylenebis(dicarboximide)；7,18-Didecyl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone
• CAS: 82531-04-2
• 化学式: C₄₄H₅₀N₂O₄
• 分子量: 670.892
• InChiKey: RIEQTUDJFVSMGD-UHFFFAOYSA-N

物化性质

• 熔点：
  >250 °C
• 沸点：
  804.7±38.0 °C(Predicted)
• 密度：
  1.194±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  12.7
• 重原子数：
  50
• 可旋转键数：
  18
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  74.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N,N'-didecyl-3,4,9,10-perylenetetracarboxylic diimide 在 盐酸 、 硼烷四氢呋喃络合物 作用下， 生成 N,N'-didecyl-3,4,9,10-perylenetetramethylenyldiamine
  参考文献：
  名称：

  Hsu, Shih-Ying; Chiang, Long Y., Synthetic Communications, 1989, vol. 19, # 11-12, p. 1885 - 1890

  摘要：

  DOI：
• 作为产物：
  描述：

  1-氨基癸烷 、 3,4,9,10-苝四羧酸二酐 以 水 为溶剂， 反应 24.33h， 生成 N,N'-didecyl-3,4,9,10-perylenetetracarboxylic diimide
  参考文献：
  名称：

  绿色环保高效合成synthesis和萘二酰亚胺

  摘要：

  绿色的一锅法水热路线可定量生成高纯度的荧光双酰亚胺染料，而无需催化剂或有机溶剂。

  DOI：

  10.1039/c6cc06567h

文献信息

• A Disposable and Noncontact Paper Breathalyzer Based on Small Conjugated Molecules/Carbon Nanotubes Electrodes
  作者：Sara Luiza Gusso、Letícia Barros Prado、Anderson Emanuel Ximim Gavim、Jeferson Ferreira de Deus、Leonardo Foti、Abd. Rashid Bin Mohd Yusoff、Wilson José da Silva、Paula Cristina Rodrigues、Andreia Gerniski Macedo

  DOI：10.1002/pssa.202100808

  日期：2022.4

  N′-di(decyl)-3,4,9,10-perylenebis(dicarboximide) (PDIC10) is first functionalized by hydrothermal synthesis method and processed onto single-walled carbon nanotube (SWCN) electrodes and paper substrate. The PDC10/SWCN/paper device can be applied as a noncontact breathalyzer to detect and quantify ethanol alcohol and determine equivalent blood alcohol concentration (BAC). The sensing mechanism increases the electrical

  在此，N , N '-二(癸基)-3,4,9,10-苝双(二甲酰亚胺) (PDIC10) 首先通过水热合成方法功能化并加工到单壁碳纳米管 (SWCN) 电极和纸基板上。PDC10/SWCN/纸装置可用作非接触式呼气测醉器，以检测和量化乙醇酒精并确定等效血液酒精浓度 (BAC)。传感机制增加了乙醇 (EtOH) 暴露时的电阻。该设备允许对 0.01% 至 0.2% 的 BAC 值进行量化，在此范围内ΔR (%) 为 2-25%，在循环中具有足够的稳定性。
• SENSOR COMPOUNDS AND ASSOCIATED METHODS AND DEVICES
  申请人：UNIVERSITY OF UTAH RESEARCH FOUNDATION

  公开号：US20180201612A1

  公开（公告）日：2018-07-19

  Methods of detecting a non-explosive analyte can include exposing a sensor compound to a non-explosive analyte and displaying a change in the sensor compound upon exposure of the sensor compound to the non-explosive analyte. A variety of sensor compounds for detecting a target analyte, including both explosive and non-explosive analytes, is also described. Sensor devices for detecting a target analyte can include a substrate and a sensor compound positioned on the substrate in a plurality of detection zones.

  检测非爆炸性分析物的方法可以包括将传感器化合物暴露于非爆炸性分析物，并在传感器化合物暴露于非爆炸性分析物时显示传感器化合物的变化。还描述了用于检测目标分析物（包括爆炸性和非爆炸性分析物）的各种传感器化合物。用于检测目标分析物的传感器设备可以包括底板和位于底板上的传感器化合物，其位于多个检测区域中。
• Organic Field-effect Transistors based on Disubstituted Perylene Diimides: Effect of Alkyl Chains on the Device Performance
  作者：Alexander V. Mumyatov、Lidiya I. Leshanskaya、Denis V. Anokhin、Nadezhda N. Dremova、Pavel A. Troshin

  DOI：10.1016/j.mencom.2014.09.020

  日期：2014.9

  The preparation and systematic investigation of n-type semiconductor materials based on disubstituted perylene diimides (PDIs) possessing alkyl chains with variable length (from C-4 to C-12) are reported. It was shown that electrical characteristics of field-effect transistors can be tuned by changing the length of the alkyl chains in the PDIs used as semiconductor materials.
• HSU, SHIH-YING;CHIANG, LONG Y., SYNTH. COMMUN., 19,(1989) N1-12, C. 1885-1889
  作者：HSU, SHIH-YING、CHIANG, LONG Y.

  DOI：——

  日期：——
• [EN] SENSOR COMPOUNDS AND ASSOCIATED METHODS AND DEVICES<br/>[FR] COMPOSÉS DE DÉTECTION ET PROCÉDÉS ET DISPOSITIFS ASSOCIÉS
  申请人：UNIV UTAH RES FOUND

  公开号：WO2017008074A1

  公开（公告）日：2017-01-12

  Methods of detecting a non-explosive analyte can include exposing a sensor compound to a non-explosive analyte and displaying a change in the sensor compound upon exposure of the sensor compound to the non-explosive analyte. A variety of sensor compounds for detecting a target analyte, including both explosive and non-explosive analytes, is also described. Sensor devices for detecting a target analyte can include a substrate and a sensor compound positioned on the substrate in a plurality of detection zones.